1 3
Topics in Current Chemistry (2020) 378:1
81. Gualandi A, Mengozzi L, Wilson CM (2014) Synergy, compatibility, and innovation: merging
Lewis acids with stereoselective enamine catalysis. Asia J Org Chem 3:984–995
82. Kemp B, Hampel N, Ofial AR, Mayr H (2003) Structure-nucleophilicity relationships for enamines. Chem Eur J 9:2209–2218
83. Cozzi PG, Benfatti F, Zoli L (2009) Organocatalytic asymmetric alkylation of aldehydes by SN1type reaction of alcohols. Angew Chem Int Ed 48:1313–1316
84. Guiteras Capdevila M, Benfatti F, Zoli L, Stenta M, Cozzi PG (2010) Merging organocatalysis
with an indium(III)-mediated process: a stereoselective α-alkylation of aldehydes with allylic alcohols. Chem Eur J 16(37):11237–11241
85. Sinisi R, Vita MV, Gualandi A, Emer E, Cozzi PG (2011) SN1-type reactions in the presence of
water: indium(III)-promoted highly enantioselective organocatalytic propargylation of aldehydes.
Chem Eur J 17(27):7404–7408
86. Motoyama K, Ikeda M, Miyake Y, Nishibayashi Y (2011) Cooperative catalytic reactions using
Lewis acids and organocatalysts: enantioselective propargylic alkylation of propargylic alcohols
bearing an internal alkyne with aldehydes. Eur J Org Chem 12:2239–2246
87. Guiteras Capdevila M, Emer E, Benfatti F, Gualandi A, Wilson CM, Cozzi PG (2012) Indium(III)promoted organocatalytic enantioselective α-alkylation of aldehydes with benzylic and benzhydrylic alcohols. Asian J Org Chem 1(1):38–42
88. Xiao J (2012) Merging organocatalysis with transition metal catalysis: highly stereoselective
α-alkylation of aldehydes. Org Lett 14(7):1716–1719
89. Rueping M, Volla CMR, Atodiresei I (2012) Catalytic asymmetric addition of aldehydes to oxocarbenium ions: a dual catalytic system for the synthesis of chromenes. Org Lett 14(17):4642–4645
90. Bentley KW (1965) The isoquinoline alkaloids, 1st edn. Pergamon, London, p 1965
91. Michael JP (1995) Quinoline, quinazoline, and acridone alkaloids. Nat Prod Rep 12(1):77–89
92. Frisch K, Landa A, Saaby S, Jørgensen KA (2005) Organocatalytic diastereo- and enantioselective
annulation reactions—construction of optically active 1,2-dihydroisoquinoline and 1,2-dihydrophthalazine derivatives. Angew Chem Int Ed 44(37):6058–6063
93. Mengozzi L, Gualandi A, Cozzi PG (2014) A highly enantioselective acyl-Mannich reaction of
isoquinolines with aldehydes promoted by proline derivatives: an approach to 13-alkyl-tetrahydroprotoberberine alkaloids. Chem Sci 5(10):3915–3921
94. Sun S, Mao Y, Lou H, Liu L (2015) Copper(II)/amine synergistically catalyzed enantioselective
alkylation of cyclic N-acyl hemiaminals with aldehydes. Chem Commun 51(53):19691–19694
95. Berti F, Malossi F, Pineschi M (2015) A highly enantioselective Mannich reaction of aldehydes
with cyclic N-acyliminium ions by synergistic catalysis. Chem Commun 51(71):13694–13697
96. Hashmi ASK, Hutchings GJ (2006) Gold catalysis. Angew Chem Int Ed 45(47):7896–7936
97. Fürstner A, Davies PW (2007) Catalytic carbophilic activation: catalysis by platinum and gold
π-acids. Angew Chem Int Ed 46(19):3410–3449
98. Hashmi ASK (2007) Gold-catalyzed organic reactions. Chem Rev 107(7):3180–3211
99. Jiménez-Núñez E, Echavarren AM (2008) Gold-catalyzed cycloisomerizations of enynes: a mechanistic perspective. Chem Rev 108(8):3326–3350
100. Li ZG, Brouwer C, He C (2008) Gold-catalyzed organic transformations. Chem Rev
108(8):3239–3265
101. Fürstner A (2009) Chem Soc Rev 38:3208–3221
102. Binder JT, Crone B, Haug TT, Menz H, Kirsch SF (2008) Direct carbocyclization of aldehydes
with alkynes: combining gold catalysis with aminocatalysis. Org Lett 10(5):1025–1028
103. Jensen KL, Franke PT, Arrniz C, Kobbelgaard S, Jørgensen KA (2010) Enantioselective synthesis of cyclopentene carbaldehydes by a direct multicatalytic cascade sequence: carbocyclization of
aldehydes with alkynes. Chem Eur J 16(6):1750–1753
104. Vachan BS, Karuppasamy M, Vinoth P, Vivek Kumar S, Perumal S, Vellaisamy S, Menéndez
JC (2019) Proline and its derivatives as organocatalysts for multicomponent reactions in aqueous media: synergic pathways to the green synthesis of heterocycles. Adv Synth Cat. https ://doi.
