43
Table 2 Collective summary of V-based electrodes along with their cell configurations and
electrochemical performances for aqueous ZIBs
Cathode morphologies/
preparative methods
Electrolyte +
additive
Potential
Window
Current
density
(mA g
−1
)
Cyclability
(mAh g
−1 )
Ref.
V 2 O 5 nanosheets / sol-gel
3 M ZnSO 4
0.4–1.4
100
182 after
30 cycles
[76]
Porous V 2 O 5 nanofibers /
electrospinning
3 M
Zn(CF 3 SO 3 ) 2
0.5–1.5
588
(1C = 294)
166 after
500 cycles
[77]
V 10 O 24 •12H 2 O dendrite /
hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.7–1.7
500
~135 after
500 cycles
[78]
Na 0.33 V 2 O 5 nanowires /
hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.2–1.6
200
~250 after
500 cycles
[68]
Na 5 V 12 O 32 nanobelts /
hydrothermal
2 M ZnSO 4
0.4–1.4
500
~200 after
100 cycles
[79]
Na 0.76 V 6 O 15 nanobelts /
hydrothermal
2 M ZnSO 4
0.4–1.4
500
~110 after
100 cycles
[79]
K 2 V 8 O 21 nanobelts /
hydrothermal
2 M ZnSO 4
0.4–1.4
1000
~220 after
50 cycles
[80]
Ag 0.4 V 2 O 5 nanorods /
hydrothermal
3 M ZnSO 4
0.4–1.4
5000
216 after
2000 cycles
[81]
(NH 4 ) 2 V 10 O 25 •8H 2 O nanobelts
/ hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.7–1.7
500
~180 ater
1000 cycles
[82]
LiV 3 O 8 flakes / solid-state
reaction
1 M ZnSO 4
0.6–1.6
133
~140 after
65 cycles
[63]
NaV 3 O 8 •1.5H 2 O nanobelts /
liquid–solid stirring method
1 M
ZnSO 4 + 1 M
Na 2 SO 4
0.3–1.3
1000
221 after
100 cycles
[83]
1 M ZnSO 4 /
gelatin
0.3–1.3
500
~120 after
120 cycles
KV 3 O 8 nanostructure /
hydrothermal
2 M ZnSO 4
0.4–1.4
500
~90 after
1000 cycles
[84]
Zn 2 V 2 O 7 nanowire /
hydrothermal
1 M ZnSO 4
0.4–1.4
300
197 after
200 cycles
[70]
Fe 5 V 12 O 39 (OH)•9H 2 O
nanosheets / water bath
3 M
Zn(CF 3 SO 3 ) 2
0.4–1.6
1000
200 after
50 cycles
[85]
Zn 3 V 2 O 7 (OH) 2 •2H 2 O
nanowire / microwave
1 M ZnSO 4
0.2–1.8
200
101 after
300 cycles
[65]
V 5 O 12 •6H 2 O nanobelts /
electrodeposition
3 M
Zn(CF 3 SO 3 ) 2
0.2–1.6
500
346 after
100 cycles
[86]
K 0.5 V 2 O 5 ·0.76H 2 O nanorods /
hydrothermal
1 M ZnSO 4
0.4–1.4
8000
150 after
1500 cycles
[87]
(NH 4 ) 2 V 4 O 9 sheets /
hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.3–1.3
100
328 after
100 cycles
[88]
Zn 0.3 V 2 O 5 ·1.5H 2 O
nanospheres / in situ
electrochemical cycling
3 M
Zn(CF 3 SO 3 ) 2
0.3–1.6
10,000
214 after
20,000 cycles
[89]
(continued)
Recent Developments of Zinc-Ion Batteries
Table 2 Collective summary of V-based electrodes along with their cell configurations and
electrochemical performances for aqueous ZIBs
Cathode morphologies/
preparative methods
Electrolyte +
additive
Potential
Window
Current
density
(mA g
−1
)
Cyclability
(mAh g
−1 )
Ref.
V 2 O 5 nanosheets / sol-gel
3 M ZnSO 4
0.4–1.4
100
182 after
30 cycles
[76]
Porous V 2 O 5 nanofibers /
electrospinning
3 M
Zn(CF 3 SO 3 ) 2
0.5–1.5
588
(1C = 294)
166 after
500 cycles
[77]
V 10 O 24 •12H 2 O dendrite /
hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.7–1.7
500
~135 after
500 cycles
[78]
Na 0.33 V 2 O 5 nanowires /
hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.2–1.6
200
~250 after
500 cycles
[68]
Na 5 V 12 O 32 nanobelts /
hydrothermal
2 M ZnSO 4
0.4–1.4
500
~200 after
100 cycles
[79]
Na 0.76 V 6 O 15 nanobelts /
hydrothermal
2 M ZnSO 4
0.4–1.4
500
~110 after
100 cycles
[79]
K 2 V 8 O 21 nanobelts /
hydrothermal
2 M ZnSO 4
0.4–1.4
1000
~220 after
50 cycles
[80]
Ag 0.4 V 2 O 5 nanorods /
hydrothermal
3 M ZnSO 4
0.4–1.4
5000
216 after
2000 cycles
[81]
(NH 4 ) 2 V 10 O 25 •8H 2 O nanobelts
/ hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.7–1.7
500
~180 ater
1000 cycles
[82]
LiV 3 O 8 flakes / solid-state
reaction
1 M ZnSO 4
0.6–1.6
133
~140 after
65 cycles
[63]
NaV 3 O 8 •1.5H 2 O nanobelts /
liquid–solid stirring method
1 M
ZnSO 4 + 1 M
Na 2 SO 4
0.3–1.3
1000
221 after
100 cycles
[83]
1 M ZnSO 4 /
gelatin
0.3–1.3
500
~120 after
120 cycles
KV 3 O 8 nanostructure /
hydrothermal
2 M ZnSO 4
0.4–1.4
500
~90 after
1000 cycles
[84]
Zn 2 V 2 O 7 nanowire /
hydrothermal
1 M ZnSO 4
0.4–1.4
300
197 after
200 cycles
[70]
Fe 5 V 12 O 39 (OH)•9H 2 O
nanosheets / water bath
3 M
Zn(CF 3 SO 3 ) 2
0.4–1.6
1000
200 after
50 cycles
[85]
Zn 3 V 2 O 7 (OH) 2 •2H 2 O
nanowire / microwave
1 M ZnSO 4
0.2–1.8
200
101 after
300 cycles
[65]
V 5 O 12 •6H 2 O nanobelts /
electrodeposition
3 M
Zn(CF 3 SO 3 ) 2
0.2–1.6
500
346 after
100 cycles
[86]
K 0.5 V 2 O 5 ·0.76H 2 O nanorods /
hydrothermal
1 M ZnSO 4
0.4–1.4
8000
150 after
1500 cycles
[87]
(NH 4 ) 2 V 4 O 9 sheets /
hydrothermal
3 M
Zn(CF 3 SO 3 ) 2
0.3–1.3
100
328 after
100 cycles
[88]
Zn 0.3 V 2 O 5 ·1.5H 2 O
nanospheres / in situ
electrochemical cycling
3 M
Zn(CF 3 SO 3 ) 2
0.3–1.6
10,000
214 after
20,000 cycles
[89]
(continued)
Recent Developments of Zinc-Ion Batteries