249
3. Stiles AB, Chen F, Harrison JB, Hu X, Storm DA, Yang HX (1991) Catalytic conversion of
synthesis gas to methanol and other oxygenated products. Ind Eng Chem Res 30:811–821.
https://doi.org/10.1021/ie00053a002
4. Ma T, Imai H, Shige T, Sugio T, Li X (2015) Synthesis of hydrocarbons from H 2 -deficient
syngas in Fischer-Tropsch synthesis over Co-based catalyst coupled with Fe-based catalyst as
water-gas shift reaction. J Nano 2015:268121. https://doi.org/10.1155/2015/268121
5. Ma S, Guo X, Zhao L, Scott S, Bao X (2013) Recent progress in methane dehydroaromatization: from laboratory curiosities to promising technology. J Energy Chem 22:1–20. https://doi.
org/10.1016/S2095- 4956(13)60001- 7
6. Xi Y, Heyden A (2019) Direct oxidation of methane to methanol enabled by electronic atomic
monolayer-metal support interaction. ACS Catal 9(7):6073–6079. https://doi.org/10.1021/
acscatal.9b01619
7. Ito T, Lunsford JH (1985) Synthesis of ethylene and ethane by partial oxidation of methane
over lithium-doped magnesium oxide. Nature 314:721–722. nature.com/articles/314721b0
8. Lu YA, Xu ZS, Tian ZJ, Zhang T, Lin LW (1999) Methane aromatization in the absence of an
added oxidant and the bench scale reaction test. Catal Lett 62:215–220. https://doi.org/10.102
3/A:1019063425801
9. Wang LS, Tao LX, XieM S, Xu GF, Huang JS, Xu YD (1993) Dehydrogenation and aromatization of methane under non-oxidizing conditions. Catal Lett 21:35–41. https://doi.org/10.1007/
BF00767368
10. Majhi S, Mohanty P, Wang H, Pant KK (2013) Direct conversion of natural gas to
higher hydrocarbons: a review. J Energy Chem 22:543–554. https://doi.org/10.1016/
S2095- 4956(13)60071- 6
11. Liu S, Wang L, Ohnishi R, Ichikawa M (1999) Bifunctional catalysis of Mo/HZSM-5 in
the dehydroaromatization of methane to benzene and naphthalene XAFS/TG/DTA/MASS/
FTIR characterization and supporting effects. J Catal 181:175–188. https://doi.org/10.1006/
jcat.1998.2310
12. Kosinov N, Uslamin EA, Meng L, Parastaev A, Liu A, Hensen EJM (2019) Reversible nature
of coke formation on Mo/ZSM-5 methane dehydroaromatization catalysts. Angew Chem Int
Ed 58:7068–7072. https://doi.org/10.1002/anie.201902730
13. Schwach P, Pan X, Bao X (2017) Direct conversion of methane to value-added chemicals
over heterogeneous catalysts: challenges and prospects. Chem Rev 117:8497–8520. https://
doi.org/10.1021/acs.chemrev.6b00715
14. Ismagilov ZR, Matus EV, Tsikoza LT (2008) Direct conversion of methane on Mo/ZSM-5
catalysts to produce benzene and hydrogen: achievements and perspectives. Energy Environ
Sci 1:526–541. https://doi.org/10.1039/B810981H
15. Spivey JJ, Hutchings G (2014) Catalytic aromatization of methane. Chem Soc Rev 43:792–803.
https://doi.org/10.1039/C3CS60259A
16. Majhi S, Pant KK (2013) Direct conversion of methane with methanol toward higher hydrocarbon over Ga modified Mo/H-ZSM-5 catalyst. J Ind Eng Chem 20:2364–2369. https://doi.
org/10.1016/j.jiec.2013.10.014
17. Bijani PM, Sohrabi M, Sahebdelfar S (2012) Thermodynamic analysis of nonoxidative dehydroaromatization of methane. Chem Eng Tech 35:1–9. https://doi.org/10.1002/ceat.201100436
18. Yaws CL (1999) Chemical properties handbook: physical, thermodynamic, environmental,
transport, safety, and health related properties for organic and inorganic chemicals. McGrawHill, New York. accessengineeringlibrary.com/content/book/9780070734012
19. Kinage AK, Ohnishi R, Ichikawa M (2003) Marked enhancement of the methane dehydrocondensation toward benzene using effective Pd catalytic membrane reactor with Mo/ZSM-5.
