118
4 Mechano-Responsive Luminescence via Crystal-to-Crystal Phase …
were recorded on a Hitachi F-7000 spectrometer. Absorption spectra were recorded
on the basis of synchronous fluorescence spectroscopy using a Hitachi F-7000 spectrometer equipped with an integrating sphere. Fluorescence microscopic spectra were
recorded on a Photonic Hamamatsu PMA-12 Multichannel Analyzer. The emission
quantum yields of the solid samples were recorded on a Hamamatsu QuantaurusQY spectrometer with an integrating sphere. Emission lifetime measurements were
recorded on a Hamamatsu Quantaurus-Tau spectrometer. Elemental analyses and
low- and high resolution mass spectra were recorded at the Global Facility Center at Hokkaido University. Photographs were obtained using Olympus BX51 or
SZX7 microscopes with Olympus DP72, Nikon D5100 digital cameras. Thermal
gravimetric analysis profiles were recorded on Bruker TG-DTA2010SAT.
4.8.2 Data for Single-Crystal X-ray Structural Analyses
Single-crystal X-ray structural analyses were carried out on a Rigaku R-AXIS RAPID
diffractometer using graphite monochromated Mo-K α radiation. The structure was
solved by direct methods and expanded using Fourier techniques. Non-hydrogen
atoms were refined anisotoropically. Hydrogen atoms were refined using the riding
model. All calculations were performed using the CrystalStructure crystallographic
software package except for refinement, which was performed using SHELXL-2013
[10] (Figs. 4.14 and 4.15).
4.8.3 PXRD Patterns and Simulated Powder Patterns of 1ch
and 1ac
See Fig. 4.16.
4.8.4 Photophysical Properties
See Figs. 4.17 and 4.18.
4 Mechano-Responsive Luminescence via Crystal-to-Crystal Phase …
were recorded on a Hitachi F-7000 spectrometer. Absorption spectra were recorded
on the basis of synchronous fluorescence spectroscopy using a Hitachi F-7000 spectrometer equipped with an integrating sphere. Fluorescence microscopic spectra were
recorded on a Photonic Hamamatsu PMA-12 Multichannel Analyzer. The emission
quantum yields of the solid samples were recorded on a Hamamatsu QuantaurusQY spectrometer with an integrating sphere. Emission lifetime measurements were
recorded on a Hamamatsu Quantaurus-Tau spectrometer. Elemental analyses and
low- and high resolution mass spectra were recorded at the Global Facility Center at Hokkaido University. Photographs were obtained using Olympus BX51 or
SZX7 microscopes with Olympus DP72, Nikon D5100 digital cameras. Thermal
gravimetric analysis profiles were recorded on Bruker TG-DTA2010SAT.
4.8.2 Data for Single-Crystal X-ray Structural Analyses
Single-crystal X-ray structural analyses were carried out on a Rigaku R-AXIS RAPID
diffractometer using graphite monochromated Mo-K α radiation. The structure was
solved by direct methods and expanded using Fourier techniques. Non-hydrogen
atoms were refined anisotoropically. Hydrogen atoms were refined using the riding
model. All calculations were performed using the CrystalStructure crystallographic
software package except for refinement, which was performed using SHELXL-2013
[10] (Figs. 4.14 and 4.15).
4.8.3 PXRD Patterns and Simulated Powder Patterns of 1ch
and 1ac
See Fig. 4.16.
4.8.4 Photophysical Properties
See Figs. 4.17 and 4.18.