1 3
Topics in Current Chemistry (2019) 377:38
57. Yoshida A, Ikeda M, Hattori G, Miyake Y, Nishibayashi Y (2011) Cooperative catalytic reactions
using organocatalysts and transition metal catalysts: enantioselective propargylic alkylation of propargylic esters with aldehydes. Org Lett 13(4):592–595
58. Belot S, Vogt KA, Besnard C, Krause N, Alexakis A (2009) Enantioselective one pot organocatalytic Michael addition/gold-catalyzed tandem acetalization/cyclization. Angew Chem Int Ed
48(47):8923–8926
59. Wang Z, Li X, Huang Y (2013) Direct α-vinylidenation of aldehydes and subsequent cascade: gold
and amine catalysts work synergistically. Angew Chem Int Ed 52(52):14219–14223
60. Mo F, Lim HN, Dong G (2015) Bifunctional ligand-assisted catalytic ketone α-alkenylation
with internal alkynes: controlled synthesis of enones and mechanistic studies. J Am Chem Soc
137(49):15518–15527
61. Su Y-L, Li L-L, Zhou X-L, Dai Z-Y, Wang P-S, Gong L-Z (2018) Asymmetric α-allylation of
aldehydes with alkynes by integrating chiral hydridopalladium and enamine catalysis. Org Lett
20(8):2403–2406
62. Gómez-Bengoa E, García JM, Jiménez S, Lapuerta I, Mielgo A, Odriozola JM, Otazo I, Razkin J,
Urruzuno I, Vera S, Oiarbide M, Palomo C (2013) Asymmetric synthesis of propargylic alcohols
via aldol reaction of aldehydes with ynals promoted by prolinol ether-transition metal-Brønsted
acid cooperative catalysis. Chem Sci 4:3198–3204
63. Dong Z, Ren Z, Thompson SJ, Xu Y, Dong G (2017) Transition-metal-catalyzed CH alkylation
using alkenes. Chem Rev 117(13):9333–9403
64. Wang Z, Reinus BJ, Dong G (2012) Catalytic intermolecular C-alkylation of 1,2 diketones with
simple olefins: a recyclable directing group strategy. J Am Chem Soc 134(34):13954–13957
65. Mo F, Dong G (2014) Regioselective ketone α-alkylation with simple olefins via dual activation.
Science 345(6192):68–72
66. Xing D, Qi X, Marchant D, Liu P, Dong G (2019) Branched-selective direct α-alkylation of cyclic
ketones with simple alkenes. Angew Chem 131(13):4410–4414
67. Qurban S, Gong J, Du Y, Kang Q (2018) Rhodium(III)/amine synergistically catalyzed enantioselective Michael addition of cyclic ketones with α, β-unsaturated 2-acyl imidazoles. Org Chem
Front 5:2870–2874
68. Wang PS, Lin HC, Zhai YJ, Han ZY, Gong LZ (2014) Chiral Counteranion strategy for asymmetric oxidative C(sp3)-H/C(sp3)-H coupling: enantioselective α-allylation of aldehydes with terminal
alkenes. Angew Chem Int Ed 53(45):12218–12221
69. Shen H-C, Zhang L, Chen S-S, Feng J, Zhang B-W, Zhang Y, Zhang X, Wu Y-D, Gong L-Z (2019)
Enantioselective addition of cyclic ketones to unactivated alkenes enabled by amine/Pd(II) cooperative catalysis. ACS Catal 9(2):791–797
70. Tang S, Wu X, Liao W, Liu K, Liu C, Luo S, Lei A (2014) Synergistic Pd/enamine catalysis:
a strategy for the C–H/C–H oxidative coupling of allylarenes with unactivated ketones. Org Lett
16(13):3584–3587
71. Yang T, Ferrali A, Campbell L, Dixon DJ (2008) Combination iminium, enamine and copper(I)
cascade catalysis: a carboannulation for the synthesis of cyclopentenes. Chem Commun
25:2923–2925
72. Sun W, Zhu G, Hong L, Wang R (2011) The marriage of organocatalysis with metal catalysis:
access to multisubstituted chiral 2,5-dihydropyrroles by cascade iminium/enamine-metal cooperative catalysis. Chem Eur J 17(50):13958–13962
73. Zhao GL, Ullah F, Deiana L, Lin S, Zhang Q, Sun J, Ibrahem I, Dziedzic P, Córdova A (2010)
Dynamic kinetic asymmetric transformation (DYKAT) by combined amine- and transition-metalcatalyzed enantioselective cycloisomerization. Chem Eur J 16(5):1585–1591
74. Lin S, Zhao GL, Deiana L, Sun J, Zhang Q, Leijonmarck H, Cordova A (2010) Dynamic kinetic
asymmetric domino oxa-Michael/carbocyclization by combination of transition-metal and amine
catalysis: catalytic enantioselective synthesis of dihydrofurans. Chem Eur J 16(47):13930–13934
75. Deiana L, Afewerki S, Palo-Nieto C, Verho O, Johnston EV, Córdova A (2012) Highly enantioselective cascade transformations by merging heterogeneous transition metal catalysis with asymmetric aminocatalysis. Sci Rep 2:851
76. Deiana L, Jiang Y, Palo-Nieto C, Afewerki S, Incerti-Pradillos CA, Verho O, Tai CW, Johnston
EV, Córdova A (2014) Combined heterogeneous metal/chiral amine: multiple relay catalysis for
versatile eco-friendly synthesis. Angew Chem Int Ed 53(13):3447–3451
Reprinted from the journal
