1 3
Topics in Current Chemistry (2019) 377:31
27. Sato K, Hyodo M, Aoki M, Zheng XQ, Noyori R (2001) Oxidation of sulfides to sulfoxides and
sulfones with 30% hydrogen peroxide under organic solvent- and halogen-free conditions. Tetrahedron 57:2469–2476
28. Yamada S, Mashiko T, Terashima S (1977) (Acetylacetonato) [(–)-N-alkylephedrinato]dioxomolybdenum, a new class of chiral chelate complexes which catalyze asymmetric epoxidation of
allylic alcohol. J Am Chem Soc 99:1988–1990
29. Basak A, Barlan AU, Yamamoto H (2006) Catalytic enantioselective oxidation of sulfides and
disulfides by a chiral complex of bis-hydroxamic acid and molybdenum. Tetrahedron Asymmetry
17:508–511
30. Dickman MH, Pope MT (1994) Peroxo and superoxo complexes of chromium, molybdenum, and
tungsten. Chem Rev 94:569–584
31. Zong L, Wang C, Moeljadi AMP, Ye X, Ganguly R, Li Y, Hirao H, Tan CH (2016) Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation.
Nat Commun 7:13455
32. Paria S, Lee HJ, Maruoka K (2019) Enantioselective alkynylation of isatin derivatives using a
chiral phase-transfer/transition-metal hybrid catalyst system. ACS Catal 9:2395–2399
33. Blay G, Monleon A, Pedro JR (2009) Recent developments in asymmetric alkynylation of
imines. Curr Org Chem 13:1498–1539
34. Trost BM, Weiss AH (2009) The enantioselective addition of alkyne nucleophiles to carbonyl
groups. Adv Synth Catal 351:963–983
35. Sawamura M, Ito Y (1992) Catalytic asymmetric synthesis by means of secondary interaction
between chiral ligands and substrates. Chem Rev 92:857–871
36. Shibasaki M, Yoshikawa N (2002) Lanthanide complexes in multifunctional asymmetric catalysis. Chem Rev 102:2187–2209
37. Ma J-A, Cahard D (2004) Towards perfect catalytic asymmetric synthesis: dual activation of the
electrophile and the nucleophile. Angew Chem Int Ed 43:4566–4583
38. Kull T, Peters R (2008) Contact ion pair directed Lewis acid catalysis: asymmetric synthesis of
trans-configured β-lactones. Angew Chem Int Ed 47:5461–5464
39. Kull T, Cabrera J, Peters R (2010) Catalytic asymmetric synthesis of trans-configured β-lactones:
cooperation of Lewis acid and ion pair catalysis. Chem Eur J 16:9132–9139
40. Meier P, Broghammer F, Latendorf K, Rauhut G, Peters R (2012) Cooperative Al(salen)-pyridinium catalysts for the asymmetric synthesis of trans-configured β-lactones by [2 + 2]-cyclocondensation of acylbromides and aldehydes: investigation of pyridinium substituent effects. Molecules 17:7121–7150
41. Kurono N, Ohkuma T (2016) Catalytic asymmetric cyanation reactions. ACS Catal 6:989–1023
42. Brodbeck D, Broghammer F, Meisner J, Klepp J, Garnier D, Frey W, Kästner J, Peters R (2017)
An aluminum fluoride complex with an appended ammonium salt as an exceptionally active
cooperative catalyst for the asymmetric carboxycyanation of aldehydes. Angew Chem Int Ed
56:4056–4060
43. Brodbeck D, Álvarez-Barcia S, Meisner J, Broghammer F, Klepp J, Garnier D, Frey W, Kästner
J, Peters R (2019) Asymmetric carboxycyanation of aldehydes by cooperative AlF/onium salt
catalysts: from cyanoformate to KCN as cyanide source. Chem Eur J 25:1515–1524
44. Broghammer F, Brodbeck D, Junge T, Peters R (2017) Cooperative Lewis acid–onium salt catalysis as tool for the desymmetrization of meso-epoxides. Chem Commun 53:1156–1159
45. Schulze B, Schubert US (2014) Beyond click chemistry–supramolecular interactions of 1,2,3-triazoles. Chem Soc Rev 43:2522–2571
46. Cai J, Sessler JL (2014) Neutral CH and cationic CH donor groups as anion receptors. Chem Soc
Rev 43:6198–6213
47. Ohmatsu K, Kiyokawa M, Ooi T (2011) Chiral 1,2,3-Triazoliums as new cationic organic catalysts with anion-recognition ability: application to asymmetric alkylation of oxindoles. J Am
Chem Soc 133:1307–1309
48. Ohmatsu K, Ando Y, Nakashima T, Ooi T (2016) A modular strategy for the direct catalytic
asymmetric α-amination of carbonyl compounds. Chem 1:802–810
49. Chen S-K, Ma W-Q, Yan Z-B, Zhang F-M, Wang S-H, Tu Y-Q, Zhang X-M, Tian J-M (2018)
Organo-cation catalyzed asymmetric homo/heterodialkylation of bisoxindoles: construction of
vicinal all-carbon quaternary stereocenters and total synthesis of (−)-chimonanthidine. J Am
Chem Soc 140:10099–10103
Reprinted from the journal
151
Topics in Current Chemistry (2019) 377:31
27. Sato K, Hyodo M, Aoki M, Zheng XQ, Noyori R (2001) Oxidation of sulfides to sulfoxides and
sulfones with 30% hydrogen peroxide under organic solvent- and halogen-free conditions. Tetrahedron 57:2469–2476
28. Yamada S, Mashiko T, Terashima S (1977) (Acetylacetonato) [(–)-N-alkylephedrinato]dioxomolybdenum, a new class of chiral chelate complexes which catalyze asymmetric epoxidation of
allylic alcohol. J Am Chem Soc 99:1988–1990
29. Basak A, Barlan AU, Yamamoto H (2006) Catalytic enantioselective oxidation of sulfides and
disulfides by a chiral complex of bis-hydroxamic acid and molybdenum. Tetrahedron Asymmetry
17:508–511
30. Dickman MH, Pope MT (1994) Peroxo and superoxo complexes of chromium, molybdenum, and
tungsten. Chem Rev 94:569–584
31. Zong L, Wang C, Moeljadi AMP, Ye X, Ganguly R, Li Y, Hirao H, Tan CH (2016) Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation.
