1 3
Topics in Current Chemistry (2019) 377:27
23. Afif A, Radenahmad N, Cheok Q et al (2016) Ammonia-fed fuel cells: a comprehensive review.
Renew Sustain Energy Rev 60:822–835
24. Chowdhury AD, Agnihotri N, De A (2015) Hydrolysis of sodium borohydride using Ru-CoPEDOT nanocomposites as catalyst. Chem Eng J 264:531–537
25. Dalebrook AF, Gan W, Grasemann M et al (2013) Hydrogen storage: beyond conventional methods. Chem Commun 49:8735–8751
26. Preuster P, Papp C, Wasserscheid P (2017) Liquid Organic Hydrogen Carriers (LOHCs): toward a
hydrogen-free hydrogen economy. Acc Chem Res 50:74–85
27. Niermann M, Beckendorff A, Kaltschmitt M, Bonhoff K (2019) Liquid Organic Hydrogen Carrier (LOHC)—assessment based on chemical and economic properties. Int J Hydrogen Energy
44:6631–6654
28. Hu P, Fogler E, Diskin-Posner Y et al (2015) A novel liquid organic hydrogen carrier system based
on catalytic peptide formation and hydrogenation. Nat Commun 6:6859
29. Mori K, Dojo M, Yamashita H (2013) Pd and Pd–Ag nanoparticles within a macroreticular basic
resin: an efficient catalyst for hydrogen production from formic acid decomposition. ACS Catal
3:1114–1119
30. Navlani-García M, Mori K, Kuwahara Y, Yamashita H (2018) Recent strategies targeting efficient
hydrogen production from chemical hydrogen storage materials over carbon-supported catalysts.
NPG Asia Mater 2018:1–16
31. Navlani-García M, Mori K, Salinas-Torres D et al (2019) New approaches toward the hydrogen
production from formic acid dehydrogenation over Pd-based heterogeneous catalysts. Front Mater
6:44
32. García-Aguilar J, Navlani-García M, Berenguer-Murcia Á et al (2016) Evolution of the PVP–Pd
surface interaction in nanoparticles through the case study of formic acid decomposition. Langmuir
32:12110–12118
33. Podyacheva OY, Bulushev DA, Suboch AN et al (2018) Highly stable single-atom catalyst with
ionic Pd active sites supported on N-doped carbon nanotubes for formic acid decomposition.
Chemsuschem 11:3724–3727
34. Bulushev DA, Zacharska M, Shlyakhova EV et al (2016) Single isolated Pd
2+ cations supported
on N-doped carbon as active sites for hydrogen production from formic acid decomposition. ACS
Catal 6:681–691
35. Bulushev DA, Bulusheva LG, Beloshapkin S et al (2015) Pd clusters supported on amorphous,
low-porosity carbon spheres for hydrogen production from formic acid. ACS Appl Mater Interfaces
7:8719–8726
36. Mellmann D, Sponholz P, Junge H, Beller M (2016) Formic acid as a hydrogen storage material-development of homogeneous catalysts for selective hydrogen release. Chem Soc Rev
45:3954–3988
37. Enthaler S, Von Langermann J, Schmidt T (2010) Carbon dioxide and formic acid—the couple for
environmental-friendly hydrogen storage? Energy Environ Sci 3:1207–1217
38. Coffey RS (1967) The decomposition of formic acid catalysed by soluble metal complexes. Chem
Commun 1967:923–924
39. Fellay C, Dyson PJ, Laurenczy G (2008) A viable hydrogen-storage system based on selective formic acid decomposition with a ruthenium catalyst. Angew Chemie Int Ed 47:3966–3968
40. Loges B, Boddien A, Junge H, Beller M (2008) Controlled generation of hydrogen from formic
acid amine adducts at room temperature and application in H 2 /O 2 fuel cells. Angew Chem Int Ed
47:3962–3965
41. Iglesias M, Oro LA (2018) Mechanistic considerations on homogeneously catalyzed formic acid
dehydrogenation. Eur J Inorg Chem 2018:2125–2138
42. Navlani-García M, Mori K, Nozaki A et al (2016) Investigation of size sensitivity in the hydrogen
production from formic acid over carbon-supported Pd nanoparticles. Chem Sel 1:1879–1886
43. Navlani-García M, Mori K, Nozaki A et al (2016) Screening of carbon-supported PdAg nanoparticles in the hydrogen production from formic acid. Ind Eng Chem Res 55:7612–7620
44. Navlani-García M, Salinas-Torres D, Mori K et al (2018) Enhanced formic acid dehydrogenation
by the synergistic alloying effect of PdCo catalysts supported on graphitic carbon nitride. Int J
Hydrogen Energy (in press) https ://doi.org/10.1016/j.ijhyd ene.2018.11.057
45. Sun J, Qiu H, Cao W et al (2019) Ultrafine Pd particles embedded in nitrogen-enriched mesoporous
carbon for efficient H 2 production from formic acid decomposition. ACS Sustain Chem Eng
