1 3
Topics in Current Chemistry (2019) 377:22
Acknowledgements The authors are grateful to Universidad Nacional del Litoral (UNL, Project
PIC50420150100009LI), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET, Project PIP-2015 0100093), and Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT, Project PICT-2015-2651, Project PICT 2014-1020) for the financial support. They also thank Claudia M.
Romani for her technical assistance.
References
1. Alfano OM, Cassano AE (2009) In De Lasa H, Serrano-Rosales B (eds) Advances in chemical
engineering, vol. 36: Photocatalytic Technologies, pp 229–287, Elsevier, New York
2. Imoberdorf GE, Irazoqui HA, Cassano AE, Alfano OM (2005) Photocatalytic degradation of tetrachloroethylene in gas phase on TiO 2 films: a kinetic study. Ind Eng Chem Res
44:6075–6085
3. Alfano OM, Cabrera MI, Cassano AE (1997) Photocatalytic reactions involving hydroxyl radical
attack I. Reaction kinetics formulation with explicit photon absorption effects. J Catal 172:370–379
4. Muñoz-Batista MJ, Ballari MM, Kubacka A, Alfano OM, Fernández-García M (2019) Braiding kinetics and spectroscopy in photo-catalysis: the spectro-kinetic approach. Chem Soc Rev
48:637–682
5. Turchi CS, Ollis DF (1990) Photocatalytic degradation of organic water contamination: mechanisms involving hydroxyl radical attack. J Catal 122:178–192
6. Satuf ML, Brandi RJ, Cassano AE, Alfano OM (2008) Photocatalytic degradation of 4-chlorophenol: a kinetic study. Appl Catal B Environ 82:37–49
7. Marugán J, van Grieken R, Cassano AE, Alfano OM (2008) Intrinsic kinetic modeling with
explicit radiation absorption effects of the photocatalytic oxidation of cyanide with TiO 2 and silicasupported TiO 2 suspensions. Appl Catal B Environ 85:48–60
8. Manassero A, Satuf ML, Alfano OM (2015) Kinetic modeling of the photocatalytic degradation of
clofibric acid in a slurry reactor. Environ Sci Pollut Res 22:926–937
9. Tolosana-Moranchel A, Casas JA, Carbajo J, Faraldos M, Bahamonde A (2017) Influence of TiO 2
optical parameters in a slurry photocatalytic reactor: kinetic modelling. Appl Catal B Environ
200:164–173
10. Mueses MA, Machuca-Martinez F, Li Puma G (2013) Effective quantum yield and reaction rate
model for evaluation of photocatalytic degradation of water contaminants in heterogeneous pilotscale solar photoreactors. Chem Eng J 215–216:937–947
11. Brandi RJ, Rintoul G, Alfano OM, Cassano AE (2002) Photocatalytic reactors. Reaction kinetics in
a flat plate solar simulator. Catal Today 76:161–175
12. Zalazar CS, Romero RL, Martín CA, Cassano AE (2005) Photocatalytic intrinsic reaction kinetics
I: mineralization of dichloroacetic acid. Chem Eng Sci 60:5240–5254
13. Zalazar CS, Romero RL, Martín CA, Cassano AE (2005) Photocatalytic intrinsic reaction kinetics.
II: effects of oxygen concentration on the kinetics of the photocatalytic degradation of dichloroacetic acid. Chem Eng Sci 60:4311–4322
14. Ballari MM, Alfano OM, Cassano AE (2009) Photocatalytic degradation of dichloroacetic acid. A
kinetic study with a mechanistically based reaction model. Ind Eng Chem Res 48:1847–1858
15. Minero C, Vione D (2006) A quantitative evaluation of the photocatalytic performance of TiO 2
slurries. Appl Catal B Environ 67:257–269
16. Camera-Roda G, Augugliaro V, Cardillo AG, Loddo V, Palmisano L, Parrino F, Santarelli F (2015)
A reaction engineering approach to kinetic analysis of photocatalytic reactions in slurry system.
Catal Today 259:87–96
17. Camera-Roda G, Loddo V, Palmisano L, Parrino F (2017) Guidelines for the assessment of the rate
law of slurry photocatalytic reactions. Catal Today 281:221–230
18. Casado C, Marugán J, Timmers R, Muñoz M, van Grieken R (2017) Comprehensive multiphysics
modeling of photocatalytic processes by computational fluid dynamics based on intrinsic kinetic
parameters determined in a differential photoreactor. Chem Eng J 310:368–380
297
Reprinted from the journal
Topics in Current Chemistry (2019) 377:22
Acknowledgements The authors are grateful to Universidad Nacional del Litoral (UNL, Project
PIC50420150100009LI), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET, Project PIP-2015 0100093), and Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT, Project PICT-2015-2651, Project PICT 2014-1020) for the financial support. They also thank Claudia M.
