180. Zhang C, Gee JA, Sholl DS, Lively RP (2014) Crystal-size-dependent structural transitions in
nanoporous crystals: adsorption-induced transitions in ZIF-8. J Phys Chem C
118:20727–20733
181. Hobday CL, Woodall CH, Lennox MJ, Frost M, Kamenev K, Düren T, Morrison CA,
Moggach SA (2018) Understanding the adsorption process in ZIF-8 using high pressure
crystallography and computational modelling. Nat Commun 9:1429
182. Chapman KW, Halder GJ, Chupas PJ (2008) Guest-dependent high pressure phenomena in a
nanoporous metalÀorganic framework material. J Am Chem Soc 130:10524–10526
183. Graham AJ, Tan J-C, Allan DR, Moggach SA (2012) The effect of pressure on Cu-btc:
framework compression vs. guest inclusion. Chem Commun 48:1535–1537
184. Graham AJ, Allan DR, Muszkiewicz A, Morrison CA, Moggach SA (2011) The effect of high
pressure on MOF-5: guest-induced modification of pore size and content at high pressure.
Angew Chem Int Ed 50:11138–11141
185. Graham AJ, Banu A-M, Düren T, Greenaway A, McKellar SC, Mowat JPS, Ward K, Wright
PA, Moggach SA (2014) Stabilization of scandium terephthalate MOFs against reversible
amorphization and structural phase transition by guest uptake at extreme pressure. J Am Chem
Soc 136:8606–8613
186. Aguado S, Bergeret G, Titus MP, Moizan V, Nieto-Draghi C, Bats N, Farrusseng D (2011)
Guest-induced gate-opening of a zeolite imidazolate framework. New J Chem 35:546–550
187. Yot PG, Ma Q, Haines J et al (2012) Large breathing of the MOF MIL-47(VIV) under
mechanical pressure: a joint experimental–modelling exploration. Chem Sci 3:1100–1104
188. Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud KP (2008) A
new zirconium inorganic building brick forming metal organic frameworks with exceptional
stability. J Am Chem Soc 130:13850–13851
189. Su Z, Miao Y-R, Zhang G, Miller JT, Suslick KS (2017) Bond breakage under pressure in a
metal organic framework. Chem Sci 8:8004–8011
190. Hobday CL, Marshall RJ, Murphie CF et al (2016) A computational and experimental
approach linking disorder, high-pressure behavior, and mechanical properties in UiO frameworks. Angew Chem Int Ed 55:2401–2405
191. Rogge SMJ, Wieme J, Vanduyfhuys L, Vandenbrande S, Maurin G, Verstraelen T,
Waroquier M, Van Speybroeck V (2016) Thermodynamic insight in the high-pressure behavior of UiO-66: effect of linker defects and linker expansion. Chem Mater 28:5721–5732
192. Yot PG, Yang K, Ragon F, Dmitriev V, Devic T, Horcajada P, Serre C, Maurin G (2016)
Exploration of the mechanical behavior of metal organic frameworks UiO-66(Zr) and
MIL-125(Ti) and their NH2 functionalized versions. Dalt Trans 45:4283–4288
193. Bennett TD, Tan J-C, Moggach SA, Galvelis R, Mellot-Draznieks C, Reisner BA,
Thirumurugan A, Allan DR, Cheetham AK (2010) Mechanical properties of dense zeolitic
imidazolate frameworks (ZIFs): a high-pressure X-ray diffraction, nanoindentation and computational study of the zinc framework Zn(Im)2, and its lithium boron analogue, LiB(Im)4.