Nat Commun 7:13455
32. Paria S, Lee HJ, Maruoka K (2019) Enantioselective alkynylation of isatin derivatives using a
chiral phase-transfer/transition-metal hybrid catalyst system. ACS Catal 9:2395–2399
33. Blay G, Monleon A, Pedro JR (2009) Recent developments in asymmetric alkynylation of
imines. Curr Org Chem 13:1498–1539
34. Trost BM, Weiss AH (2009) The enantioselective addition of alkyne nucleophiles to carbonyl
groups. Adv Synth Catal 351:963–983
35. Sawamura M, Ito Y (1992) Catalytic asymmetric synthesis by means of secondary interaction
between chiral ligands and substrates. Chem Rev 92:857–871
36. Shibasaki M, Yoshikawa N (2002) Lanthanide complexes in multifunctional asymmetric catalysis. Chem Rev 102:2187–2209
37. Ma J-A, Cahard D (2004) Towards perfect catalytic asymmetric synthesis: dual activation of the
electrophile and the nucleophile. Angew Chem Int Ed 43:4566–4583
38. Kull T, Peters R (2008) Contact ion pair directed Lewis acid catalysis: asymmetric synthesis of
trans-configured β-lactones. Angew Chem Int Ed 47:5461–5464
39. Kull T, Cabrera J, Peters R (2010) Catalytic asymmetric synthesis of trans-configured β-lactones:
cooperation of Lewis acid and ion pair catalysis. Chem Eur J 16:9132–9139
40. Meier P, Broghammer F, Latendorf K, Rauhut G, Peters R (2012) Cooperative Al(salen)-pyridinium catalysts for the asymmetric synthesis of trans-configured β-lactones by [2 + 2]-cyclocondensation of acylbromides and aldehydes: investigation of pyridinium substituent effects. Molecules 17:7121–7150
41. Kurono N, Ohkuma T (2016) Catalytic asymmetric cyanation reactions. ACS Catal 6:989–1023
42. Brodbeck D, Broghammer F, Meisner J, Klepp J, Garnier D, Frey W, Kästner J, Peters R (2017)
An aluminum fluoride complex with an appended ammonium salt as an exceptionally active
cooperative catalyst for the asymmetric carboxycyanation of aldehydes. Angew Chem Int Ed
56:4056–4060
43. Brodbeck D, Álvarez-Barcia S, Meisner J, Broghammer F, Klepp J, Garnier D, Frey W, Kästner
J, Peters R (2019) Asymmetric carboxycyanation of aldehydes by cooperative AlF/onium salt
catalysts: from cyanoformate to KCN as cyanide source. Chem Eur J 25:1515–1524
44. Broghammer F, Brodbeck D, Junge T, Peters R (2017) Cooperative Lewis acid–onium salt catalysis as tool for the desymmetrization of meso-epoxides. Chem Commun 53:1156–1159
45. Schulze B, Schubert US (2014) Beyond click chemistry–supramolecular interactions of 1,2,3-triazoles. Chem Soc Rev 43:2522–2571
46. Cai J, Sessler JL (2014) Neutral CH and cationic CH donor groups as anion receptors. Chem Soc
Rev 43:6198–6213
47. Ohmatsu K, Kiyokawa M, Ooi T (2011) Chiral 1,2,3-Triazoliums as new cationic organic catalysts with anion-recognition ability: application to asymmetric alkylation of oxindoles. J Am
Chem Soc 133:1307–1309
48. Ohmatsu K, Ando Y, Nakashima T, Ooi T (2016) A modular strategy for the direct catalytic
asymmetric α-amination of carbonyl compounds. Chem 1:802–810
49. Chen S-K, Ma W-Q, Yan Z-B, Zhang F-M, Wang S-H, Tu Y-Q, Zhang X-M, Tian J-M (2018)
Organo-cation catalyzed asymmetric homo/heterodialkylation of bisoxindoles: construction of
vicinal all-carbon quaternary stereocenters and total synthesis of (−)-chimonanthidine. J Am
Chem Soc 140:10099–10103
Reprinted from the journal
151