Catal Lett 88:199–202. springer.com/article/10.1023/A:1024022124804
20. Wong ST, Xu Y, Liu W, Wang L, Guo X (1996) Methane activation without using oxidants
over supported Mo catalysts. Appl Catal A Gen 136:7–17. https://doi.org/10.1016/0926- 860
X(95)00260- Xm
Thermocatalytic Conversion of Natural Gas to Petrochemical Feedstocks…
3. Stiles AB, Chen F, Harrison JB, Hu X, Storm DA, Yang HX (1991) Catalytic conversion of
synthesis gas to methanol and other oxygenated products. Ind Eng Chem Res 30:811–821.
https://doi.org/10.1021/ie00053a002
4. Ma T, Imai H, Shige T, Sugio T, Li X (2015) Synthesis of hydrocarbons from H 2 -deficient
syngas in Fischer-Tropsch synthesis over Co-based catalyst coupled with Fe-based catalyst as
water-gas shift reaction. J Nano 2015:268121. https://doi.org/10.1155/2015/268121
5. Ma S, Guo X, Zhao L, Scott S, Bao X (2013) Recent progress in methane dehydroaromatization: from laboratory curiosities to promising technology. J Energy Chem 22:1–20. https://doi.
org/10.1016/S2095- 4956(13)60001- 7
6. Xi Y, Heyden A (2019) Direct oxidation of methane to methanol enabled by electronic atomic
monolayer-metal support interaction. ACS Catal 9(7):6073–6079. https://doi.org/10.1021/
acscatal.9b01619
7. Ito T, Lunsford JH (1985) Synthesis of ethylene and ethane by partial oxidation of methane
over lithium-doped magnesium oxide. Nature 314:721–722. nature.com/articles/314721b0
8. Lu YA, Xu ZS, Tian ZJ, Zhang T, Lin LW (1999) Methane aromatization in the absence of an
added oxidant and the bench scale reaction test. Catal Lett 62:215–220. https://doi.org/10.102
3/A:1019063425801
9. Wang LS, Tao LX, XieM S, Xu GF, Huang JS, Xu YD (1993) Dehydrogenation and aromatization of methane under non-oxidizing conditions. Catal Lett 21:35–41. https://doi.org/10.1007/
BF00767368
10. Majhi S, Mohanty P, Wang H, Pant KK (2013) Direct conversion of natural gas to
higher hydrocarbons: a review. J Energy Chem 22:543–554. https://doi.org/10.1016/
S2095- 4956(13)60071- 6
11. Liu S, Wang L, Ohnishi R, Ichikawa M (1999) Bifunctional catalysis of Mo/HZSM-5 in
the dehydroaromatization of methane to benzene and naphthalene XAFS/TG/DTA/MASS/
FTIR characterization and supporting effects. J Catal 181:175–188. https://doi.org/10.1006/
jcat.1998.2310
12. Kosinov N, Uslamin EA, Meng L, Parastaev A, Liu A, Hensen EJM (2019) Reversible nature
of coke formation on Mo/ZSM-5 methane dehydroaromatization catalysts. Angew Chem Int
Ed 58:7068–7072. https://doi.org/10.1002/anie.201902730
13. Schwach P, Pan X, Bao X (2017) Direct conversion of methane to value-added chemicals
over heterogeneous catalysts: challenges and prospects. Chem Rev 117:8497–8520. https://
doi.org/10.1021/acs.chemrev.6b00715
14. Ismagilov ZR, Matus EV, Tsikoza LT (2008) Direct conversion of methane on Mo/ZSM-5
catalysts to produce benzene and hydrogen: achievements and perspectives. Energy Environ
Sci 1:526–541. https://doi.org/10.1039/B810981H
15. Spivey JJ, Hutchings G (2014) Catalytic aromatization of methane. Chem Soc Rev 43:792–803.
https://doi.org/10.1039/C3CS60259A
16. Majhi S, Pant KK (2013) Direct conversion of methane with methanol toward higher hydrocarbon over Ga modified Mo/H-ZSM-5 catalyst. J Ind Eng Chem 20:2364–2369. https://doi.
org/10.1016/j.jiec.2013.10.014
17. Bijani PM, Sohrabi M, Sahebdelfar S (2012) Thermodynamic analysis of nonoxidative dehydroaromatization of methane. Chem Eng Tech 35:1–9. https://doi.org/10.1002/ceat.201100436
18. Yaws CL (1999) Chemical properties handbook: physical, thermodynamic, environmental,
transport, safety, and health related properties for organic and inorganic chemicals. McGrawHill, New York. accessengineeringlibrary.com/content/book/9780070734012
19. Kinage AK, Ohnishi R, Ichikawa M (2003) Marked enhancement of the methane dehydrocondensation toward benzene using effective Pd catalytic membrane reactor with Mo/ZSM-5.
Catal Lett 88:199–202. springer.com/article/10.1023/A:1024022124804
20. Wong ST, Xu Y, Liu W, Wang L, Guo X (1996) Methane activation without using oxidants
over supported Mo catalysts. Appl Catal A Gen 136:7–17. https://doi.org/10.1016/0926- 860
X(95)00260- Xm
Thermocatalytic Conversion of Natural Gas to Petrochemical Feedstocks…