org/10.1002/adsc.20190 0558
105. Marson CM (2012) Multicomponent and sequential organocatalytic reactions: diversity with atomeconomy and enantiocontrol. Chem Soc Rev 41(23):7712–7722
106. Herrera RP, Marqués-López E (2015) Multicomponent reactions: concepts and applications for
design and synthesis. Wiley, New York
Reprinted from the journal
63
Topics in Current Chemistry (2020) 378:1
81. Gualandi A, Mengozzi L, Wilson CM (2014) Synergy, compatibility, and innovation: merging
Lewis acids with stereoselective enamine catalysis. Asia J Org Chem 3:984–995
82. Kemp B, Hampel N, Ofial AR, Mayr H (2003) Structure-nucleophilicity relationships for enamines. Chem Eur J 9:2209–2218
83. Cozzi PG, Benfatti F, Zoli L (2009) Organocatalytic asymmetric alkylation of aldehydes by SN1type reaction of alcohols. Angew Chem Int Ed 48:1313–1316
84. Guiteras Capdevila M, Benfatti F, Zoli L, Stenta M, Cozzi PG (2010) Merging organocatalysis
with an indium(III)-mediated process: a stereoselective α-alkylation of aldehydes with allylic alcohols. Chem Eur J 16(37):11237–11241
85. Sinisi R, Vita MV, Gualandi A, Emer E, Cozzi PG (2011) SN1-type reactions in the presence of
water: indium(III)-promoted highly enantioselective organocatalytic propargylation of aldehydes.
Chem Eur J 17(27):7404–7408
86. Motoyama K, Ikeda M, Miyake Y, Nishibayashi Y (2011) Cooperative catalytic reactions using
Lewis acids and organocatalysts: enantioselective propargylic alkylation of propargylic alcohols
bearing an internal alkyne with aldehydes. Eur J Org Chem 12:2239–2246
87. Guiteras Capdevila M, Emer E, Benfatti F, Gualandi A, Wilson CM, Cozzi PG (2012) Indium(III)promoted organocatalytic enantioselective α-alkylation of aldehydes with benzylic and benzhydrylic alcohols. Asian J Org Chem 1(1):38–42
88. Xiao J (2012) Merging organocatalysis with transition metal catalysis: highly stereoselective
α-alkylation of aldehydes. Org Lett 14(7):1716–1719
89. Rueping M, Volla CMR, Atodiresei I (2012) Catalytic asymmetric addition of aldehydes to oxocarbenium ions: a dual catalytic system for the synthesis of chromenes. Org Lett 14(17):4642–4645
90. Bentley KW (1965) The isoquinoline alkaloids, 1st edn. Pergamon, London, p 1965
91. Michael JP (1995) Quinoline, quinazoline, and acridone alkaloids. Nat Prod Rep 12(1):77–89
92. Frisch K, Landa A, Saaby S, Jørgensen KA (2005) Organocatalytic diastereo- and enantioselective
annulation reactions—construction of optically active 1,2-dihydroisoquinoline and 1,2-dihydrophthalazine derivatives. Angew Chem Int Ed 44(37):6058–6063
93. Mengozzi L, Gualandi A, Cozzi PG (2014) A highly enantioselective acyl-Mannich reaction of
isoquinolines with aldehydes promoted by proline derivatives: an approach to 13-alkyl-tetrahydroprotoberberine alkaloids. Chem Sci 5(10):3915–3921
94. Sun S, Mao Y, Lou H, Liu L (2015) Copper(II)/amine synergistically catalyzed enantioselective
alkylation of cyclic N-acyl hemiaminals with aldehydes. Chem Commun 51(53):19691–19694
95. Berti F, Malossi F, Pineschi M (2015) A highly enantioselective Mannich reaction of aldehydes
with cyclic N-acyliminium ions by synergistic catalysis. Chem Commun 51(71):13694–13697
96. Hashmi ASK, Hutchings GJ (2006) Gold catalysis. Angew Chem Int Ed 45(47):7896–7936
97. Fürstner A, Davies PW (2007) Catalytic carbophilic activation: catalysis by platinum and gold
π-acids. Angew Chem Int Ed 46(19):3410–3449
98. Hashmi ASK (2007) Gold-catalyzed organic reactions. Chem Rev 107(7):3180–3211
99. Jiménez-Núñez E, Echavarren AM (2008) Gold-catalyzed cycloisomerizations of enynes: a mechanistic perspective. Chem Rev 108(8):3326–3350
100. Li ZG, Brouwer C, He C (2008) Gold-catalyzed organic transformations. Chem Rev
108(8):3239–3265
101. Fürstner A (2009) Chem Soc Rev 38:3208–3221
102. Binder JT, Crone B, Haug TT, Menz H, Kirsch SF (2008) Direct carbocyclization of aldehydes
with alkynes: combining gold catalysis with aminocatalysis. Org Lett 10(5):1025–1028
103. Jensen KL, Franke PT, Arrniz C, Kobbelgaard S, Jørgensen KA (2010) Enantioselective synthesis of cyclopentene carbaldehydes by a direct multicatalytic cascade sequence: carbocyclization of
aldehydes with alkynes. Chem Eur J 16(6):1750–1753
104. Vachan BS, Karuppasamy M, Vinoth P, Vivek Kumar S, Perumal S, Vellaisamy S, Menéndez
JC (2019) Proline and its derivatives as organocatalysts for multicomponent reactions in aqueous media: synergic pathways to the green synthesis of heterocycles. Adv Synth Cat. https ://doi.
org/10.1002/adsc.20190 0558
105. Marson CM (2012) Multicomponent and sequential organocatalytic reactions: diversity with atomeconomy and enantiocontrol. Chem Soc Rev 41(23):7712–7722
106. Herrera RP, Marqués-López E (2015) Multicomponent reactions: concepts and applications for
design and synthesis. Wiley, New York
Reprinted from the journal
63