N
X
C
Hal
O
N
S
P Si
Natural
Products
Solvents
C
C
C
C C
C
177
5.2 Alkenes
177
Substituent R
H a
H b
H c
J ab J ac
J bc Other
–SCH 3
6.43 5.18 4.95
10.3 16.4 -0.3 CH 3 2.25
–S–phenyl
6.53 5.32 5.32
9.6 16.7 -0.2
–S(O)CH 3
6.77 5.92 6.08
9.8 16.7 -0.6 CH 3 2.61
–S(O) 2 CH 3
6.76 6.14 6.43
10.0 16.5 -0.5 CH 3 2.96
–S(O) 2 CH=CH 2 6.67 6.17 6.41
10.0 16.4 -0.6
–S(O) 2 OH
6.73 6.13 6.41
10.2 16.8 -1.2
–S(O) 2 OCH 3
6.57 6.22 6.43
10.1 16.9 -0.6 CH 3 3.85
–S(O) 2 NH 2
6.93 5.98 6.17
10.0 16.3
0
NH 2 6.7
–S(O) 2 NH–phenyl 6.56 5.86 6.18
10.1 16.7 -0.3 NH 9.07
–SF 5
6.63 5.64 5.96
9.8 16.6
0.4
–SCN
6.19 5.70 5.66
–CHO
6.37 6.52 6.35
10.0 17.4
1.0 CHO 9.59
–COCH 3
6.30 5.91 6.21
10.7 18.7
1.3 CH 3 2.29
–COCH=CH 2
6.67 5.82 6.28
11.0 17.9
1.4
–CO–phenyl
7.20 5.81 6.52
9.9 17.7
2.3
–COOH
6.15 5.95 6.53
10.5 17.2
1.8 COOH 12.8
–COOCH 3
6.12 5.83 6.41
10.6 17.4
1.5 CH 3 3.77
–CONH 2
6.48 5.71 6.17
7.9 17.3
5.0 NH 2 7.55
–CON(CH 3 ) 2
6.64 5.55 6.12
9.8 17.0
3.4
–COF
6.14 6.25 6.60
10.7 17.3
0.8
–COCl
6.35 6.16 6.63
10.6 17.4
0.2
–P(CH 3 ) 2
6.23 5.51 5.39
11.8 18.3
2.0 CH 3 0.95
–P(CH=CH 2 ) 2
6.16 5.64 5.59
11.8 18.4
2.0
–P(phenyl) 2
7.38 6.31 7.07
12.5 18.2
0
–PCl 2
7.48 6.68 6.64
11.7 18.6
0.4
–P(O)(phenyl) 2
6.72 6.21 6.25
12.9 18.9
1.8
–PSCl 2
6.42 5.90 6.13
11.0 17.5
0.3
–P(S)(CH 3 ) 2
6.60 6.14 6.26
11.8 17.9
1.8
–P(S)(phenyl) 2
6.82 6.17 6.34
11.7 17.9
1.6
–Li
7.29 6.65 5.91
19.3 23.9
7.1
–MgBr
6.66 6.15 5.51
17.7 23.3
7.6
–Si(CH 3 ) 3
6.11 5.88 5.63
14.6 20.2
3.8 CH 3 0.06
–Sn(CH=CH 2 ) 3
6.39 6.21 5.75
13.4 20.7
3.1
–Pb(CH=CH 2 ) 3
6.70 6.19 5.46
12.2 19.8
2.1
–HgBr
6.45 5.92 5.52
11.9 18.7
3.1
S
O
||
C
P
M