8. Wickramasinhe LD, Mazumder S, Gonawala S, Madusanka Perera M, Baydoun H, Thapa B,
Li L, Xis L, Mao G, Zhou Z, Schlegel HB, Verani CN (2014) The mechanisms of rectification in
Au| molecule| Au devices based on Langmuir-Blodgett monolayers of iron (III) and copper
(II) surfactants. Angew Chem Int Ed 53:14462–14467
9. Lanznaster M, Hratchian HP, Heeg MJ, McGarvey BR, Schlegel HB, Verani CN (2006)
Structural and electronic behavior of unprecedented five-coordinate iron(III) and gallium(III)
complexes with a new phenol-rich electroactive ligand. Inorg Chem 45:955–957
10. Chetty R, Christensen PA, Golding BT (2003) In situ FTIR studies on the electrochemical
reduction of halogenated phenols. ChemComm 8:984–985
11. Villalba M, Mendez De Leo LP, Calvo EJ (2014) PM-IRRA spectroelectrochemistry of
hexacyanoferrate films in layer-by-layer polyelectrolyte multilayers. ChemElectroChem
1:195–199
12. Nakamoto K (1978) Infrared and Raman spectra of inorganic and coordination compounds, 3rd
edn. Wiley, New York
13. Kulesza PJ, Malik MA, Zamponi S, Berrettoni M, Marassi R (1995) Electrolyte-cation-dependent coloring, electrochromism and thermochromism of cobalt (II) hexacyanoferrate (III, II)
films. J Electroanal Chem 397:287–292
14. Joseph J, Gomathi H, Rao GP (1991) Electrodes modified with cobalt hexacyanoferrate. J
Electroanal Chem 304:263–269
15. Brand I, Rüdiger C, Hingerl K, Portenkirchner E, Kunze-Liebhäuser J (2015) Compact titanium
oxycarbide: a new substrate for quantitative analysis of molecular films by means of infrared
reflection absorption spectroscopy. J Phys Chem C 119:13767–13776
16. Dongmo S, Wittstock G, Christoffers J, Brand I (2017) In situ determination of potential-driven
structural changes in a redox-active plumbagin polymer film on a glassy carbon electrode using
PM IRRAS under electrochemical control. Electrochim Acta 255:298–308
17. Vieira L, Schennach R, Gollas B (2015) In situ PM-IRRAS of a glassy carbon electrode/deep
eutectic solvent interface. Phys Chem Chem Phys 17:12870–12880
18. Monyoncho EA, Steinmann SN, Michel C, Baranova EA, Woo TK, Sautet P (2016) Ethanol
electro-oxidation on palladium revisited using polarization modulation infrared reflection
absorption spectroscopy (PM-IRRAS) and density functional theory (DFT): why is it difficult
to break the CÀC bond? ACS Catal 6:4894–4906
19. Monyoncho EA, Zamlynny V, Woo TK, Baranova EA (2018) The utility of polarization
modulation infrared reflection absorption spectroscopy (PM-IRRAS) in surface and in situ
studies: new data processing and presentation. Analyst (Cambridge, UK) 143:2563–2573
20. Alkire RC, Bartlett PN, Lipkowski J (2015) Electrochemistry of carbon electrodes. Weinheim,
Willey
21. Porter MD, Bright TB, Allara DL (1986) Quantitative aspects of infrared external reflection
spectroscopy: polymer/glassy carbon interface. Anal Chem 58:2461–2465
22. Dongmo S, Witt J, Wittstock G (2015) Electropolymerization of quinone-polymers onto grafted
quinone monolayers: a route towards non-passivating, catalytically active films. Electrochim
Acta 155:474–482
23. Moncelli MR, Becucci L, Nelson A, Guidelli R (1996) Electrochemical modeling of electron
and proton transfer to ubiquinone-10 in a self-assembled phospholipid monolayer. Biophys J
70:2716–2726
24. Buffeteau T, Desbat B, Blaudez D, Turlet JM (2000) Calibration procedure to derive IRRAS
spectra from PM IRRAS spectra. Appl Spectrosc 54:1646–1650
25. Buffeteau T, Desbat B, Turlet JM (1991) Polarization modulation FT-IR spectroscopy of
surfaces and ultra-thin films: experimental procedure and quantitative analysis. Appl Spectrosc
45:380–388
26. Zamlynny V, Lipkowski J (2006) Quantitative SNIFTIRS and PM IRRAS of organic molecules
at electrode surfaces. In: Alkire RC, Kolb DM, Lipkowski J, Ross PN (eds) Advances in
electrochemical science and engineering, Diffraction and spectroscopic methods in electrochemistry, vol 9. Wiley-VCH, Weinheim, pp 315–376
