40. Bowes KF, Cole JM, Husheer SLG, Raithby PR, Savarese TL, Sparkes HA et al (2006)
Photocrystallographic structure determination of a new geometric isomer of [Ru(NH 3 ) 4 (H 2 O)
(η
1
-OSO)] [MeC 6 H 4 SO 3 ] 2 . Chem Commun:2448–2450
41. Phillips AE, Cole JM, d’Almeida T, Low KS (2010) Effects of the reaction cavity on metastable
optical excitation in ruthenium-sulfur dioxide complexes. Phys Rev B 82:155118
42. Phillips AE, Cole JM, d’Almeida T, Low KS (2012) Ru–OSO coordination photogenerated at
100 K in tetraammineaqua(sulfur dioxide)ruthenium(II) (Æ)-camphorsulfonate. Inorg Chem
51:1204–1206
43. Sylvester SO, Cole JM, Waddell PG (2012) Photoconversion bonding mechanism in ruthenium
sulfur dioxide linkage photoisomers revealed by in situ diffraction. J Am Chem Soc
134:11860–11863
44. Cole JM, Velazquez-Garcia JJ, Gosztola DJ, Wang SG, Chen Y-S (2018) η
2
-SO 2 linkage
photoisomer of an osmium coordination complex. Inorg Chem 57:2673–2677
45. Allen AD, Senoff CV (1965) Nitrogenopentammineruthenium(II) complexes. Chem Commun
(Lond):621–622
46. Tanaka H, Nishibayashi Y, Yoshizawa K (2016) Interplay between theory and experiment for
ammonia synthesis catalyzed by transition metal complexes. Acc Chem Res 49:987–995
47. Nishibayashi Y (2018) Development of catalytic nitrogen fixation using transition metaldinitrogen complexes under mild reaction conditions. Dalton Trans 47:11290–11297
48. Yang Y, Liu J, Wei Z, Wang S, Ma J (2019) Transition metal-dinitrogen complex embedded
graphene for nitrogen reduction reaction. ChemCatChem 11:2821–2827
49. Fomitchev DV, Bagley KA, Coppens P (2000) The first crystallographic evidence for side-on
coordination of N 2 to a single metal center in a photoinduced metastable state. J Am Chem Soc
122:532–533
50. Goulkov M, Schaniel D, Woike T (2010) Pulse recording of thermal and linkage isomer
gratings in nitrosyl compounds. J Opt Soc Am B 27:927–932
51. Sylvester SO, Cole JM (2013) Solar-powered nanomechanical transduction from crystalline
molecular rotors. Adv Mater 25:3324–3328
52. Cole JM, Yeung KYM, Pace G, Sylvester SO, Mersch D, Friend RH (2015) In situ synthesis,
crystallisation, and thin-film processing of single crystals of trans-[Ru(SO 2 )(NH 3 ) 4 (H 2 O)][pTolSO 3 ] 2 bearing SO 2 linkage photo-isomers: towards optical device applications.
CrystEngComm 17:5026–5031
53. Brayshaw SK, Knight JW, Raithby PR, Savarese TL, Schiffers S, Teat SJ et al (2010)
Photocrystallography – design and methodology for the use of a light-emitting diode device.
J Appl Crystallogr 43:337–340
54. Kaminski R, Jarzembska KN, Kutyla SE, Kaminski M (2016) A portable light-delivery device
for in situ photocrystallographic experiments in the home laboratory. J Appl Crystallogr
49:1383–1387
55. Avrami M (1941) Kinetics of phase change. III. Granulation, phase change, and microstructure.
J Chem Phys 9:177–184
56. Avrami M (1940) Kinetics of phase change. II. Transformation-time relations for random
distribution of nuclei. J Chem Phys 8:212–224
57. Avrami M (1939) Kinetics of phase change. I. General theory. J Chem Phys 7:1103–1112
58. Hatcher LE, Christensen J, Hamilton ML, Trincao J, Allan DR, Warren MR et al (2014) Steadystate and pseudo-steady-state photocrystallographic studies on linkage isomers of [Ni(Et 4 dien)
(η
2
-O,ON)(η
1
-NO 2 )]: identification of a new linkage isomer. Chem Eur J 20:3128–3134
59. Hatcher LE, Skelton JM, Warren MR, Stubbs C, da Silva EL, Raithby PR (2018) Monitoring
photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic
kinetic study of [Pd(Bu 4 dien)NO 2 ]BPh 4 . Phys Chem Chem Phys 20:5874–5886
60. Benedict JB, Coppens P (2009) Kinetics of the single-crystal to single-crystal two-photon
photodimerization of α-trans-cinnamic acid to α-truxillic acid. J Phys Chem A 113:3116–3120
Watching Photochemistry Happen: Recent Developments in Dynamic Single-Crystal. . .
