284
Table 11.1 Commercial activated carbons for dyes wastewaters treatment
Starting material Preparation of adsorbents
Adsorbate type
and name
Additional
information
Results
References
Commercial
activated carbon
None
Reactive: reactive
turquoise blue QG
Surface
area = 618.7 m
2
/g
Max. sorption capacity = 140 mg/g
(pH = 2, T = 30 °C), the best fit for the
kinetic data – pseudo second-order model,
process was exothermic, the main
mechanism was physisorption
Schimmel
et al.
(2010)
Panreac, Fagron None
Mordant: mordant
blue 9
Surface area of
Fagron = 514 m
2
/g
Surface area of
Panreac = 296 m
2
/g
Max. sorption capacities:
Fagron – 221 mg/g
Fagron – 80,300 mg/g
Fagron – 200,490 mg/g
Panreac– 213 mg/g
Martins
and Nunes
(2015)
Panreac, Fagron Oxidant acid treatment (20 mL of
4.6 mol/L HNO
3 ), heated at 60 °C,
washed with deionized water and dry
at room temperature (24 h)
Max. sorption capacities:
Fagron – HNO
3 180 mg/g
Panreac – HNO
3 93 mg/g
Norit ROX 0.8
None
Reactive: red,
yellow, blue
Direct: red,
yellow, blue
Acid: red, rellow,
blue
Basic: red, yellow,
blue
Surface
area = 833–
1032 m
2
/g
Percentage removal of dyes were
following:
Reactive: blue 57%, red 47%, yellow
34%;
Direct: red 20%, yellow 9%, blue 27%;
Acid: red 43 %, yellow 78%, blue 45%;
Basic: red 87%, yellow 90%, blue 99%
Pereira
et al.
(2003)
Norit ROX 0.8
Oxidation with 5 mol/L HNO
3 , 3 h,
T – boiling
Norit ROX 0.8
Oxidation with 5 mol/L HNO
3 ,
3 + 3 h, T – boiling
Norit ROX 0.8
Oxidation
with 1 mol/L H
2 O
2 , T – room
Activated carbon Reduction with NH
3 , T = 200 °C
Activated carbon Thermal: under N
2 flow, T = 700 °C,
+1 h under dry air flow, T – room
Activated carbon Thermal: under H
2 flow, T = 700 °C,
+1 h under dry air flow, T – room
Activated carbon Thermal: under H
2 flow, T = 900 °C,
+1 h under dry air flow, T – room
A. Wołowicz and M. Wawrzkiewicz
Table 11.1 Commercial activated carbons for dyes wastewaters treatment
Starting material Preparation of adsorbents
Adsorbate type
and name
Additional
information
Results
References
Commercial
activated carbon
None
Reactive: reactive
turquoise blue QG
Surface
area = 618.7 m
2
/g
Max. sorption capacity = 140 mg/g
(pH = 2, T = 30 °C), the best fit for the
kinetic data – pseudo second-order model,
process was exothermic, the main
mechanism was physisorption
Schimmel
et al.
(2010)
Panreac, Fagron None
Mordant: mordant
blue 9
Surface area of
Fagron = 514 m
2
/g
Surface area of
Panreac = 296 m
2
/g
Max. sorption capacities:
Fagron – 221 mg/g
Fagron – 80,300 mg/g
Fagron – 200,490 mg/g
Panreac– 213 mg/g
Martins
and Nunes
(2015)
Panreac, Fagron Oxidant acid treatment (20 mL of
4.6 mol/L HNO
3 ), heated at 60 °C,
washed with deionized water and dry
at room temperature (24 h)
Max. sorption capacities:
Fagron – HNO
3 180 mg/g
Panreac – HNO
3 93 mg/g
Norit ROX 0.8
None
Reactive: red,
yellow, blue
Direct: red,
yellow, blue
Acid: red, rellow,
blue
Basic: red, yellow,
blue
Surface
area = 833–
1032 m
2
/g
Percentage removal of dyes were
following:
Reactive: blue 57%, red 47%, yellow
34%;
Direct: red 20%, yellow 9%, blue 27%;
Acid: red 43 %, yellow 78%, blue 45%;
Basic: red 87%, yellow 90%, blue 99%
Pereira
et al.
(2003)
Norit ROX 0.8
Oxidation with 5 mol/L HNO
3 , 3 h,
T – boiling
Norit ROX 0.8
Oxidation with 5 mol/L HNO
3 ,
3 + 3 h, T – boiling
Norit ROX 0.8
Oxidation
with 1 mol/L H
2 O
2 , T – room
Activated carbon Reduction with NH
3 , T = 200 °C
Activated carbon Thermal: under N
2 flow, T = 700 °C,
+1 h under dry air flow, T – room
Activated carbon Thermal: under H
2 flow, T = 700 °C,
+1 h under dry air flow, T – room
Activated carbon Thermal: under H
2 flow, T = 900 °C,
+1 h under dry air flow, T – room
A. Wołowicz and M. Wawrzkiewicz
