313
185. Farrá n A, Cai C, Sandoval M, Xu Y, Liu J, Herná iz MJ, Linhardt RJ (2015) Green Solvents in
Carbohydrate Chemistry: From Raw Materials to Fine Chemicals. Chem Rev 115:6811
186. Liguori F, Moreno-Marrodan C, Barbaro P (2015) Environmentally Friendly Synthesis of
γ-Valerolactone by Direct Catalytic Conversion of Renewable Sources. ACS Catal 5:1882
187. Santoro S, Ferlin F, Luciani L, Ackermann L, Vaccaro L (2017) Biomass-derived solvents
as effective media for cross-coupling reactions and C–H functionalization processes. Green
Chem 19:1601
188. Santoro S, Marrocchi A, Lanari D, Ackermann L, Vaccaro L (2018) Towards Sustainable
C−H Functionalization Reactions: The Emerging Role of Bio‐Based Reaction Media. Chem
Eur J 24:13383
189. Rasina D, Kahler-Quesada A, Ziarelli S, Warratz S, Cao H, Santoro S, Ackermann L,
Vaccaro L (2016) Heterogeneous palladium-catalysed Catellani reaction in biomass-derived
γ-valerolactone. Green Chem 18:5025
190. Ackermann L, Vicente R, Born R (2008) Palladium‐Catalyzed Direct Arylations of 1,2,3‐
Triazoles with Aryl Chlorides using Conventional Heating. Adv Synth Catal 350:741
191. Ferlin F, Luciani L, Santoro S, Marrocchi A, Lanari D, Bechtoldt A, Ackermann L, Vaccaro
L (2018) A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in
γ-valerolactone as a biomass-derived medium. Green Chem 20:2888
192. Bechtoldt A, Baumert ME, Vaccaro L, Ackermann L (2018) Ruthenium(ii) oxidase catalysis
for C–H alkenylations in biomass-derived γ-valerolactone. Green Chem 20:398
193. Bu Q, Rogge T, Kotek V, Ackermann L (2018) Distal Weak Coordination of Acetamides in
Ruthenium(II)‐Catalyzed C−H Activation Processes. Angew Chem Int Ed 57:765
194. Bu Q, Goń ka E, Kuciń ski K, Ackermann L (2018) Cobalt-Catalyzed Hiyama‐Type C−H
Activation with Arylsiloxanes: Versatile Access to Highly ortho‐Decorated Biaryls. Chem
Eur J 25:2213
195. Li BJ, Yang SD, Shi ZJ (2008) Recent Advances in Direct Arylation via Palladium-Catalyzed
Aromatic C-H Activation. Synlett 949
196. Ackermann L, Vicente R, Kapdi AR (2009) Transition-metal-catalyzed direct arylation of
(hetero)arenes by C-H bond cleavage. Angew Chem Int Ed 48: 9792
197. Tsai AS, Wilson RM, Harada H, Bergman RG, Ellman JA (2009) Rhodium catalyzed enantioselective cyclization of substituted imidazolesvia C–H bond activation. Chem Commun:3910
198. Fischmeister C, Doucet H (2011) Greener solvents for ruthenium and palladium-catalysed
aromatic C–H bond functionalisation. Green Chem 13:741
199. Crabtree RH (1993) Photocatalysis in C-H Activation. Springer, Netherlands
200. Chen J-R, Hu X-Q, Lu L-Q, Xiao W-J (2016) Exploration of Visible-Light Photocatalysis
in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond. Acc Chem
Res 49:1911
201. Capaldo L, Ravelli D (2017) Hydrogen Atom Transfer (HAT): A Versatile Strategy for
Substrate Activation in Photocatalyzed Organic Synthesis. Eur J Org Chem 15:2056
202. Protti S, Fagnoni M, Ravelli D (2015) Photocatalytic C–H Activation by Hydrogen‐Atom
Transfer in Synthesis. ChemCatChem, 10:1516
203. Fagnoni M, Dondi D, Ravelli D, Albini A (2007) Photocatalysis for the Formation of the
C−C Bond. Chem Rev 107:2725
204. Ravelli D, Dondi D, Fagnoni M, Albini A (2009) Photocatalysis. A multi-faceted concept for
green chemistry. Chem Soc Rev 38:1999
205. Tzirakis MD, Lykakis IN, Orfanopoulos M (2009) Decatungstate as an efficient photocatalyst in organic chemistry. Chem Soc Rev 38:2609
206. Condie AG, Gonzalez-Gomez JC, Stephenson CRJ (2010) Visible-Light Photoredox
Catalysis: Aza-Henry Reactions via C−H Functionalization. J Am Chem Soc 132:1464
207. Zou Y-Q, Lu L-Q, Fu L, Chang N-J, Chen J-R, Xiao W-J (2011) Visible-light-induced oxidation/[3+2] cycloaddition/oxidative aromatization sequence: a photocatalytic strategy to construct pyrrolo[2,1-a]isoquinolines. Angew Chem Int Ed 50:7171
Insights into Sustainable C–H Bond Activation
