298
6.3.5 Silicon-Organic Phosphorus Compounds (δ in ppm relative to
TMS, J in Hz)
6.3.6 References
[1] H.C. Marsmann, 29 Si-NMR Spectroscopic results, In: NMR Basic Principles
and Progress, P. Diehl E. Fluck R. Kosfeld, Eds.; Vol 17, Springer·Verlag:
Berlin, Heidelberg 1981; p 65.
[2] B. Wrackmeyer, Applications of 29 Si NMR parameters, Annu. Rep. NMR
Spectrosc. 2006, 57, 1.
[3] F. Uhlig, 29 Si NMR Spectroscopy, In: Organosilicon Compounds, V.Ya. Lee,
Ed.; Academic Press: Cambridge, 2017, p 59.
[4] H.C. Marsmann, Silicon-29 NMR, In: eMagRes, R.K. Harris, R.L. Wasylishen,
Eds. 2011.
[5] M. Grignon-Dubois, M. Laguerre, 29 Si NMR Access to stereochemistry of
organosilicon compounds. 3. Vinylic silanes, Organometallics, 1988, 7, 1443.
[7] R.L. Scholl, G.E. Maciel, W.K. Musker, Silicon-29 chemical shifts of
organosilicon compounds, J. Am. Chem. Soc. 1972, 94, 6376.
[8] C.R. Ernst, L. Spialter, G.R. Buell, D.L. Wilhite, Silicon-29 nuclear magnetic
resonance. Chemical shift substituent effects, J. Am. Chem. Soc. 1974, 96,
5375.
Si(CH 3 ) 3
P
(H 3 C) 3 Si
Si(CH 3 ) 3
P
(H 3 C) 3 Si
-0.7
1 J SiP 23.2
| 2 J SiH | 6.5
2.8
1 J SiP 27.3
| 2 J SiH | 6.8
15.8
2 J SiP -44
-13.8
| 2 J SiP | 18.6
(H 3 C) 3 Si N
CH 3
P Cl
Cl
(H 3 C) 3 Si N P
CH 3
CH 3
CH 3
Heteronuclear NMR Spectroscopy
6