308
Carbon Dioxide Enhances the Reactivity towards Primary Carbon–Hydrogen Bonds.
ChemCatChem 7:3254
83. Hu YL, Wu YP, Lu M (2018) Co (II)‐C12 alkyl carbon chain multi‐functional ionic liquid
immobilized on nano‐SiO2 nano‐SiO2@CoCl3‐C12IL as an efficient cooperative catalyst for
C–H activation by direct acylation of aryl halides with aldehydes. Appl. Organomet. Chem.
32:e4096
84. Cotugno P, Monopoli A, Ciminale F, Milella A, Nacci A (2014) Palladium‐Catalyzed
Cross‐Coupling of Styrenes with Aryl Methyl Ketones in Ionic Liquids: Direct Access to
Cyclopropanes. Angew. Chem. Int. Ed. 53:13563
85. Ruokonen S-K, Sanwald C, Sundvik M, Polnick S, Vyavaharkar K, Duša F, Holding AJ, King
AWT, Kilpeläinen I, Lämmerhofer M, Panula P, Wiedmer SK (2016) Effect of Ionic Liquids
on Zebrafish (Danio rerio) Viability, Behavior, and Histology; Correlation between Toxicity
and Ionic Liquid Aggregation. Environ. Sci. Technol. 50:7116
86. Kumar M, Trivedi N, Reddy CRK, Jha B (2011) Toxic Effects of Imidazolium Ionic Liquids
on the Green Seaweed Ulva lactuca: Oxidative Stress and DNA Damage. Chem. Res.
Toxicol. 24:1882
87. Stefanidis G, Stankiewicz A (eds) (2016) Alternative Energy Sources for Green Chemistry,
The Royal Society of Chemistry, Cambridge
88. Tundo P, Perosa A, Zecchini F (eds) (2007) Methods and Reagents for Green Chemistry: An
Introduction, John Wiley & Sons, Hoboken
89. Zhao H, Cheng M, Zhang J, Cai M (2014) Recyclable and reusable PdCl2(PPh3)2/PEG-2000/
H2O system for the carbonylative Sonogashira coupling reaction of aryl iodides with alkynes.
Green Chem. 16:2515
90. Cecchini MM, Charnay C, De Angelis F, Lamaty F, Martinez J, Colacino E (2014)
Poly(ethylene glycol)‐Based Ionic Liquids: Properties and Uses as Alternative Solvents in
Organic Synthesis and Catalysis. ChemSusChem 7:45
91. Vafaeezadeh M, Hashemi MM (2015) Polyethylene glycol (PEG) as a green solvent for carbon–carbon bond formation reactions. J. Mol. Liq. 207:73
92. Bergbreiter DE (2002) Using Soluble Polymers To Recover Catalysts and Ligands. Chem.
Rev. 102:3345
93. Han W, Liu C, Jin Z (2008) Aerobic Ligand‐Free Suzuki Coupling Reaction of Aryl Chlorides
Catalyzed by In Situ Generated Palladium Nanoparticles at Room Temperature. Adv. Synth.
Catal. 350:501
94. Burley GA, Davies DL, Griffith GA, Lee M, Singh K (2010) Cu-Catalyzed N-Alkynylation
of Imidazoles, Benzimidazoles, Indazoles, and Pyrazoles Using PEG as Solvent Medium.
J. Org. Chem. 75:980
95. Chandrasekhar S, Narsihmulu C, Sultana SS, Reddy NR (2002) Poly(ethylene glycol) (PEG)
as a Reusable Solvent Medium for Organic Synthesis. Application in the Heck Reaction. Org.
Lett. 4:4399
96. Declerck V, Colacino E, Bantreil X, Martinez J, Lamaty F. (2012) Poly(ethylene glycol) as
reaction medium for mild Mizoroki–Heck reaction in a ball-mill. Chem. Commun. 48:11778
97. Li J-H, Liu W-J, Xie Y-X (2005) Recyclable and Reusable Pd(OAc)2/DABCO/PEG-400
System for Suzuki−Miyaura Cross-Coupling Reaction. J. Org.Chem. 70:5409
98. Liu L, Zhang Y, Wang Y (2005) Phosphine-Free Palladium Acetate Catalyzed Suzuki
Reaction in Water. J. Org. Chem. 70:6122
99. Wang L, Zhang Y, Liu L, Wang Y (2006) Palladium-Catalyzed Homocoupling and CrossCoupling Reactions of Aryl Halides in Poly(ethylene glycol). J. Org. Chem. 71:1284
100. Ackermann L, Vicente R (2009) Catalytic Direct Arylations in Polyethylene Glycol (PEG):
Recyclable Palladium(0) Catalyst for C−H Bond Cleavages in the Presence of Air. Org.
Lett. 11:4922
101. Zhou Q, Wei S, Han W (2014) In Situ Generation of Palladium Nanoparticles: Ligand-Free
Palladium Catalyzed Pivalic Acid Assisted Carbonylative Suzuki Reactions at Ambient
Conditions. J. Org. Chem. 79:1454
D. S. Deshmukh et al.
Carbon Dioxide Enhances the Reactivity towards Primary Carbon–Hydrogen Bonds.
