1 3
Topics in Current Chemistry (2019) 377:5
48. Santos E, Leiva EPM, Vielstich W (1991) CO adsorbate on Pt(111) single crystal surfaces. Electrochim Acta 36:555–561
49. Farias MJS, Busó-Rogero C, Gisber R, Herrero E, Feliu JM (2014) Influence of the CO adsorption
environment on its reactivity with (111) terrace sites in stepped Pt electrodes under alkaline media.
J Phys Chem C 118:1925–1934
50. García G, Koper MTM (2008) Stripping voltammetry of carbon monoxide oxidation on stepped
platinum single-crystal electrodes in alkaline solution. Phys Chem Chem Phys 10:3802–3811
51. Farias MJS, Herrero E, Feliu JM (2013) Site selectivity for CO adsorption and stripping on stepped
and kinked platinum surfaces in alkaline medium. J Phys Chem C 117:2903–2913
52. Farias MJS, Camara GA, Feliu JM (2015) Understanding the CO preoxidation and the intrinsic catalytic activity of step sites in stepped Pt surfaces in acidic medium. J Phys Chem C
119:20272–20282
53. Herrero E, Chen QS, Hernandez J, Sun SG, Feliu JM (2011) Effects of the surface mobility on the
oxidation of adsorbed CO on platinum electrodes in alkaline media. The role of the adlayer and
surface defects. Phys Chem Chem Phys 13:16762–16771
54. Lebedeva NP, Rodes A, Feliu JM, Koper MTM, van Santen RA (2002) Role of crystalline defects
in electrocatalysis: CO adsorption and oxidation on stepped platinum electrodes as studied by
in situ infrared spectroscopy. J Phys Chem B 106:9863–9872
55. Calle-Vallejo F, Pohl MD, Bandarenka AS (2017) Quantitative coordination—activity relations for
the design of enhanced Pt catalysts for CO electro-oxidation. ACS Catal 7:4355–4359
56. Farias MJS, Vidal-Iglesias FJ, Solla-Gullón J, Herrero E, Feliu JM (2014) On the behavior of CO
oxidation on shape-controlled Pt nanoparticles in alkaline medium. J Electroanal Chem 716:16–22
57. McPherson IJ, Ash PA, Jones L, Varambhia A, Jacobs RMJ, Vincent KA (2017) Electrochemical
CO oxidation at platinum on carbon studied through analysis of anomalous in situ IR spectra. J
Phys Chem C 121:17176–17187
58. Backus EHG, Eichler A, Kleyn AW, Bonn M (2005) Real-time observation of molecular motion on
a surface. Science 310:1790–1793
59. Farias MJS, Cheuquepán W, Tanaka AA, Feliu JM (2018) Unraveling the nature of active sites in
ethanol electro-oxidation by site-specific marking of a Pt catalyst with isotope-labeled
13 CO. J Phys
Chem Lett 9:1206–1210
60. Farias MJS, Cheuquepán W, Tanaka AA, Feliu JM (2017) Nonuniform synergistic effect of Sn and
Ru in site-specific catalytic activity of Pt at bimetallic surfaces toward CO electro-oxidation. ACS
Catal 7:3434–3445
61. Vielstich W (2003) Electrochemical energy conversion: methanol fuel cell as example. J Braz
Chem Soc 14:503–509
62. Cuesta A (2017) Electrooxidation of C 1 organic molecules on Pt electrodes. Curr Opin Electrochem 4:32–38
63. Herrero E, Feliu JM (2018) Understanding formic acid oxidation mechanism on platinum single
crystal electrodes. Curr Opinion Electrochem 9:145–150
64. Grozovski V, Climent V, Herrero E, Feliu JM (2010) Intrinsic activity and poisoning rate for
HCOOH oxidation on platinum stepped surfaces. Phys Chem Chem Phys 12:8822–8831
65. Grozovski V, Climent V, Herrero E, Feliu JM (2011) The role of the surface structure in the oxidation mechanism of methanol. J Electroanal Chem 662:43–51
66. Miki A, Ye S, Osawa M (2002) Surface-enhanced IR absorption on platinum nanoparticles: an
application to real-time monitoring of electrocatalytic reactions. Chem Commun 150:1500–1501
67. Chen YX, Heinen M, Jusys Z, Behm RJ (2006) Bridge-bonded formate: active intermediate or
spectator species in formic acid oxidation on a Pt film electrode? Langmuir 22:10399–10408
68. Osawa M, Komatsu KI, Samjeské G, Uchida T, Ikeshoji T, Cuesta A, Gutiérrez C (2011) The role
of bridge-bonded adsorbed formate in the electrocatalytic oxidation of formic acid on platinum.
