70
2 Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) …
b)
40
35
30
25
20
15
10
5
Intensity
a)
2θ / º
3/CHCl 3 , Powder XRD
3/CHCl 3 , simulated
40
35
30
25
20
15
10
5
Intensity
2θ / º
3/Py, Powder XRD
3/Py, simulated
40
35
30
25
20
15
10
5
Intensity
2θ / º
c)
3/CH 2 Cl 2 , Powder XRD
3/CH 2 Cl 2 , simulated
Fig. 2.39 Experimental powder XRD patterns of eleven 3/solvent obtained by solvent addition
to 3 ground (colored solid lines) and simulated powder patterns of 3/solvent derived form the single crystal structures (black solid lines), in which 3/solvent corresponds to a 3/CHCl 3 , b 3/Py, c
3/CH 2 Cl 2 , d 3/CH 2 Br 2 , e 3/DMA, f 3/AcH, g 3/CH 3 CN, h 3/DMF, i 3/SPO, j 3/racPO, and k
3/acetone