Percec V, Heck J, Tomazos D, Falkenberg F, Blackwell H, Ungar G (1993) Self-assembly of tapershaped monoesters of oligo(ethylene oxide) with 3,4,5-tris(p-dodecyloxybenzyloxy)benzoic
acid and of their polymethacrylates into tubular supramolecular architectures displaying a
columnar mesophase. J Chem Soc Perkin Trans 1:2799–2811
Percec V, Schlueter D, Ungar G, Cheng SZD, Zhang A (1998c) Hierarchical control of internal
superstructure, diameter, and stability of supramolecular and macromolecular columns generated from tapered monodendritic building blocks. Macromolecules 31:1745–1762
Percec V, Heck J, Lee M, Ungar G, Alvarez-Castillo A (1992a) Poly{2-vinyloxyethyl 3,4,5-tris
[4-(n-dodecanyloxy)benzyloxy]benzoate}: a self-assembled supramolecular polymer similar to
tobacco mosaic virus. J Mater Chem 2:1033–1039
Percec V, Holerca MN, Magonov SN, DJP Y, Ungar G, Duan H, Hudson SD (2001) Poly
(oxazolines)s with tapered minidendritic side groups. The simplest cylindrical models to
investigate the formation of two-dimensional and three-dimensional order by direct visualization. Biomacromolecules 2:706–728
Percec V, Lee M, Heck J, Blackwell HE, Ungar G, Alvarez-Castillo A (1992b) Reentrant isotropic
phase in a supramolecular disc-like oligomer of 4-[3,4,5-tris(n-dodecyloxy)benzoyloxy]-40 -[(2-vinyloxy)ethoxy]biphenyl. J Mater Chem 2:931–938
Percec V, Schlueter D (1997) Mechanistic investigations on the formation of supramolecular
cylindrical shaped oligomers and polymers by living ring opening metathesis polymerization
of a 7-oxanorbornene monomer substituted with two tapered monodendrons. Macromolecules
30:5783–5790
Ronda JC, Reina JA, Cádiz V, Giamberini M, Nicolais L (2003) Self-organized liquid-crystalline
polyethers obtained by grafting tapered mesogenic groups onto poly(epichlorohydrin): toward
biomimetic ion channels. J Polym Sci Part A Polym Chem 41:2918–2929
Rosen BM, Wilson CJ, Wilson DA, Peterca M, Imam MR, Percec V (2009) Dendron-mediated selfassembly, disassembly, and self-organization of complex systems. Chem Rev 109:6275–6540
Schilling FC, Bovey FA, Davis DD, Lovinger AJ, Macgregor RB Jr, Walsh CA, Zeigler JM (1989a)
The effect of pressure on the solid-state structure and UV-visible absorption spectra of symmetrically substituted poly(di-n-alkylsilylenes). Macromolecules 22:4645–4648
Schilling FC, Bovey FA, Lovinger AJ, Zeigler JM (1986) Characterization of poly(di-nhexylsilane) in the solid state. II. Carbon-13 and silicon-29 magic-angle spinning NMR studies.
Macromolecules 19:2660–2663
Schilling FC, Lovinger AJ, Zeigler JM, Davis DD, Bovey FA (1989b) Solid-state structures and
thermochromism of poly(di-n-butylsilylene) and poly(di-n-pentylsilylene). Macromolecules
22:3055–3063
Seitz M, Plesnivy T, Schimossek K, Edelmann M, Ringsdorf H (1996) Formation of hexagonal
columnar mesophases by linear and branched oligo- and polyamides. Macromolecules
29:6560–6574
Sirlin C, Bosio L, Simon J (1987) Spinal columnar liquid crystals: polymeric octasubstituted [small
micro]-oxo-(phthalocyaninato)tin(IV). J Chem Soc Chem Commun 5:379–380
Sworen JC, Smith JA, Wagener KB, Baugh LS, Rucker SP (2003) Modeling random methyl
branching in ethylene/propylene copolymers using metathesis chemistry: synthesis and thermal
behavior. J Am Chem Soc 125:2228–2240
Tahar-Djebbar I, Nekelson F, Heinrich B, Donnio B, Guillon D, Kreher D, Mathevet F, Attias AJ
(2011) Lamello-columnar mesophase formation in a side-chain liquid crystal π-conjugated
polymer architecture. Chem Mater 23:4653–4656
Tang H, Sun S, Wu J, Wu P, Wan X (2010) Conformational changes in novel thermotropic liquid
crystalline polymer without conventional mesogens: a Raman spectroscopic investigation.
Polymer 51:5482–5489
Tashiro K, Sasaki S, Kobayashi M (1996) Structural investigation of orthorhombic-to-hexagonal
phase transition in polyethylene crystal: the experimental confirmation of the conformationally
disordered structure by X-ray diffraction and infrared/Raman spectroscopic measurements.