237
Photocrystallographic structure determination of a new geometric isomer of [Ru(NH 3 ) 4 (H 2 O)
(η
1
-OSO)] [MeC 6 H 4 SO 3 ] 2 . Chem Commun:2448–2450
41. Phillips AE, Cole JM, d’Almeida T, Low KS (2010) Effects of the reaction cavity on metastable
optical excitation in ruthenium-sulfur dioxide complexes. Phys Rev B 82:155118
42. Phillips AE, Cole JM, d’Almeida T, Low KS (2012) Ru–OSO coordination photogenerated at
100 K in tetraammineaqua(sulfur dioxide)ruthenium(II) (Æ)-camphorsulfonate. Inorg Chem
51:1204–1206
43. Sylvester SO, Cole JM, Waddell PG (2012) Photoconversion bonding mechanism in ruthenium
sulfur dioxide linkage photoisomers revealed by in situ diffraction. J Am Chem Soc
134:11860–11863
44. Cole JM, Velazquez-Garcia JJ, Gosztola DJ, Wang SG, Chen Y-S (2018) η
2
-SO 2 linkage
photoisomer of an osmium coordination complex. Inorg Chem 57:2673–2677
45. Allen AD, Senoff CV (1965) Nitrogenopentammineruthenium(II) complexes. Chem Commun
(Lond):621–622
46. Tanaka H, Nishibayashi Y, Yoshizawa K (2016) Interplay between theory and experiment for
ammonia synthesis catalyzed by transition metal complexes. Acc Chem Res 49:987–995
47. Nishibayashi Y (2018) Development of catalytic nitrogen fixation using transition metaldinitrogen complexes under mild reaction conditions. Dalton Trans 47:11290–11297
48. Yang Y, Liu J, Wei Z, Wang S, Ma J (2019) Transition metal-dinitrogen complex embedded
graphene for nitrogen reduction reaction. ChemCatChem 11:2821–2827
49. Fomitchev DV, Bagley KA, Coppens P (2000) The first crystallographic evidence for side-on
coordination of N 2 to a single metal center in a photoinduced metastable state. J Am Chem Soc
122:532–533
50. Goulkov M, Schaniel D, Woike T (2010) Pulse recording of thermal and linkage isomer
gratings in nitrosyl compounds. J Opt Soc Am B 27:927–932
51. Sylvester SO, Cole JM (2013) Solar-powered nanomechanical transduction from crystalline
molecular rotors. Adv Mater 25:3324–3328
52. Cole JM, Yeung KYM, Pace G, Sylvester SO, Mersch D, Friend RH (2015) In situ synthesis,
crystallisation, and thin-film processing of single crystals of trans-[Ru(SO 2 )(NH 3 ) 4 (H 2 O)][pTolSO 3 ] 2 bearing SO 2 linkage photo-isomers: towards optical device applications.
CrystEngComm 17:5026–5031
53. Brayshaw SK, Knight JW, Raithby PR, Savarese TL, Schiffers S, Teat SJ et al (2010)
Photocrystallography – design and methodology for the use of a light-emitting diode device.
J Appl Crystallogr 43:337–340
54. Kaminski R, Jarzembska KN, Kutyla SE, Kaminski M (2016) A portable light-delivery device
for in situ photocrystallographic experiments in the home laboratory. J Appl Crystallogr
49:1383–1387
55. Avrami M (1941) Kinetics of phase change. III. Granulation, phase change, and microstructure.
J Chem Phys 9:177–184
56. Avrami M (1940) Kinetics of phase change. II. Transformation-time relations for random
distribution of nuclei. J Chem Phys 8:212–224
57. Avrami M (1939) Kinetics of phase change. I. General theory. J Chem Phys 7:1103–1112
58. Hatcher LE, Christensen J, Hamilton ML, Trincao J, Allan DR, Warren MR et al (2014) Steadystate and pseudo-steady-state photocrystallographic studies on linkage isomers of [Ni(Et 4 dien)
(η
2
-O,ON)(η
1
-NO 2 )]: identification of a new linkage isomer. Chem Eur J 20:3128–3134
59. Hatcher LE, Skelton JM, Warren MR, Stubbs C, da Silva EL, Raithby PR (2018) Monitoring
photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic
kinetic study of [Pd(Bu 4 dien)NO 2 ]BPh 4 . Phys Chem Chem Phys 20:5874–5886
60. Benedict JB, Coppens P (2009) Kinetics of the single-crystal to single-crystal two-photon
photodimerization of α-trans-cinnamic acid to α-truxillic acid. J Phys Chem A 113:3116–3120
Watching Photochemistry Happen: Recent Developments in Dynamic Single-Crystal. . .
237