Chem Eur J 16:10684–10690
194. Dissegna S, Vervoorts P, Hobday CL, Düren T, Daisenberger D, Smith AJ, Fischer RA,
Kieslich G (2018) Tuning the mechanical response of metal–organic frameworks by defect
engineering. J Am Chem Soc 140:11581–11584
195. Wu H, Yildirim T, Zhou W (2013) Exceptional mechanical stability of highly porous
zirconium metal–organic framework UiO-66 and its important implications. J Phys Chem
Lett 4:925–930
196. Peterson GW, DeCoste JB, Glover TG, Huang Y, Jasuja H, Walton KS (2013) Effects of
pelletization pressure on the physical and chemical properties of the metal–organic frameworks Cu3(BTC)2 and UiO-66. Microporous Mesoporous Mater 179:48–53
197. Peterson GW, DeCoste JB, Fatollahi-Fard F, Britt DK (2014) Engineering UiO-66-NH2 for
toxic gas removal. Ind Eng Chem Res 53:701–707
198
S. A. Moggach and I. D. H. Oswald
nanoporous crystals: adsorption-induced transitions in ZIF-8. J Phys Chem C
118:20727–20733
181. Hobday CL, Woodall CH, Lennox MJ, Frost M, Kamenev K, Düren T, Morrison CA,
Moggach SA (2018) Understanding the adsorption process in ZIF-8 using high pressure
crystallography and computational modelling. Nat Commun 9:1429
182. Chapman KW, Halder GJ, Chupas PJ (2008) Guest-dependent high pressure phenomena in a
nanoporous metalÀorganic framework material. J Am Chem Soc 130:10524–10526
183. Graham AJ, Tan J-C, Allan DR, Moggach SA (2012) The effect of pressure on Cu-btc:
framework compression vs. guest inclusion. Chem Commun 48:1535–1537
184. Graham AJ, Allan DR, Muszkiewicz A, Morrison CA, Moggach SA (2011) The effect of high
pressure on MOF-5: guest-induced modification of pore size and content at high pressure.
Angew Chem Int Ed 50:11138–11141
185. Graham AJ, Banu A-M, Düren T, Greenaway A, McKellar SC, Mowat JPS, Ward K, Wright
PA, Moggach SA (2014) Stabilization of scandium terephthalate MOFs against reversible
amorphization and structural phase transition by guest uptake at extreme pressure. J Am Chem
Soc 136:8606–8613
186. Aguado S, Bergeret G, Titus MP, Moizan V, Nieto-Draghi C, Bats N, Farrusseng D (2011)
Guest-induced gate-opening of a zeolite imidazolate framework. New J Chem 35:546–550
187. Yot PG, Ma Q, Haines J et al (2012) Large breathing of the MOF MIL-47(VIV) under
mechanical pressure: a joint experimental–modelling exploration. Chem Sci 3:1100–1104
188. Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud KP (2008) A
new zirconium inorganic building brick forming metal organic frameworks with exceptional
stability. J Am Chem Soc 130:13850–13851
189. Su Z, Miao Y-R, Zhang G, Miller JT, Suslick KS (2017) Bond breakage under pressure in a
metal organic framework. Chem Sci 8:8004–8011
190. Hobday CL, Marshall RJ, Murphie CF et al (2016) A computational and experimental
approach linking disorder, high-pressure behavior, and mechanical properties in UiO frameworks. Angew Chem Int Ed 55:2401–2405
191. Rogge SMJ, Wieme J, Vanduyfhuys L, Vandenbrande S, Maurin G, Verstraelen T,
Waroquier M, Van Speybroeck V (2016) Thermodynamic insight in the high-pressure behavior of UiO-66: effect of linker defects and linker expansion. Chem Mater 28:5721–5732
192. Yot PG, Yang K, Ragon F, Dmitriev V, Devic T, Horcajada P, Serre C, Maurin G (2016)
Exploration of the mechanical behavior of metal organic frameworks UiO-66(Zr) and
MIL-125(Ti) and their NH2 functionalized versions. Dalt Trans 45:4283–4288
193. Bennett TD, Tan J-C, Moggach SA, Galvelis R, Mellot-Draznieks C, Reisner BA,
Thirumurugan A, Allan DR, Cheetham AK (2010) Mechanical properties of dense zeolitic
imidazolate frameworks (ZIFs): a high-pressure X-ray diffraction, nanoindentation and computational study of the zinc framework Zn(Im)2, and its lithium boron analogue, LiB(Im)4.
Chem Eur J 16:10684–10690
194. Dissegna S, Vervoorts P, Hobday CL, Düren T, Daisenberger D, Smith AJ, Fischer RA,
Kieslich G (2018) Tuning the mechanical response of metal–organic frameworks by defect
engineering. J Am Chem Soc 140:11581–11584
195. Wu H, Yildirim T, Zhou W (2013) Exceptional mechanical stability of highly porous
zirconium metal–organic framework UiO-66 and its important implications. J Phys Chem
Lett 4:925–930
196. Peterson GW, DeCoste JB, Glover TG, Huang Y, Jasuja H, Walton KS (2013) Effects of
pelletization pressure on the physical and chemical properties of the metal–organic frameworks Cu3(BTC)2 and UiO-66. Microporous Mesoporous Mater 179:48–53
197. Peterson GW, DeCoste JB, Fatollahi-Fard F, Britt DK (2014) Engineering UiO-66-NH2 for
toxic gas removal. Ind Eng Chem Res 53:701–707
198
S. A. Moggach and I. D. H. Oswald