185. Farrá n A, Cai C, Sandoval M, Xu Y, Liu J, Herná iz MJ, Linhardt RJ (2015) Green Solvents in
Carbohydrate Chemistry: From Raw Materials to Fine Chemicals. Chem Rev 115:6811
186. Liguori F, Moreno-Marrodan C, Barbaro P (2015) Environmentally Friendly Synthesis of
γ-Valerolactone by Direct Catalytic Conversion of Renewable Sources. ACS Catal 5:1882
187. Santoro S, Ferlin F, Luciani L, Ackermann L, Vaccaro L (2017) Biomass-derived solvents
as effective media for cross-coupling reactions and C–H functionalization processes. Green
Chem 19:1601
188. Santoro S, Marrocchi A, Lanari D, Ackermann L, Vaccaro L (2018) Towards Sustainable
C−H Functionalization Reactions: The Emerging Role of Bio‐Based Reaction Media. Chem
Eur J 24:13383
189. Rasina D, Kahler-Quesada A, Ziarelli S, Warratz S, Cao H, Santoro S, Ackermann L,
Vaccaro L (2016) Heterogeneous palladium-catalysed Catellani reaction in biomass-derived
γ-valerolactone. Green Chem 18:5025
190. Ackermann L, Vicente R, Born R (2008) Palladium‐Catalyzed Direct Arylations of 1,2,3‐
Triazoles with Aryl Chlorides using Conventional Heating. Adv Synth Catal 350:741
191. Ferlin F, Luciani L, Santoro S, Marrocchi A, Lanari D, Bechtoldt A, Ackermann L, Vaccaro
L (2018) A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in
γ-valerolactone as a biomass-derived medium. Green Chem 20:2888
192. Bechtoldt A, Baumert ME, Vaccaro L, Ackermann L (2018) Ruthenium(ii) oxidase catalysis
for C–H alkenylations in biomass-derived γ-valerolactone. Green Chem 20:398
193. Bu Q, Rogge T, Kotek V, Ackermann L (2018) Distal Weak Coordination of Acetamides in
Ruthenium(II)‐Catalyzed C−H Activation Processes. Angew Chem Int Ed 57:765
194. Bu Q, Goń ka E, Kuciń ski K, Ackermann L (2018) Cobalt-Catalyzed Hiyama‐Type C−H
Activation with Arylsiloxanes: Versatile Access to Highly ortho‐Decorated Biaryls. Chem
Eur J 25:2213
195. Li BJ, Yang SD, Shi ZJ (2008) Recent Advances in Direct Arylation via Palladium-Catalyzed
Aromatic C-H Activation. Synlett 949
196. Ackermann L, Vicente R, Kapdi AR (2009) Transition-metal-catalyzed direct arylation of
(hetero)arenes by C-H bond cleavage. Angew Chem Int Ed 48: 9792
197. Tsai AS, Wilson RM, Harada H, Bergman RG, Ellman JA (2009) Rhodium catalyzed enantioselective cyclization of substituted imidazolesvia C–H bond activation. Chem Commun:3910
198. Fischmeister C, Doucet H (2011) Greener solvents for ruthenium and palladium-catalysed
aromatic C–H bond functionalisation. Green Chem 13:741
199. Crabtree RH (1993) Photocatalysis in C-H Activation. Springer, Netherlands
200. Chen J-R, Hu X-Q, Lu L-Q, Xiao W-J (2016) Exploration of Visible-Light Photocatalysis
in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond. Acc Chem
Res 49:1911
201. Capaldo L, Ravelli D (2017) Hydrogen Atom Transfer (HAT): A Versatile Strategy for
Substrate Activation in Photocatalyzed Organic Synthesis. Eur J Org Chem 15:2056
202. Protti S, Fagnoni M, Ravelli D (2015) Photocatalytic C–H Activation by Hydrogen‐Atom
Transfer in Synthesis. ChemCatChem, 10:1516
203. Fagnoni M, Dondi D, Ravelli D, Albini A (2007) Photocatalysis for the Formation of the
C−C Bond. Chem Rev 107:2725
204. Ravelli D, Dondi D, Fagnoni M, Albini A (2009) Photocatalysis. A multi-faceted concept for
green chemistry. Chem Soc Rev 38:1999
205. Tzirakis MD, Lykakis IN, Orfanopoulos M (2009) Decatungstate as an efficient photocatalyst in organic chemistry. Chem Soc Rev 38:2609
206. Condie AG, Gonzalez-Gomez JC, Stephenson CRJ (2010) Visible-Light Photoredox
Catalysis: Aza-Henry Reactions via C−H Functionalization. J Am Chem Soc 132:1464
207. Zou Y-Q, Lu L-Q, Fu L, Chang N-J, Chen J-R, Xiao W-J (2011) Visible-light-induced oxidation/[3+2] cycloaddition/oxidative aromatization sequence: a photocatalytic strategy to construct pyrrolo[2,1-a]isoquinolines. Angew Chem Int Ed 50:7171
Insights into Sustainable C–H Bond Activation