7:1963–1972
219
Reprinted from the journal
Topics in Current Chemistry (2019) 377:27
23. Afif A, Radenahmad N, Cheok Q et al (2016) Ammonia-fed fuel cells: a comprehensive review.
Renew Sustain Energy Rev 60:822–835
24. Chowdhury AD, Agnihotri N, De A (2015) Hydrolysis of sodium borohydride using Ru-CoPEDOT nanocomposites as catalyst. Chem Eng J 264:531–537
25. Dalebrook AF, Gan W, Grasemann M et al (2013) Hydrogen storage: beyond conventional methods. Chem Commun 49:8735–8751
26. Preuster P, Papp C, Wasserscheid P (2017) Liquid Organic Hydrogen Carriers (LOHCs): toward a
hydrogen-free hydrogen economy. Acc Chem Res 50:74–85
27. Niermann M, Beckendorff A, Kaltschmitt M, Bonhoff K (2019) Liquid Organic Hydrogen Carrier (LOHC)—assessment based on chemical and economic properties. Int J Hydrogen Energy
44:6631–6654
28. Hu P, Fogler E, Diskin-Posner Y et al (2015) A novel liquid organic hydrogen carrier system based
on catalytic peptide formation and hydrogenation. Nat Commun 6:6859
29. Mori K, Dojo M, Yamashita H (2013) Pd and Pd–Ag nanoparticles within a macroreticular basic
resin: an efficient catalyst for hydrogen production from formic acid decomposition. ACS Catal
3:1114–1119
30. Navlani-García M, Mori K, Kuwahara Y, Yamashita H (2018) Recent strategies targeting efficient
hydrogen production from chemical hydrogen storage materials over carbon-supported catalysts.
NPG Asia Mater 2018:1–16
31. Navlani-García M, Mori K, Salinas-Torres D et al (2019) New approaches toward the hydrogen
production from formic acid dehydrogenation over Pd-based heterogeneous catalysts. Front Mater
6:44
32. García-Aguilar J, Navlani-García M, Berenguer-Murcia Á et al (2016) Evolution of the PVP–Pd
surface interaction in nanoparticles through the case study of formic acid decomposition. Langmuir
32:12110–12118
33. Podyacheva OY, Bulushev DA, Suboch AN et al (2018) Highly stable single-atom catalyst with
ionic Pd active sites supported on N-doped carbon nanotubes for formic acid decomposition.
Chemsuschem 11:3724–3727
34. Bulushev DA, Zacharska M, Shlyakhova EV et al (2016) Single isolated Pd
2+ cations supported
on N-doped carbon as active sites for hydrogen production from formic acid decomposition. ACS
Catal 6:681–691
35. Bulushev DA, Bulusheva LG, Beloshapkin S et al (2015) Pd clusters supported on amorphous,
low-porosity carbon spheres for hydrogen production from formic acid. ACS Appl Mater Interfaces
7:8719–8726
36. Mellmann D, Sponholz P, Junge H, Beller M (2016) Formic acid as a hydrogen storage material-development of homogeneous catalysts for selective hydrogen release. Chem Soc Rev
45:3954–3988
37. Enthaler S, Von Langermann J, Schmidt T (2010) Carbon dioxide and formic acid—the couple for
environmental-friendly hydrogen storage? Energy Environ Sci 3:1207–1217
38. Coffey RS (1967) The decomposition of formic acid catalysed by soluble metal complexes. Chem
Commun 1967:923–924
39. Fellay C, Dyson PJ, Laurenczy G (2008) A viable hydrogen-storage system based on selective formic acid decomposition with a ruthenium catalyst. Angew Chemie Int Ed 47:3966–3968
40. Loges B, Boddien A, Junge H, Beller M (2008) Controlled generation of hydrogen from formic
acid amine adducts at room temperature and application in H 2 /O 2 fuel cells. Angew Chem Int Ed
47:3962–3965
41. Iglesias M, Oro LA (2018) Mechanistic considerations on homogeneously catalyzed formic acid
dehydrogenation. Eur J Inorg Chem 2018:2125–2138
42. Navlani-García M, Mori K, Nozaki A et al (2016) Investigation of size sensitivity in the hydrogen
production from formic acid over carbon-supported Pd nanoparticles. Chem Sel 1:1879–1886
43. Navlani-García M, Mori K, Nozaki A et al (2016) Screening of carbon-supported PdAg nanoparticles in the hydrogen production from formic acid. Ind Eng Chem Res 55:7612–7620
44. Navlani-García M, Salinas-Torres D, Mori K et al (2018) Enhanced formic acid dehydrogenation
by the synergistic alloying effect of PdCo catalysts supported on graphitic carbon nitride. Int J
Hydrogen Energy (in press) https ://doi.org/10.1016/j.ijhyd ene.2018.11.057
45. Sun J, Qiu H, Cao W et al (2019) Ultrafine Pd particles embedded in nitrogen-enriched mesoporous
carbon for efficient H 2 production from formic acid decomposition. ACS Sustain Chem Eng
7:1963–1972
219
Reprinted from the journal