Macromolecules 29:7460–7469
5 Columnar Phase-Forming Polymers
145
acid and of their polymethacrylates into tubular supramolecular architectures displaying a
columnar mesophase. J Chem Soc Perkin Trans 1:2799–2811
Percec V, Schlueter D, Ungar G, Cheng SZD, Zhang A (1998c) Hierarchical control of internal
superstructure, diameter, and stability of supramolecular and macromolecular columns generated from tapered monodendritic building blocks. Macromolecules 31:1745–1762
Percec V, Heck J, Lee M, Ungar G, Alvarez-Castillo A (1992a) Poly{2-vinyloxyethyl 3,4,5-tris
[4-(n-dodecanyloxy)benzyloxy]benzoate}: a self-assembled supramolecular polymer similar to
tobacco mosaic virus. J Mater Chem 2:1033–1039
Percec V, Holerca MN, Magonov SN, DJP Y, Ungar G, Duan H, Hudson SD (2001) Poly
(oxazolines)s with tapered minidendritic side groups. The simplest cylindrical models to
investigate the formation of two-dimensional and three-dimensional order by direct visualization. Biomacromolecules 2:706–728
Percec V, Lee M, Heck J, Blackwell HE, Ungar G, Alvarez-Castillo A (1992b) Reentrant isotropic
phase in a supramolecular disc-like oligomer of 4-[3,4,5-tris(n-dodecyloxy)benzoyloxy]-40 -[(2-vinyloxy)ethoxy]biphenyl. J Mater Chem 2:931–938
Percec V, Schlueter D (1997) Mechanistic investigations on the formation of supramolecular
cylindrical shaped oligomers and polymers by living ring opening metathesis polymerization
of a 7-oxanorbornene monomer substituted with two tapered monodendrons. Macromolecules
30:5783–5790
Ronda JC, Reina JA, Cádiz V, Giamberini M, Nicolais L (2003) Self-organized liquid-crystalline
polyethers obtained by grafting tapered mesogenic groups onto poly(epichlorohydrin): toward
biomimetic ion channels. J Polym Sci Part A Polym Chem 41:2918–2929
Rosen BM, Wilson CJ, Wilson DA, Peterca M, Imam MR, Percec V (2009) Dendron-mediated selfassembly, disassembly, and self-organization of complex systems. Chem Rev 109:6275–6540
Schilling FC, Bovey FA, Davis DD, Lovinger AJ, Macgregor RB Jr, Walsh CA, Zeigler JM (1989a)
The effect of pressure on the solid-state structure and UV-visible absorption spectra of symmetrically substituted poly(di-n-alkylsilylenes). Macromolecules 22:4645–4648
Schilling FC, Bovey FA, Lovinger AJ, Zeigler JM (1986) Characterization of poly(di-nhexylsilane) in the solid state. II. Carbon-13 and silicon-29 magic-angle spinning NMR studies.
Macromolecules 19:2660–2663
Schilling FC, Lovinger AJ, Zeigler JM, Davis DD, Bovey FA (1989b) Solid-state structures and
thermochromism of poly(di-n-butylsilylene) and poly(di-n-pentylsilylene). Macromolecules
22:3055–3063
Seitz M, Plesnivy T, Schimossek K, Edelmann M, Ringsdorf H (1996) Formation of hexagonal
columnar mesophases by linear and branched oligo- and polyamides. Macromolecules
29:6560–6574
Sirlin C, Bosio L, Simon J (1987) Spinal columnar liquid crystals: polymeric octasubstituted [small
micro]-oxo-(phthalocyaninato)tin(IV). J Chem Soc Chem Commun 5:379–380
Sworen JC, Smith JA, Wagener KB, Baugh LS, Rucker SP (2003) Modeling random methyl
branching in ethylene/propylene copolymers using metathesis chemistry: synthesis and thermal
behavior. J Am Chem Soc 125:2228–2240
Tahar-Djebbar I, Nekelson F, Heinrich B, Donnio B, Guillon D, Kreher D, Mathevet F, Attias AJ
(2011) Lamello-columnar mesophase formation in a side-chain liquid crystal π-conjugated
polymer architecture. Chem Mater 23:4653–4656
Tang H, Sun S, Wu J, Wu P, Wan X (2010) Conformational changes in novel thermotropic liquid
crystalline polymer without conventional mesogens: a Raman spectroscopic investigation.
Polymer 51:5482–5489
Tashiro K, Sasaki S, Kobayashi M (1996) Structural investigation of orthorhombic-to-hexagonal
phase transition in polyethylene crystal: the experimental confirmation of the conformationally
disordered structure by X-ray diffraction and infrared/Raman spectroscopic measurements.
Macromolecules 29:7460–7469
5 Columnar Phase-Forming Polymers
145
