References
Chai CP, Zhu XQ, Wang P, Ren MQ, Chen XF, Xu YD, Fan XH, Ye C, Chen EQ, Zhou QF (2007)
Synthesis and phase structures of mesogen-jacketed liquid crystalline polymers containing
1,3,4-oxadiazole based side chains. Macromolecules 40:9361–9370
Chen L, Chen YW, Zha DJ, Yang Y (2006a) Synthesis and properties of polyacetylenes with
directly attached bis(4-alkoxyphenyl)terephthalate mesogens as pendants. J Polym Sci Part A
Polym Chem 44:2499–2509
Chen XF, Tenneti KK, Li CY, Bai YW, Zhou R, Wan XH, Fan XH, Zhou QF (2006b) Design,
synthesis, and characterization of bent-core mesogen-jacketed liquid crystalline polymers.
Macromolecules 39:517–527
Chen S, Gao LC, Zhao XD, Chen XF, Fan XH, Xie PY, Zhou QF (2007) Synthesis and properties of
mesogen-jacketed liquid crystalline polymers with asymmetry mesogenic core. Macromolecules 40:5718–5725
Chen S, Zhang L-Y, Gao L-C, Chen X-F, Fan X-H, Shen Z, Zhou Q-F (2009) Influence of alkoxy
tail length and unbalanced mesogenic core on phase behavior of mesogen-jacketed liquid
crystalline polymers. J Polym Sci Part A Polym Chem 47:505–514
HN
O
O
SO3Na
HN
NaO3S
HN
O
O
SO3Na
NH
NaO 3 S
SPAS
PSPAS
O
O
O
SO3Na
O
NaO3S
O
O
O
SO3Na
O
NaO3S
SPCS
PSPCS
SO3
+
N
C12H25
N
C16H33
H3N
OC12H25
OC12H25
OC12H25
SO3
N
C12H25
r
SO3
SO3
N
C16H33
H3N
OC12H25
OC12H25
OC12H25
r
r
PSPAS/PSPCS
PSPAS-C12/PSPCS-C12
PSPAS-C16/PSPCS-C16
PSPAS-Ar-3C12/PSPCS-Ar-3C12
r : degree of neutralization
DMF, H2O
24 h
DMF, H2O
24 h
x
x
Scheme 14 Preparation of MJLCPs by ionic interaction (Cheng et al. 2011b)
2 Mesogen-Jacketed Liquid Crystalline Polymers: Molecular Design and. . .
55