Romani for her technical assistance.
References
1. Alfano OM, Cassano AE (2009) In De Lasa H, Serrano-Rosales B (eds) Advances in chemical
engineering, vol. 36: Photocatalytic Technologies, pp 229–287, Elsevier, New York
2. Imoberdorf GE, Irazoqui HA, Cassano AE, Alfano OM (2005) Photocatalytic degradation of tetrachloroethylene in gas phase on TiO 2 films: a kinetic study. Ind Eng Chem Res
44:6075–6085
3. Alfano OM, Cabrera MI, Cassano AE (1997) Photocatalytic reactions involving hydroxyl radical
attack I. Reaction kinetics formulation with explicit photon absorption effects. J Catal 172:370–379
4. Muñoz-Batista MJ, Ballari MM, Kubacka A, Alfano OM, Fernández-García M (2019) Braiding kinetics and spectroscopy in photo-catalysis: the spectro-kinetic approach. Chem Soc Rev
48:637–682
5. Turchi CS, Ollis DF (1990) Photocatalytic degradation of organic water contamination: mechanisms involving hydroxyl radical attack. J Catal 122:178–192
6. Satuf ML, Brandi RJ, Cassano AE, Alfano OM (2008) Photocatalytic degradation of 4-chlorophenol: a kinetic study. Appl Catal B Environ 82:37–49
7. Marugán J, van Grieken R, Cassano AE, Alfano OM (2008) Intrinsic kinetic modeling with
explicit radiation absorption effects of the photocatalytic oxidation of cyanide with TiO 2 and silicasupported TiO 2 suspensions. Appl Catal B Environ 85:48–60
8. Manassero A, Satuf ML, Alfano OM (2015) Kinetic modeling of the photocatalytic degradation of
clofibric acid in a slurry reactor. Environ Sci Pollut Res 22:926–937
9. Tolosana-Moranchel A, Casas JA, Carbajo J, Faraldos M, Bahamonde A (2017) Influence of TiO 2
optical parameters in a slurry photocatalytic reactor: kinetic modelling. Appl Catal B Environ
200:164–173
10. Mueses MA, Machuca-Martinez F, Li Puma G (2013) Effective quantum yield and reaction rate
model for evaluation of photocatalytic degradation of water contaminants in heterogeneous pilotscale solar photoreactors. Chem Eng J 215–216:937–947
11. Brandi RJ, Rintoul G, Alfano OM, Cassano AE (2002) Photocatalytic reactors. Reaction kinetics in
a flat plate solar simulator. Catal Today 76:161–175
12. Zalazar CS, Romero RL, Martín CA, Cassano AE (2005) Photocatalytic intrinsic reaction kinetics
I: mineralization of dichloroacetic acid. Chem Eng Sci 60:5240–5254
13. Zalazar CS, Romero RL, Martín CA, Cassano AE (2005) Photocatalytic intrinsic reaction kinetics.
II: effects of oxygen concentration on the kinetics of the photocatalytic degradation of dichloroacetic acid. Chem Eng Sci 60:4311–4322
14. Ballari MM, Alfano OM, Cassano AE (2009) Photocatalytic degradation of dichloroacetic acid. A
kinetic study with a mechanistically based reaction model. Ind Eng Chem Res 48:1847–1858
15. Minero C, Vione D (2006) A quantitative evaluation of the photocatalytic performance of TiO 2
slurries. Appl Catal B Environ 67:257–269
16. Camera-Roda G, Augugliaro V, Cardillo AG, Loddo V, Palmisano L, Parrino F, Santarelli F (2015)
A reaction engineering approach to kinetic analysis of photocatalytic reactions in slurry system.
Catal Today 259:87–96
17. Camera-Roda G, Loddo V, Palmisano L, Parrino F (2017) Guidelines for the assessment of the rate
law of slurry photocatalytic reactions. Catal Today 281:221–230
18. Casado C, Marugán J, Timmers R, Muñoz M, van Grieken R (2017) Comprehensive multiphysics
modeling of photocatalytic processes by computational fluid dynamics based on intrinsic kinetic
parameters determined in a differential photoreactor. Chem Eng J 310:368–380
297
Reprinted from the journal