114
4 In Situ PM IRRAS Studies of Redox-spi1;Active Molecular Films...
Li L, Xis L, Mao G, Zhou Z, Schlegel HB, Verani CN (2014) The mechanisms of rectification in
Au| molecule| Au devices based on Langmuir-Blodgett monolayers of iron (III) and copper
(II) surfactants. Angew Chem Int Ed 53:14462–14467
9. Lanznaster M, Hratchian HP, Heeg MJ, McGarvey BR, Schlegel HB, Verani CN (2006)
Structural and electronic behavior of unprecedented five-coordinate iron(III) and gallium(III)
complexes with a new phenol-rich electroactive ligand. Inorg Chem 45:955–957
10. Chetty R, Christensen PA, Golding BT (2003) In situ FTIR studies on the electrochemical
reduction of halogenated phenols. ChemComm 8:984–985
11. Villalba M, Mendez De Leo LP, Calvo EJ (2014) PM-IRRA spectroelectrochemistry of
hexacyanoferrate films in layer-by-layer polyelectrolyte multilayers. ChemElectroChem
1:195–199
12. Nakamoto K (1978) Infrared and Raman spectra of inorganic and coordination compounds, 3rd
edn. Wiley, New York
13. Kulesza PJ, Malik MA, Zamponi S, Berrettoni M, Marassi R (1995) Electrolyte-cation-dependent coloring, electrochromism and thermochromism of cobalt (II) hexacyanoferrate (III, II)
films. J Electroanal Chem 397:287–292
14. Joseph J, Gomathi H, Rao GP (1991) Electrodes modified with cobalt hexacyanoferrate. J
Electroanal Chem 304:263–269
15. Brand I, Rüdiger C, Hingerl K, Portenkirchner E, Kunze-Liebhäuser J (2015) Compact titanium
oxycarbide: a new substrate for quantitative analysis of molecular films by means of infrared
reflection absorption spectroscopy. J Phys Chem C 119:13767–13776
16. Dongmo S, Wittstock G, Christoffers J, Brand I (2017) In situ determination of potential-driven
structural changes in a redox-active plumbagin polymer film on a glassy carbon electrode using
PM IRRAS under electrochemical control. Electrochim Acta 255:298–308
17. Vieira L, Schennach R, Gollas B (2015) In situ PM-IRRAS of a glassy carbon electrode/deep
eutectic solvent interface. Phys Chem Chem Phys 17:12870–12880
18. Monyoncho EA, Steinmann SN, Michel C, Baranova EA, Woo TK, Sautet P (2016) Ethanol
electro-oxidation on palladium revisited using polarization modulation infrared reflection
absorption spectroscopy (PM-IRRAS) and density functional theory (DFT): why is it difficult
to break the CÀC bond? ACS Catal 6:4894–4906
19. Monyoncho EA, Zamlynny V, Woo TK, Baranova EA (2018) The utility of polarization
modulation infrared reflection absorption spectroscopy (PM-IRRAS) in surface and in situ
studies: new data processing and presentation. Analyst (Cambridge, UK) 143:2563–2573
20. Alkire RC, Bartlett PN, Lipkowski J (2015) Electrochemistry of carbon electrodes. Weinheim,
Willey
21. Porter MD, Bright TB, Allara DL (1986) Quantitative aspects of infrared external reflection
spectroscopy: polymer/glassy carbon interface. Anal Chem 58:2461–2465
22. Dongmo S, Witt J, Wittstock G (2015) Electropolymerization of quinone-polymers onto grafted
quinone monolayers: a route towards non-passivating, catalytically active films. Electrochim
Acta 155:474–482
23. Moncelli MR, Becucci L, Nelson A, Guidelli R (1996) Electrochemical modeling of electron
and proton transfer to ubiquinone-10 in a self-assembled phospholipid monolayer. Biophys J
70:2716–2726
24. Buffeteau T, Desbat B, Blaudez D, Turlet JM (2000) Calibration procedure to derive IRRAS
spectra from PM IRRAS spectra. Appl Spectrosc 54:1646–1650
25. Buffeteau T, Desbat B, Turlet JM (1991) Polarization modulation FT-IR spectroscopy of
surfaces and ultra-thin films: experimental procedure and quantitative analysis. Appl Spectrosc
45:380–388
26. Zamlynny V, Lipkowski J (2006) Quantitative SNIFTIRS and PM IRRAS of organic molecules
at electrode surfaces. In: Alkire RC, Kolb DM, Lipkowski J, Ross PN (eds) Advances in
electrochemical science and engineering, Diffraction and spectroscopic methods in electrochemistry, vol 9. Wiley-VCH, Weinheim, pp 315–376
114
4 In Situ PM IRRAS Studies of Redox-spi1;Active Molecular Films...