ChemCatChem 7:3254
83. Hu YL, Wu YP, Lu M (2018) Co (II)‐C12 alkyl carbon chain multi‐functional ionic liquid
immobilized on nano‐SiO2 nano‐SiO2@CoCl3‐C12IL as an efficient cooperative catalyst for
C–H activation by direct acylation of aryl halides with aldehydes. Appl. Organomet. Chem.
32:e4096
84. Cotugno P, Monopoli A, Ciminale F, Milella A, Nacci A (2014) Palladium‐Catalyzed
Cross‐Coupling of Styrenes with Aryl Methyl Ketones in Ionic Liquids: Direct Access to
Cyclopropanes. Angew. Chem. Int. Ed. 53:13563
85. Ruokonen S-K, Sanwald C, Sundvik M, Polnick S, Vyavaharkar K, Duša F, Holding AJ, King
AWT, Kilpeläinen I, Lämmerhofer M, Panula P, Wiedmer SK (2016) Effect of Ionic Liquids
on Zebrafish (Danio rerio) Viability, Behavior, and Histology; Correlation between Toxicity
and Ionic Liquid Aggregation. Environ. Sci. Technol. 50:7116
86. Kumar M, Trivedi N, Reddy CRK, Jha B (2011) Toxic Effects of Imidazolium Ionic Liquids
on the Green Seaweed Ulva lactuca: Oxidative Stress and DNA Damage. Chem. Res.
Toxicol. 24:1882
87. Stefanidis G, Stankiewicz A (eds) (2016) Alternative Energy Sources for Green Chemistry,
The Royal Society of Chemistry, Cambridge
88. Tundo P, Perosa A, Zecchini F (eds) (2007) Methods and Reagents for Green Chemistry: An
Introduction, John Wiley & Sons, Hoboken
89. Zhao H, Cheng M, Zhang J, Cai M (2014) Recyclable and reusable PdCl2(PPh3)2/PEG-2000/
H2O system for the carbonylative Sonogashira coupling reaction of aryl iodides with alkynes.
Green Chem. 16:2515
90. Cecchini MM, Charnay C, De Angelis F, Lamaty F, Martinez J, Colacino E (2014)
Poly(ethylene glycol)‐Based Ionic Liquids: Properties and Uses as Alternative Solvents in
Organic Synthesis and Catalysis. ChemSusChem 7:45
91. Vafaeezadeh M, Hashemi MM (2015) Polyethylene glycol (PEG) as a green solvent for carbon–carbon bond formation reactions. J. Mol. Liq. 207:73
92. Bergbreiter DE (2002) Using Soluble Polymers To Recover Catalysts and Ligands. Chem.
Rev. 102:3345
93. Han W, Liu C, Jin Z (2008) Aerobic Ligand‐Free Suzuki Coupling Reaction of Aryl Chlorides
Catalyzed by In Situ Generated Palladium Nanoparticles at Room Temperature. Adv. Synth.
Catal. 350:501
94. Burley GA, Davies DL, Griffith GA, Lee M, Singh K (2010) Cu-Catalyzed N-Alkynylation
of Imidazoles, Benzimidazoles, Indazoles, and Pyrazoles Using PEG as Solvent Medium.
J. Org. Chem. 75:980
95. Chandrasekhar S, Narsihmulu C, Sultana SS, Reddy NR (2002) Poly(ethylene glycol) (PEG)
as a Reusable Solvent Medium for Organic Synthesis. Application in the Heck Reaction. Org.
Lett. 4:4399
96. Declerck V, Colacino E, Bantreil X, Martinez J, Lamaty F. (2012) Poly(ethylene glycol) as
reaction medium for mild Mizoroki–Heck reaction in a ball-mill. Chem. Commun. 48:11778
97. Li J-H, Liu W-J, Xie Y-X (2005) Recyclable and Reusable Pd(OAc)2/DABCO/PEG-400
System for Suzuki−Miyaura Cross-Coupling Reaction. J. Org.Chem. 70:5409
98. Liu L, Zhang Y, Wang Y (2005) Phosphine-Free Palladium Acetate Catalyzed Suzuki
Reaction in Water. J. Org. Chem. 70:6122
99. Wang L, Zhang Y, Liu L, Wang Y (2006) Palladium-Catalyzed Homocoupling and CrossCoupling Reactions of Aryl Halides in Poly(ethylene glycol). J. Org. Chem. 71:1284
100. Ackermann L, Vicente R (2009) Catalytic Direct Arylations in Polyethylene Glycol (PEG):
Recyclable Palladium(0) Catalyst for C−H Bond Cleavages in the Presence of Air. Org.
Lett. 11:4922
101. Zhou Q, Wei S, Han W (2014) In Situ Generation of Palladium Nanoparticles: Ligand-Free
Palladium Catalyzed Pivalic Acid Assisted Carbonylative Suzuki Reactions at Ambient
Conditions. J. Org. Chem. 79:1454
D. S. Deshmukh et al.