1 3
Topics in Current Chemistry (2019) 377:11
95. Chen YX, Miki A, Ye S, Sakai H, Osawa M (2003) Formate, an active intermediate for direct oxidation of methanol on Pt electrode. J Am Chem Soc 125:3680–3681
96. Shao MH, Adzic RR (2005) Electrooxidation of ethanol on a Pt electrode in acid solutions: in situ
ATR-SEIRAS study. Electrochim Acta 50:2415–2422
97. Shao MH, Warren J, Marinkovic NS, Faguy PW, Adzic RR (2005) In situ ATR-SEIRAS study
of electrooxidation of dimethyl ether on a Pt electrode in acid solutions. Electrochem Commun
7:459–465
98. Burgi T (2001) ATR-IR spectroscopy at the metal–liquid interface: influence of film properties on
anomalous band-shape. Phys Chem Chem Phys 3:2124–2130
99. Bell AT (2003) The impact of nanoscience on heterogeneous catalysis. Science
299(5613):1688–1691
100. Benfield RE (1992) Mean coordination numbers and the non-metal–metal transition in clusters. J
Chem Soc Faraday Trans 88:1107–1110
101. Beale AM, Weckhuysen BM (2010) EXAFS as a tool to interrogate the size and shape of mono
and bimetallic catalyst nanoparticles. Phys Chem Chem Phys 12:5562–5574
102. Frenkel A (2007) Solving the 3D structure of metal nanoparticles. Zeitschrift fur Kristallographie
222:605–611
103. Sasaki K, Marinkovic NS (2016) X-ray absorption spectroscopic characterization of nanomaterial
catalysts in electrochemistry and fuel cells. In: Kumar CSSR (ed) X-ray and neutron techniques for
nanomaterials characterization, chapter 6. Springer, New York, pp 315–365
104. Marinkovic NS, Sasaki K, Adzic RR (2018) Determination of single- and multi-component nanoparticle sizes by X-ray absorption spectroscopy. J Electrochem Soc 165(15):J3222–J3230
105. Trasatti S (1999) In: Wieckowski A (ed) Interfacial electrochemistry: theory, experiment, and
applications. Marcel Dekker, New York, pp 769–788
106. Batzill M, Diebold U (2005) The surface and materials science of tin oxide. Prog Surf Sci
79:47–154
107. Li M, Marinkovic N, Sasaki K (2012) In situ characterization of ternary Pt–Rh–SnO 2 /C catalysts
for ethanol electrooxidation. Electrocatalysis 3:376–385
108. de Tacconi NR, Lezna RO, Beden B, Hahn F, Lamy C (1994) In-situ FTIR study of the electrocatalytic oxidation of ethanol at iridium and rhodium electrodes. J Electroanal Chem 379:329–337
109. Cao L, Sun G, Li H, Xin Q (2007) Carbon-supported IrSn catalysts for a direct ethanol fuel cell.
Electrochem Commun 9:2541–2546
110. Du W, Wang Q, Saxner D, Aaron Deskins N, Su D, Krzanowski JE, Frenkel AI, Teng X (2011)
Highly active iridium/iridium–tin/tin oxide heterogeneous nanoparticles as alternative electrocatalysts for the ethanol oxidation reaction. J Am Chem Soc 133:15172–15183
111. Zhang J, Sasaki K, Sutter E, Adzic RR (2007) Stabilization of platinum oxygen-reduction electrocatalysts using gold clusters. Science 315(5809):220–222
112. Adzic RR, Zhang J, Sasaki K, Vukmirovic MB, Shao M, Wang JX, Nilekar AU, Mavrikakis M,
Valerio JA, Uribe F (2007) Platinum monolayer fuel cell electrocatalysts. Top Catal 46:249–262
113. Sasaki K, Adzic RR (2008) Monolayer-level Ru- and NbO 2 -supported platinum electrocatalysts for
methanol oxidation. J Electrochem Soc 105:B180–B186
Publisher’s Note Springer Nature remains neutral with regard to jurisdictional claims in published
maps and institutional affiliations.
