494
24 Water and Aqueous Solutions
20. C.Q. Sun, X. Zhang, J. Zhou, Y. Huang, Y. Zhou, W. Zheng, Density, elasticity, and stability
anomalies of water molecules with fewer than four neighbors. J. Phys. Chem. Lett. 4, 2565–2570
(2013)
21. Y. Huang, X. Zhang, Z. Ma, Y. Zhou, J. Zhou, W. Zheng, C.Q. Sun, Size, separation, structure
order, and mass density of molecules packing in water and ice. Sci. Rep. 3, 3005 (2013)
22. Q. Zeng, T. Yan, K. Wang, Y. Gong, Y. Zhou, Y. Huang, C.Q. Sun, B. Zou, Compression
icing of room-temperature NaX solutions (X = F, Cl, Br, I). Phys. Chem. Chem. Phys. 18(20),
14046–14054 (2016)
23. Q. Zeng, C. Yao, K. Wang, C.Q. Sun, B. Zou, Room-temperature NaI/H 2 O compression icing:
Solute–solute interactions. Phys. Chem. Chem. Phys. 19, 26645–26650 (2017)
24. Y.L. Huang, X. Zhang, Z.S. Ma, G.H. Zhou, Y.Y. Gong, C.Q. Sun, Potential paths for the
Hydrogen-bond relaxing with (H2O)(N) cluster size. J. Phys. Chem. C 119(29), 16962–16971
(2015)
25. Y. Huang, X. Zhang, Z. Ma, Y. Zhou, G. Zhou, C.Q. Sun, Hydrogen-bond asymmetric local
potentials in compressed ice. J. Phys. Chem. B 117(43), 13639–13645 (2013)
26. X. Zhang, Y. Huang, Z. Ma, Y. Zhou, J. Zhou, W. Zheng, Q. Jiang, C.Q. Sun, Hydrogen-bond
memory and water-skin supersolidity resolving the Mpemba paradox. Phys. Chem. Chem.
Phys. 16(42), 22995–23002 (2014)
27. D. Marx, M.E. Tuckerman, J. Hutter, M. Parrinello, The nature of the hydrated excess proton
in water. Nature 397(6720), 601–604 (1999)
28. Y. Crespo, A. Hassanali, Characterizing the local solvation environment of OH − in water
clusters with AIMD. J. Chem. Phys. 144(7), 074304 (2016)
29. A. Mandal, K. Ramasesha, L. De Marco, A. Tokmakoff, Collective vibrations of water-solvated
hydroxide ions investigated with broadband 2DIR spectroscopy. J. Chem. Phys. 140(20),
204508 (2014)
30. S.T. Roberts, P.B. Petersen, K. Ramasesha, A. Tokmakoff, I.S. Ufimtsev, T.J. Martinez, Observation of a Zundel-like transition state during proton transfer in aqueous hydroxide solutions.
Proc. Natl. Acad. Sci. 106(36), 15154–15159 (2009)
31. J. Chen, C. Yao, X. Liu, X. Zhang, C.Q. Sun, Y. Huang, H 2 O 2 and HO − solvation dynamics: Solute capabilities and solute-solvent molecular interactions. Chem. Select 2, 8517–8523
(2017)
32. C.Q. Sun, Relaxation of the chemical bond. Springer Ser. Chem. Phys. 108, 807 (2014).
(Springer, Heidelberg)
33. X. Zhang, Y. Huang, Z. Ma, Y. Zhou, W. Zheng, J. Zhou, C.Q. Sun, A common supersolid skin
covering both water and ice. Phys. Chem. Chem. Phys. 16(42), 22987–22994 (2014)
34. M. Thämer, L. De Marco, K. Ramasesha, A. Mandal, A. Tokmakoff, Ultrafast 2D IR
spectroscopy of the excess proton in liquid water. Science 350(6256), 78–82 (2015)
35. Y. Zhou, D. Wu, Y. Gong, Z. Ma, Y. Huang, X. Zhang, C.Q. Sun, Base-hydration-resolved
hydrogen-bond networking dynamics: Quantum point compression. J. Mol. Liq. 223, 1277–
1283 (2016)
36. X. Zhang, T. Yan, Y. Huang, Z. Ma, X. Liu, B. Zou, C.Q. Sun, Mediating relaxation and
polarization of hydrogen-bonds in water by NaCl salting and heating. Phys. Chem. Chem.
Phys. 16(45), 24666–24671 (2014)
37. Y. Gong, Y. Zhou, H. Wu, D. Wu, Y. Huang, C.Q. Sun, Raman spectroscopy of alkali halide
hydration: Hydrogen bond relaxation and polarization. J. Raman Spectrosc. 47(11), 1351–1359
(2016)
38. S. Park, D.E. Moilanen, M.D. Fayer, Water Dynamics: The Effects of Ions and Nanoconfinement. J. Phys. Chem. B 112(17), 5279–5290 (2008)
39. C.Q. Sun, Supersolidity of the undercoordinated and the hydrating water (Perspective). Phys.
Chem. Chem. Phys. 20, 30104–30119 (2018)