25
Topics in Current Chemistry (2019) 377:38
57. Yoshida A, Ikeda M, Hattori G, Miyake Y, Nishibayashi Y (2011) Cooperative catalytic reactions
using organocatalysts and transition metal catalysts: enantioselective propargylic alkylation of propargylic esters with aldehydes. Org Lett 13(4):592–595
58. Belot S, Vogt KA, Besnard C, Krause N, Alexakis A (2009) Enantioselective one pot organocatalytic Michael addition/gold-catalyzed tandem acetalization/cyclization. Angew Chem Int Ed
48(47):8923–8926
59. Wang Z, Li X, Huang Y (2013) Direct α-vinylidenation of aldehydes and subsequent cascade: gold
and amine catalysts work synergistically. Angew Chem Int Ed 52(52):14219–14223
60. Mo F, Lim HN, Dong G (2015) Bifunctional ligand-assisted catalytic ketone α-alkenylation
with internal alkynes: controlled synthesis of enones and mechanistic studies. J Am Chem Soc
137(49):15518–15527
61. Su Y-L, Li L-L, Zhou X-L, Dai Z-Y, Wang P-S, Gong L-Z (2018) Asymmetric α-allylation of
aldehydes with alkynes by integrating chiral hydridopalladium and enamine catalysis. Org Lett
20(8):2403–2406
62. Gómez-Bengoa E, García JM, Jiménez S, Lapuerta I, Mielgo A, Odriozola JM, Otazo I, Razkin J,
Urruzuno I, Vera S, Oiarbide M, Palomo C (2013) Asymmetric synthesis of propargylic alcohols
via aldol reaction of aldehydes with ynals promoted by prolinol ether-transition metal-Brønsted
acid cooperative catalysis. Chem Sci 4:3198–3204
63. Dong Z, Ren Z, Thompson SJ, Xu Y, Dong G (2017) Transition-metal-catalyzed CH alkylation
using alkenes. Chem Rev 117(13):9333–9403
64. Wang Z, Reinus BJ, Dong G (2012) Catalytic intermolecular C-alkylation of 1,2 diketones with
simple olefins: a recyclable directing group strategy. J Am Chem Soc 134(34):13954–13957
65. Mo F, Dong G (2014) Regioselective ketone α-alkylation with simple olefins via dual activation.
Science 345(6192):68–72
66. Xing D, Qi X, Marchant D, Liu P, Dong G (2019) Branched-selective direct α-alkylation of cyclic
ketones with simple alkenes. Angew Chem 131(13):4410–4414
67. Qurban S, Gong J, Du Y, Kang Q (2018) Rhodium(III)/amine synergistically catalyzed enantioselective Michael addition of cyclic ketones with α, β-unsaturated 2-acyl imidazoles. Org Chem
Front 5:2870–2874
68. Wang PS, Lin HC, Zhai YJ, Han ZY, Gong LZ (2014) Chiral Counteranion strategy for asymmetric oxidative C(sp3)-H/C(sp3)-H coupling: enantioselective α-allylation of aldehydes with terminal
alkenes. Angew Chem Int Ed 53(45):12218–12221
69. Shen H-C, Zhang L, Chen S-S, Feng J, Zhang B-W, Zhang Y, Zhang X, Wu Y-D, Gong L-Z (2019)
Enantioselective addition of cyclic ketones to unactivated alkenes enabled by amine/Pd(II) cooperative catalysis. ACS Catal 9(2):791–797
70. Tang S, Wu X, Liao W, Liu K, Liu C, Luo S, Lei A (2014) Synergistic Pd/enamine catalysis:
a strategy for the C–H/C–H oxidative coupling of allylarenes with unactivated ketones. Org Lett
16(13):3584–3587
71. Yang T, Ferrali A, Campbell L, Dixon DJ (2008) Combination iminium, enamine and copper(I)
cascade catalysis: a carboannulation for the synthesis of cyclopentenes. Chem Commun
25:2923–2925
72. Sun W, Zhu G, Hong L, Wang R (2011) The marriage of organocatalysis with metal catalysis:
access to multisubstituted chiral 2,5-dihydropyrroles by cascade iminium/enamine-metal cooperative catalysis. Chem Eur J 17(50):13958–13962
73. Zhao GL, Ullah F, Deiana L, Lin S, Zhang Q, Sun J, Ibrahem I, Dziedzic P, Córdova A (2010)
Dynamic kinetic asymmetric transformation (DYKAT) by combined amine- and transition-metalcatalyzed enantioselective cycloisomerization. Chem Eur J 16(5):1585–1591
74. Lin S, Zhao GL, Deiana L, Sun J, Zhang Q, Leijonmarck H, Cordova A (2010) Dynamic kinetic
asymmetric domino oxa-Michael/carbocyclization by combination of transition-metal and amine
catalysis: catalytic enantioselective synthesis of dihydrofurans. Chem Eur J 16(47):13930–13934
75. Deiana L, Afewerki S, Palo-Nieto C, Verho O, Johnston EV, Córdova A (2012) Highly enantioselective cascade transformations by merging heterogeneous transition metal catalysis with asymmetric aminocatalysis. Sci Rep 2:851
76. Deiana L, Jiang Y, Palo-Nieto C, Afewerki S, Incerti-Pradillos CA, Verho O, Tai CW, Johnston
EV, Córdova A (2014) Combined heterogeneous metal/chiral amine: multiple relay catalysis for
versatile eco-friendly synthesis. Angew Chem Int Ed 53(13):3447–3451
Reprinted from the journal
25