N
X
C
O
N
S
Hal
Solvents
Natural
Products
P Si
C
C
C C
C
C
120
4 13 C NMR
4.8 Alcohols, Ethers, and Related Compounds
4.8.1 Alcohols
13 C Chemical Shifts of Alcohols (δ in ppm)
Cl 3 C
OH
F 3 C
OH
OH
HO
OH
OH
OH
HO
OH
OH
HO
OH
OH
HO
OH
OH
OH
OH
OH
OH
OH
HO
OH
OH
CH 3 OH
OH
OH
OH
OH
OH
OH
OH
OH
HO
OH
HO
OH
OH
OH
OH
HO
HO
50.2
18.2
15.2
14.2
14.3
36.0
31.9
63.4
66.0
125.1
114.9 137.5
99.1
63.4
73.8 83.0
50.0
61.4
75.9
63.4
75.5
91.2
83.3
91.2
36.4
28.2
32.9
14.3 39.4 30.5
31.2
23.8 33.6
32.7
57.8
20.3
23.0
23.2
62.9
25.8
39.2
62.1
64.5
64.3
48.3
73.7
60.2
76.1 72.9
74.3 74.5
65.8
66.1
18.7 (23.0) 67.7 (71.6)
68.2 (72.7)
in parentheses: in D 2 O
23.5
67.2
10.1
72.2
19.2
15.3 29.4 63.2
26.2
73.3
68.9
10.3 64.2
64.0
25.9
25.3
OH
| 1 J CF | 278
| 2 J CF | 35
OH