40. T.F. Kahan, J.P. Reid, D.J. Donaldson, Spectroscopic probes of the quasi-liquid layer on ice. J.
Phys. Chem. A 111(43), 11006–11012 (2007)
41. Y. Zhou, Y. Zhong, X. Liu, Y. Huang, X. Zhang, C.Q. Sun, NaX solvation bonding dynamics:
hydrogen bond and surface stress transition (X = HSO4, NO3, ClO4, SCN). J. Mol. Liq. 248,
432–438 (2017)
24 Water and Aqueous Solutions
20. C.Q. Sun, X. Zhang, J. Zhou, Y. Huang, Y. Zhou, W. Zheng, Density, elasticity, and stability
anomalies of water molecules with fewer than four neighbors. J. Phys. Chem. Lett. 4, 2565–2570
(2013)
21. Y. Huang, X. Zhang, Z. Ma, Y. Zhou, J. Zhou, W. Zheng, C.Q. Sun, Size, separation, structure
order, and mass density of molecules packing in water and ice. Sci. Rep. 3, 3005 (2013)
22. Q. Zeng, T. Yan, K. Wang, Y. Gong, Y. Zhou, Y. Huang, C.Q. Sun, B. Zou, Compression
icing of room-temperature NaX solutions (X = F, Cl, Br, I). Phys. Chem. Chem. Phys. 18(20),
14046–14054 (2016)
23. Q. Zeng, C. Yao, K. Wang, C.Q. Sun, B. Zou, Room-temperature NaI/H 2 O compression icing:
Solute–solute interactions. Phys. Chem. Chem. Phys. 19, 26645–26650 (2017)
24. Y.L. Huang, X. Zhang, Z.S. Ma, G.H. Zhou, Y.Y. Gong, C.Q. Sun, Potential paths for the
Hydrogen-bond relaxing with (H2O)(N) cluster size. J. Phys. Chem. C 119(29), 16962–16971
(2015)
25. Y. Huang, X. Zhang, Z. Ma, Y. Zhou, G. Zhou, C.Q. Sun, Hydrogen-bond asymmetric local
potentials in compressed ice. J. Phys. Chem. B 117(43), 13639–13645 (2013)
26. X. Zhang, Y. Huang, Z. Ma, Y. Zhou, J. Zhou, W. Zheng, Q. Jiang, C.Q. Sun, Hydrogen-bond
memory and water-skin supersolidity resolving the Mpemba paradox. Phys. Chem. Chem.
Phys. 16(42), 22995–23002 (2014)
27. D. Marx, M.E. Tuckerman, J. Hutter, M. Parrinello, The nature of the hydrated excess proton
in water. Nature 397(6720), 601–604 (1999)
28. Y. Crespo, A. Hassanali, Characterizing the local solvation environment of OH − in water
clusters with AIMD. J. Chem. Phys. 144(7), 074304 (2016)
29. A. Mandal, K. Ramasesha, L. De Marco, A. Tokmakoff, Collective vibrations of water-solvated
hydroxide ions investigated with broadband 2DIR spectroscopy. J. Chem. Phys. 140(20),
204508 (2014)
30. S.T. Roberts, P.B. Petersen, K. Ramasesha, A. Tokmakoff, I.S. Ufimtsev, T.J. Martinez, Observation of a Zundel-like transition state during proton transfer in aqueous hydroxide solutions.
Proc. Natl. Acad. Sci. 106(36), 15154–15159 (2009)
31. J. Chen, C. Yao, X. Liu, X. Zhang, C.Q. Sun, Y. Huang, H 2 O 2 and HO − solvation dynamics: Solute capabilities and solute-solvent molecular interactions. Chem. Select 2, 8517–8523
(2017)
32. C.Q. Sun, Relaxation of the chemical bond. Springer Ser. Chem. Phys. 108, 807 (2014).
(Springer, Heidelberg)
33. X. Zhang, Y. Huang, Z. Ma, Y. Zhou, W. Zheng, J. Zhou, C.Q. Sun, A common supersolid skin
covering both water and ice. Phys. Chem. Chem. Phys. 16(42), 22987–22994 (2014)
34. M. Thämer, L. De Marco, K. Ramasesha, A. Mandal, A. Tokmakoff, Ultrafast 2D IR
spectroscopy of the excess proton in liquid water. Science 350(6256), 78–82 (2015)
35. Y. Zhou, D. Wu, Y. Gong, Z. Ma, Y. Huang, X. Zhang, C.Q. Sun, Base-hydration-resolved
hydrogen-bond networking dynamics: Quantum point compression. J. Mol. Liq. 223, 1277–
1283 (2016)
36. X. Zhang, T. Yan, Y. Huang, Z. Ma, X. Liu, B. Zou, C.Q. Sun, Mediating relaxation and
polarization of hydrogen-bonds in water by NaCl salting and heating. Phys. Chem. Chem.
Phys. 16(45), 24666–24671 (2014)
37. Y. Gong, Y. Zhou, H. Wu, D. Wu, Y. Huang, C.Q. Sun, Raman spectroscopy of alkali halide
hydration: Hydrogen bond relaxation and polarization. J. Raman Spectrosc. 47(11), 1351–1359
(2016)
38. S. Park, D.E. Moilanen, M.D. Fayer, Water Dynamics: The Effects of Ions and Nanoconfinement. J. Phys. Chem. B 112(17), 5279–5290 (2008)
39. C.Q. Sun, Supersolidity of the undercoordinated and the hydrating water (Perspective). Phys.
Chem. Chem. Phys. 20, 30104–30119 (2018)
40. T.F. Kahan, J.P. Reid, D.J. Donaldson, Spectroscopic probes of the quasi-liquid layer on ice. J.
Phys. Chem. A 111(43), 11006–11012 (2007)
41. Y. Zhou, Y. Zhong, X. Liu, Y. Huang, X. Zhang, C.Q. Sun, NaX solvation bonding dynamics:
hydrogen bond and surface stress transition (X = HSO4, NO3, ClO4, SCN). J. Mol. Liq. 248,
432–438 (2017)