190
6 Thermo-Responsive Phosphorescence Control Mediated …
Ferroelectricity and polarity control in solid-state flip-flop supramolecular rotators. Nat Mater
8:342–347. (i) Yao ZS, Yamamoto K, Cai HL, Takahashi K, Sato O (2016) Above room temperature organic ferroelectrics: diprotonated 1,4-diazabicyclo[2.2.2]octane shifts between two
2-chlorobenzoates. J Am Chem Soc 138:12005–12008
5. (a) Dominguez Z, Khuong TAV, Sanrame CN, Dang H, Nuñez JE, Garcia-Garibay MA (2003)
Molecular compasses and gyroscopes with polar rotors: synthesis and characterization of
crystalline forms. J Am Chem Soc 125:8827–8837. (b) Dominguez Z, Dang H, Strouse MJ,
Garcia-Garibay MA (2002) Molecular “compasses” and “gyroscopes”. I. Expedient synthesis
and solid state dynamics of an open rotor with a bis(triarylmethyl) frame. J Am Chem Soc
124:2398–2399. (c) Godinez CE, Zepeda G, Garcia-Garibay MA (2002) Molecular compasses
and gyroscopes. II. Synthesis and characterization of molecular rotors with axially substituted
bis[2-(9-triptycyl)ethynyl]arenes. J Am Chem Soc 124:4701–4707. (d) Jarowski PD, Houk
KN, Garcia-Garibay MA (2007) Importance of correlated motions on the low barrier rotational
potentials of crystalline molecular gyroscopes. J Am Chem Soc 129:3110–3117
6. Jobba´ gy C, Dea ´
k A (2014) Stimuli-responsive dynamic gold complexes. Eur J Inorg Chem
2014:4434–4449
7. (a) Pyykkö P (2004) Theoretical chemistry of gold. Angew Chem Int Ed 43:4412–4456. (b)
Katz MJ, Sakai K, Leznoff DB (2008) The use of aurophilic and other metal–metal interactions as crystal engineering design elements to increase structural dimensionality. Chem Soc
Rev 37:1884–1895. (c) Schmidbaur H, Schier A (2008) A briefing on aurophilicity. Chem
Soc Rev 37:1931–1951. (d) Laguna A (2008) Modern supramolecular gold chemistry. Wiley,
Weinheim, Germany. (e) Chen Y, Cheng G, Li K, Shelar DP, Lu W, Che C-M (2014) Phosphorescent polymeric nanomaterials with metallophilic d 10 ···d 10 interactions self-assembled from
[Au(NHC) 2 ] + and [M(CN) 2 ] − . Chem Sci 5:1348–1353. (f) Ito H, Muromoto M, Kurenuma S,
Ishizaka S, Kitamura N, Sato H, Seki T (2013) Mechanical stimulation and solid seeding trigger
single-crystal-to-single-crystal molecular domino transformations. Nat Commun 4:2009
8. Zalesskiy SS, Sedykh AE, Kashin AS, Ananikov VP (2013) Efficient general procedure to
access a diversity of gold(0) particles and gold(I) phosphine complexes from a simple HAuCl 4
source. Localization of homogeneous/heterogeneous system’s interface and field-emission
scanning electron microscopy study. J Am Chem Soc 135:3550–3559
9. Macho V, Brombacher L, Spiess HW (2001) The NMR-WEBLAB: an internet approach to
NMR lineshape analysis. Appl Magn Reson 20:405–432
10. (a) Emmert LA, Choi W, Marshal JA, Yang Y, Meyer LA, Brozic JA (2003) The excited-state
symmetry characteristics of platinum phenylacetylene compounds. J Phys Chem A 107:11340–
11346. (b) Chao HY, Lu W, Li Y, Chan MCW, Che C-M, Cheung K-K, Zhu N (2002) Organic
triplet emissions of arylacetylide moieties harnessed through coordination to [Au(PCy 3 )] + .
Effect of molecular structure upon photoluminescent properties. J Am Chem Soc 124:14696–
14706
11. Wan S, Lu W (2017) Reversible photoactivated phosphorescence of gold(I) arylethynyl
complexes in aerated DMSO solutions and gels. Angew Chem Int Ed 56:1784–1788
12. Levitus M, Zepeda G, Dang H, Godinez C, Khuong TAV, Schmieder K, Garcia-Garibay
MA (2001) Steps to demarcate the effects of chromophore aggregation and planarization in
poly(phenyleneethynylene)s. 2. The photophysics of 1,4-diethynyl-2-fluorobenzene in solution
and in crystals. J Org Chem 66:3188–3195
13. (a) Levitus M, Schmieder K, Ricks H, Shimize KD, Bunz UHF, Garcia-Garibay MA
(2001) Steps to demarcate the effects of chromophore aggregation and planarization in
poly(phenyleneethynylene)s. 1. Rotationally interrupted conjugation in the excited states of
1,4-bis(phenylethynyl)benzene. J Am Chem Soc 123:4259–4265. (b) Levitus M, GarciaGaribay MA (2000) Polarized electronic spectroscopy and photophysical properties of
