20.5 Motivation and Objectives
387
we will be focused on formulating the Raman shifts in terms of the order, length and
strength of the representative bond of the entire specimen and their response to the
applied stimuli.
Agreement between the theory predictions and the measurements has led to consistent insight into the mechanism behind the fascinations with revelation of the
information. The information includes the referential frequency ω(1) and its bulk
shift, binding energy E b , atomic cohesive energy E coh , binding energy density E den ,
Debye temperature θ D , elastic modulus B, force constant k, compressibility β, and
the effective atomic CN for the few-layer graphene and WX 2 and their bond lengths
and energies.
References
1. C.Q. Sun, Oxidation electronics: bond-band-barrier correlation and its applications. Prog.
Mater Sci. 48(6), 521–685 (2003)
2. C. Liu, F. Yun, H. Morkoc, Ferromagnetism of ZnO and GaN: a review. J Mater. Sci. Mater.
Electron. 16(9), 555–597 (2005)
3. J.W. Li, X.J. Liu, L.W. Yang, Z.F. Zhou, G.F. Xie, Y. Pan, X.H. Wang, J. Zhou, L.T. Li, L.K.
Pan, Z. Sun, C.Q. Sun, Photoluminescence and photoabsorption blueshift of nanostructured
ZnO: skin-depth quantum trapping and electron-phonon coupling. Appl. Phys. Lett. 95(3),
3184566 (2009)
4. G.W. Shim, K. Yoo, S.-B. Seo, J. Shin, D.Y. Jung, I.-S. Kang, C.W. Ahn, B.J. Cho, S.-Y.
Choi, Large-area single-layer MoSe 2 and its van der Waals heterostructures. ACS Nano 8(7),
6655–6662 (2014)
5. C. Tan, X. Cao, X.-J. Wu, Q. He, J. Yang, X. Zhang, J. Chen, W. Zhao, S. Han, G.-H. Nam,
Recent advances in ultrathin two-dimensional nanomaterials. Chem. Rev. 117(9), 6225–6331
(2017)
6. X.J. Liu, M.L. Bo, X. Zhang, L. Li, Y.G. Nie, H. Tian, Y. Sun, S. Xu, Y. Wang, W. Zheng,
C.Q. Sun, Coordination-resolved electron spectrometrics. Chem. Rev. 115(14), 6746–6810
(2015)
7. C.Q. Sun, Y. Sun, Y.G. Ni, X. Zhang, J.S. Pan, X.H. Wang, J. Zhou, L.T. Li, W.T. Zheng,
S.S. Yu, L.K. Pan, Z. Sun, coulomb repulsion at the nanometer-sized contact: a force driving superhydrophobicity, superfluidity, superlubricity, and supersolidity. J. Phys. Chem. C
113(46), 20009–20019 (2009)
8. M.C. Daniel, D. Astruc, Gold nanoparticles: assembly, supramolecular chemistry, quantumsize-related properties, and applications toward biology, catalysis, and nanotechnology. Chem.
Rev. 104(1), 293–346 (2004)
9. C.Q. Sun, Size dependence of nanostructures: impact of bond order deficiency. Prog. Solid
State Chem. 35(1), 1–159 (2007)
10. J.R. Trelewicz, C.A. Schuh, The Hall-Petch breakdown at high strain rates: optimizing
nanocrystalline grain size for impact applications. Appl. Phys. Lett. 93(17), 171916 (2008)
11. C.Q. Sun, W.H. Zhong, S. Li, B.K. Tay, H.L. Bai, E.Y. Jiang, Coordination imperfection
suppressed phase stability of ferromagnetic, ferroelectric, and superconductive nanosolids. J.
Phys. Chem. B 108(3), 1080–1084 (2004)
12. Y.J. Tian, B. Xu, D.L. Yu, Y.M. Ma, Y.B. Wang, Y.B. Jiang, W.T. Hu, C.C. Tang, Y.F. Gao, K.
Luo, Z.S. Zhao, L.M. Wang, B. Wen, J.L. He, Z.Y. Liu, Ultrahard nanotwinned cubic boron
nitride. Nature 493(7432), 385–388 (2013)
13. Y. Wang, Y. Pu, Z. Ma, Y. Pan, C.Q. Sun, Interfacial adhesion energy of lithium-ion battery
electrodes. Extreme Mech. Lett. 9, 226–236 (2016)
387
we will be focused on formulating the Raman shifts in terms of the order, length and
strength of the representative bond of the entire specimen and their response to the
applied stimuli.
