481
Rate expression
Reaction condition
References
R
k
K K K K K P P
P
n
CH
H
C O
H O
4
2
2
7
6 1 2 3 4
2 5
2
2
=
∗
[ ]
≥
(
)
.
R
k
K K K K K P P
P
P k
k P
n
n
n
n
n
i
i
C H
H CO
H O
H h
C H
2 2
2
2
2
2
7
6 1 2 3 4
3
2
2
8
+
=
∏ ∗
[ ] +
=
−
α
∗ ∗
+
[ ]
+
≥
(
)
σ
P k k
n
H h
2
8
2
R
k
K K K P P
P
P k
k P
n
n
n
n
n
i
i
C H
H CO
H O
H h
C H
2
2
2
2
2
8
1 2 3
2
2
2
8
1
=
−
(
)∏ ∗
[ ] −
+
=
−
β
α
n n
P k k
∗
+
[ ]
+
σ
H h
2
8
where P
P
cn n
n
n
n
n
C H
C H
2
2
2
∗
=
⋅
( ) ≥
(
)
exp
P
P
c
C H
C H
2 4
2 4
2
∗
= ⋅
( )
λ
.exp
∗
[ ] =
+
+
+
+
(
) + ∑ ∏
(
)
{
} +
=
=
1
1
1
1
1
1
1
2
3
6
4
2
2
4
2
2
K P
K P
K
K K P
K P
i
n
j
i
j
CO
H
H
(
(
α
H H
2
(
)
σ
[ ]=
+
+∑
+
=
− ∗
+
1
1
1
2
8
8
2
2
K P
k P
P k k
i
N
n
n
CO
C H
H h
β
α
α
n
n
i
n
i
k P
k
K K K P P
P
k
P
n
n
n i
=
+
∑
− ∗
−
−
=
−
− +
8
8
1
3 2 1
2
8
2
2
2
2
2
2
C H
A
H CO
H O
A
C
H H
H
H O
H
2
2
2
2
2
5
3 2 1
2
7 6 4
8
n i
k
K K K P P
P
k K K P
k
CO
− +
(
)
∗
[ ]+
∗
[ ]+










 



Fe/Cu/K/SiO
2
Slurry reactor
T—250–290 °C
P—1.0–2.5 MPa,
H
2 /
CO-0.67–1.5
Chang et al. [28]
(continued)
Recent Advancements and Detailed Understanding of Kinetics for Synthesis Gas…