9,10-bis(phenylethynyl)anthracene. J Phys Chem A 104:8632–8637
14. Krämer M, Bunz UHF, Dreuw A (2017) Comprehensive look at the photochemistry of tolane.
J Phys Chem A 121:946–953
15. Cardolaccia T, Li Y, Schanze KS (2008) Phosphorescent platinum acetylide organogelators. J
Am Chem Soc 130:2535–2545
6 Thermo-Responsive Phosphorescence Control Mediated …
Ferroelectricity and polarity control in solid-state flip-flop supramolecular rotators. Nat Mater
8:342–347. (i) Yao ZS, Yamamoto K, Cai HL, Takahashi K, Sato O (2016) Above room temperature organic ferroelectrics: diprotonated 1,4-diazabicyclo[2.2.2]octane shifts between two
2-chlorobenzoates. J Am Chem Soc 138:12005–12008
5. (a) Dominguez Z, Khuong TAV, Sanrame CN, Dang H, Nuñez JE, Garcia-Garibay MA (2003)
Molecular compasses and gyroscopes with polar rotors: synthesis and characterization of
crystalline forms. J Am Chem Soc 125:8827–8837. (b) Dominguez Z, Dang H, Strouse MJ,
Garcia-Garibay MA (2002) Molecular “compasses” and “gyroscopes”. I. Expedient synthesis
and solid state dynamics of an open rotor with a bis(triarylmethyl) frame. J Am Chem Soc
124:2398–2399. (c) Godinez CE, Zepeda G, Garcia-Garibay MA (2002) Molecular compasses
and gyroscopes. II. Synthesis and characterization of molecular rotors with axially substituted
bis[2-(9-triptycyl)ethynyl]arenes. J Am Chem Soc 124:4701–4707. (d) Jarowski PD, Houk
KN, Garcia-Garibay MA (2007) Importance of correlated motions on the low barrier rotational
potentials of crystalline molecular gyroscopes. J Am Chem Soc 129:3110–3117
6. Jobba´ gy C, Dea ´
k A (2014) Stimuli-responsive dynamic gold complexes. Eur J Inorg Chem
2014:4434–4449
7. (a) Pyykkö P (2004) Theoretical chemistry of gold. Angew Chem Int Ed 43:4412–4456. (b)
Katz MJ, Sakai K, Leznoff DB (2008) The use of aurophilic and other metal–metal interactions as crystal engineering design elements to increase structural dimensionality. Chem Soc
Rev 37:1884–1895. (c) Schmidbaur H, Schier A (2008) A briefing on aurophilicity. Chem
Soc Rev 37:1931–1951. (d) Laguna A (2008) Modern supramolecular gold chemistry. Wiley,
Weinheim, Germany. (e) Chen Y, Cheng G, Li K, Shelar DP, Lu W, Che C-M (2014) Phosphorescent polymeric nanomaterials with metallophilic d 10 ···d 10 interactions self-assembled from
[Au(NHC) 2 ] + and [M(CN) 2 ] − . Chem Sci 5:1348–1353. (f) Ito H, Muromoto M, Kurenuma S,
Ishizaka S, Kitamura N, Sato H, Seki T (2013) Mechanical stimulation and solid seeding trigger
single-crystal-to-single-crystal molecular domino transformations. Nat Commun 4:2009
8. Zalesskiy SS, Sedykh AE, Kashin AS, Ananikov VP (2013) Efficient general procedure to
access a diversity of gold(0) particles and gold(I) phosphine complexes from a simple HAuCl 4
source. Localization of homogeneous/heterogeneous system’s interface and field-emission
scanning electron microscopy study. J Am Chem Soc 135:3550–3559
9. Macho V, Brombacher L, Spiess HW (2001) The NMR-WEBLAB: an internet approach to
NMR lineshape analysis. Appl Magn Reson 20:405–432
10. (a) Emmert LA, Choi W, Marshal JA, Yang Y, Meyer LA, Brozic JA (2003) The excited-state
symmetry characteristics of platinum phenylacetylene compounds. J Phys Chem A 107:11340–
11346. (b) Chao HY, Lu W, Li Y, Chan MCW, Che C-M, Cheung K-K, Zhu N (2002) Organic
triplet emissions of arylacetylide moieties harnessed through coordination to [Au(PCy 3 )] + .
Effect of molecular structure upon photoluminescent properties. J Am Chem Soc 124:14696–
14706
11. Wan S, Lu W (2017) Reversible photoactivated phosphorescence of gold(I) arylethynyl
complexes in aerated DMSO solutions and gels. Angew Chem Int Ed 56:1784–1788
12. Levitus M, Zepeda G, Dang H, Godinez C, Khuong TAV, Schmieder K, Garcia-Garibay
MA (2001) Steps to demarcate the effects of chromophore aggregation and planarization in
poly(phenyleneethynylene)s. 2. The photophysics of 1,4-diethynyl-2-fluorobenzene in solution
and in crystals. J Org Chem 66:3188–3195
13. (a) Levitus M, Schmieder K, Ricks H, Shimize KD, Bunz UHF, Garcia-Garibay MA
(2001) Steps to demarcate the effects of chromophore aggregation and planarization in
poly(phenyleneethynylene)s. 1. Rotationally interrupted conjugation in the excited states of
1,4-bis(phenylethynyl)benzene. J Am Chem Soc 123:4259–4265. (b) Levitus M, GarciaGaribay MA (2000) Polarized electronic spectroscopy and photophysical properties of
9,10-bis(phenylethynyl)anthracene. J Phys Chem A 104:8632–8637
14. Krämer M, Bunz UHF, Dreuw A (2017) Comprehensive look at the photochemistry of tolane.
J Phys Chem A 121:946–953
15. Cardolaccia T, Li Y, Schanze KS (2008) Phosphorescent platinum acetylide organogelators. J
Am Chem Soc 130:2535–2545