Agreement between the theory predictions and the measurements has led to consistent insight into the mechanism behind the fascinations with revelation of the
information. The information includes the referential frequency ω(1) and its bulk
shift, binding energy E b , atomic cohesive energy E coh , binding energy density E den ,
Debye temperature θ D , elastic modulus B, force constant k, compressibility β, and
the effective atomic CN for the few-layer graphene and WX 2 and their bond lengths
and energies.
References
1. C.Q. Sun, Oxidation electronics: bond-band-barrier correlation and its applications. Prog.
Mater Sci. 48(6), 521–685 (2003)
2. C. Liu, F. Yun, H. Morkoc, Ferromagnetism of ZnO and GaN: a review. J Mater. Sci. Mater.
Electron. 16(9), 555–597 (2005)
3. J.W. Li, X.J. Liu, L.W. Yang, Z.F. Zhou, G.F. Xie, Y. Pan, X.H. Wang, J. Zhou, L.T. Li, L.K.
Pan, Z. Sun, C.Q. Sun, Photoluminescence and photoabsorption blueshift of nanostructured
ZnO: skin-depth quantum trapping and electron-phonon coupling. Appl. Phys. Lett. 95(3),
3184566 (2009)
4. G.W. Shim, K. Yoo, S.-B. Seo, J. Shin, D.Y. Jung, I.-S. Kang, C.W. Ahn, B.J. Cho, S.-Y.
Choi, Large-area single-layer MoSe 2 and its van der Waals heterostructures. ACS Nano 8(7),
6655–6662 (2014)
5. C. Tan, X. Cao, X.-J. Wu, Q. He, J. Yang, X. Zhang, J. Chen, W. Zhao, S. Han, G.-H. Nam,
Recent advances in ultrathin two-dimensional nanomaterials. Chem. Rev. 117(9), 6225–6331
(2017)
6. X.J. Liu, M.L. Bo, X. Zhang, L. Li, Y.G. Nie, H. Tian, Y. Sun, S. Xu, Y. Wang, W. Zheng,
C.Q. Sun, Coordination-resolved electron spectrometrics. Chem. Rev. 115(14), 6746–6810
(2015)
7. C.Q. Sun, Y. Sun, Y.G. Ni, X. Zhang, J.S. Pan, X.H. Wang, J. Zhou, L.T. Li, W.T. Zheng,
S.S. Yu, L.K. Pan, Z. Sun, coulomb repulsion at the nanometer-sized contact: a force driving superhydrophobicity, superfluidity, superlubricity, and supersolidity. J. Phys. Chem. C
113(46), 20009–20019 (2009)
8. M.C. Daniel, D. Astruc, Gold nanoparticles: assembly, supramolecular chemistry, quantumsize-related properties, and applications toward biology, catalysis, and nanotechnology. Chem.
Rev. 104(1), 293–346 (2004)
9. C.Q. Sun, Size dependence of nanostructures: impact of bond order deficiency. Prog. Solid
State Chem. 35(1), 1–159 (2007)
10. J.R. Trelewicz, C.A. Schuh, The Hall-Petch breakdown at high strain rates: optimizing
nanocrystalline grain size for impact applications. Appl. Phys. Lett. 93(17), 171916 (2008)
11. C.Q. Sun, W.H. Zhong, S. Li, B.K. Tay, H.L. Bai, E.Y. Jiang, Coordination imperfection
suppressed phase stability of ferromagnetic, ferroelectric, and superconductive nanosolids. J.
Phys. Chem. B 108(3), 1080–1084 (2004)
12. Y.J. Tian, B. Xu, D.L. Yu, Y.M. Ma, Y.B. Wang, Y.B. Jiang, W.T. Hu, C.C. Tang, Y.F. Gao, K.
Luo, Z.S. Zhao, L.M. Wang, B. Wen, J.L. He, Z.Y. Liu, Ultrahard nanotwinned cubic boron
nitride. Nature 493(7432), 385–388 (2013)
13. Y. Wang, Y. Pu, Z. Ma, Y. Pan, C.Q. Sun, Interfacial adhesion energy of lithium-ion battery
electrodes. Extreme Mech. Lett. 9, 226–236 (2016)