Topics in Current Chemistry (2019) 377:24
1 3
1x10
-10
2x10
-10
3x10
-10
4x10
-10
5x10
-10
0.0
0.5
1.0
1.5
2.0
6.0x10
-10
7.5x10
-10
9.0x10
-10
1.0x10
-9
1.2x10
-9
0.0
0.5
1.0
1.5
2.0
0.025CeO 2 /TiO 2
TiO 2
EPR parameter / a.u.
Visible Reaction Rate / mol s
-1 m
-2
Kinetic parameter / a.u.
UV Reaction Rate / mol s
-1 m
-2
(a)
1.0x10
-10
2.0x10
-10
3.0x10
-10
4.0x10
-10
5.0x10
-10
0.4
0.8
1.2
1.6
2.0
0.025CeTi
0.05CeTi
0.1CeTi
Ti
0.25CeTi
0.01CeTi
UV Reaction Rate / mol s
-1 m
-2
EPR parameter / a.u.
(b)
0.4
0.6
0.8
1.0
1.2
1.4
Kinetic parameter / a.u.
2.0x10
-10
4.0x10
-10
6.0x10
-10
8.0x10
-10
0.0
0.5
1.0
1.5
2.0
2.0x10
-10
4.0x10
-10
6.0x10
-10
8.0x10
-10
0.0
0.5
1.0
1.5
2.0
Kinetic parameter / a.u.
(c)
1.36
g-Mn/CeTi
g-Mn/Ti
UV Reaction Rate / mol s
-1 m
-2
CeTi
Ti
EPR parameter / a.u.
1.63
1.61
186
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