Affiliations
Nebojsa S. Marinkovic
1
· Meng Li
2
· Radoslav R. Adzic
2
* Nebojsa S. Marinkovic
marinkov@bnl.gov
1
Synchrotron Catalysis Consortium and Columbia University, New York, NY, USA
2
Brookhaven National Laboratory, Upton, NY, USA
Reprinted from the journal
39
Topics in Current Chemistry (2019) 377:11
95. Chen YX, Miki A, Ye S, Sakai H, Osawa M (2003) Formate, an active intermediate for direct oxidation of methanol on Pt electrode. J Am Chem Soc 125:3680–3681
96. Shao MH, Adzic RR (2005) Electrooxidation of ethanol on a Pt electrode in acid solutions: in situ
ATR-SEIRAS study. Electrochim Acta 50:2415–2422
97. Shao MH, Warren J, Marinkovic NS, Faguy PW, Adzic RR (2005) In situ ATR-SEIRAS study
of electrooxidation of dimethyl ether on a Pt electrode in acid solutions. Electrochem Commun
7:459–465
98. Burgi T (2001) ATR-IR spectroscopy at the metal–liquid interface: influence of film properties on
anomalous band-shape. Phys Chem Chem Phys 3:2124–2130
99. Bell AT (2003) The impact of nanoscience on heterogeneous catalysis. Science
299(5613):1688–1691
100. Benfield RE (1992) Mean coordination numbers and the non-metal–metal transition in clusters. J
Chem Soc Faraday Trans 88:1107–1110
101. Beale AM, Weckhuysen BM (2010) EXAFS as a tool to interrogate the size and shape of mono
and bimetallic catalyst nanoparticles. Phys Chem Chem Phys 12:5562–5574
102. Frenkel A (2007) Solving the 3D structure of metal nanoparticles. Zeitschrift fur Kristallographie
222:605–611
103. Sasaki K, Marinkovic NS (2016) X-ray absorption spectroscopic characterization of nanomaterial
catalysts in electrochemistry and fuel cells. In: Kumar CSSR (ed) X-ray and neutron techniques for
nanomaterials characterization, chapter 6. Springer, New York, pp 315–365
104. Marinkovic NS, Sasaki K, Adzic RR (2018) Determination of single- and multi-component nanoparticle sizes by X-ray absorption spectroscopy. J Electrochem Soc 165(15):J3222–J3230
105. Trasatti S (1999) In: Wieckowski A (ed) Interfacial electrochemistry: theory, experiment, and
applications. Marcel Dekker, New York, pp 769–788
106. Batzill M, Diebold U (2005) The surface and materials science of tin oxide. Prog Surf Sci
79:47–154
107. Li M, Marinkovic N, Sasaki K (2012) In situ characterization of ternary Pt–Rh–SnO 2 /C catalysts
for ethanol electrooxidation. Electrocatalysis 3:376–385
108. de Tacconi NR, Lezna RO, Beden B, Hahn F, Lamy C (1994) In-situ FTIR study of the electrocatalytic oxidation of ethanol at iridium and rhodium electrodes. J Electroanal Chem 379:329–337
109. Cao L, Sun G, Li H, Xin Q (2007) Carbon-supported IrSn catalysts for a direct ethanol fuel cell.
Electrochem Commun 9:2541–2546
110. Du W, Wang Q, Saxner D, Aaron Deskins N, Su D, Krzanowski JE, Frenkel AI, Teng X (2011)
Highly active iridium/iridium–tin/tin oxide heterogeneous nanoparticles as alternative electrocatalysts for the ethanol oxidation reaction. J Am Chem Soc 133:15172–15183
111. Zhang J, Sasaki K, Sutter E, Adzic RR (2007) Stabilization of platinum oxygen-reduction electrocatalysts using gold clusters. Science 315(5809):220–222
112. Adzic RR, Zhang J, Sasaki K, Vukmirovic MB, Shao M, Wang JX, Nilekar AU, Mavrikakis M,
Valerio JA, Uribe F (2007) Platinum monolayer fuel cell electrocatalysts. Top Catal 46:249–262
113. Sasaki K, Adzic RR (2008) Monolayer-level Ru- and NbO 2 -supported platinum electrocatalysts for
methanol oxidation. J Electrochem Soc 105:B180–B186
Publisher’s Note Springer Nature remains neutral with regard to jurisdictional claims in published
maps and institutional affiliations.
Affiliations
Nebojsa S. Marinkovic
1
· Meng Li
2
· Radoslav R. Adzic
2
* Nebojsa S. Marinkovic
marinkov@bnl.gov
1
Synchrotron Catalysis Consortium and Columbia University, New York, NY, USA
2
Brookhaven National Laboratory, Upton, NY, USA
Reprinted from the journal
39