Angew Chem Int Ed 50:1159–1163
69. Iwasita T (2002) Electrocatalysis of methanol oxidation. Electrochim Acta 47:3663–3674
70. Cuesta A (2006) At least three contiguous atoms are necessary for CO formation during methanol
electrooxidation on platinum. J Am Chem Soc 128:13332–13333
71. Villegas I, Weaver MJ (1994) Carbon monoxide adlayer structures on platinum (111) electrodes:
a synergy between in situ scanning tunneling microscopy and infrared spectroscopy. J Chem Phys
101:1648–1660
72. Kim YG, Yau SL, Itaya K (1996) Direct observation of complexation of alkali cations on cyanidemodified Pt(111) by scanning tunneling microscopy. J Am Chem Soc 118:393–400
Reprinted from the journal
101
Topics in Current Chemistry (2019) 377:5
48. Santos E, Leiva EPM, Vielstich W (1991) CO adsorbate on Pt(111) single crystal surfaces. Electrochim Acta 36:555–561
49. Farias MJS, Busó-Rogero C, Gisber R, Herrero E, Feliu JM (2014) Influence of the CO adsorption
environment on its reactivity with (111) terrace sites in stepped Pt electrodes under alkaline media.
J Phys Chem C 118:1925–1934
50. García G, Koper MTM (2008) Stripping voltammetry of carbon monoxide oxidation on stepped
platinum single-crystal electrodes in alkaline solution. Phys Chem Chem Phys 10:3802–3811
51. Farias MJS, Herrero E, Feliu JM (2013) Site selectivity for CO adsorption and stripping on stepped
and kinked platinum surfaces in alkaline medium. J Phys Chem C 117:2903–2913
52. Farias MJS, Camara GA, Feliu JM (2015) Understanding the CO preoxidation and the intrinsic catalytic activity of step sites in stepped Pt surfaces in acidic medium. J Phys Chem C
119:20272–20282
53. Herrero E, Chen QS, Hernandez J, Sun SG, Feliu JM (2011) Effects of the surface mobility on the
oxidation of adsorbed CO on platinum electrodes in alkaline media. The role of the adlayer and
surface defects. Phys Chem Chem Phys 13:16762–16771
54. Lebedeva NP, Rodes A, Feliu JM, Koper MTM, van Santen RA (2002) Role of crystalline defects
in electrocatalysis: CO adsorption and oxidation on stepped platinum electrodes as studied by
in situ infrared spectroscopy. J Phys Chem B 106:9863–9872
55. Calle-Vallejo F, Pohl MD, Bandarenka AS (2017) Quantitative coordination—activity relations for
the design of enhanced Pt catalysts for CO electro-oxidation. ACS Catal 7:4355–4359
56. Farias MJS, Vidal-Iglesias FJ, Solla-Gullón J, Herrero E, Feliu JM (2014) On the behavior of CO
oxidation on shape-controlled Pt nanoparticles in alkaline medium. J Electroanal Chem 716:16–22
57. McPherson IJ, Ash PA, Jones L, Varambhia A, Jacobs RMJ, Vincent KA (2017) Electrochemical
CO oxidation at platinum on carbon studied through analysis of anomalous in situ IR spectra. J
Phys Chem C 121:17176–17187
58. Backus EHG, Eichler A, Kleyn AW, Bonn M (2005) Real-time observation of molecular motion on
a surface. Science 310:1790–1793
59. Farias MJS, Cheuquepán W, Tanaka AA, Feliu JM (2018) Unraveling the nature of active sites in
ethanol electro-oxidation by site-specific marking of a Pt catalyst with isotope-labeled
13 CO. J Phys
Chem Lett 9:1206–1210
60. Farias MJS, Cheuquepán W, Tanaka AA, Feliu JM (2017) Nonuniform synergistic effect of Sn and
Ru in site-specific catalytic activity of Pt at bimetallic surfaces toward CO electro-oxidation. ACS
Catal 7:3434–3445
61. Vielstich W (2003) Electrochemical energy conversion: methanol fuel cell as example. J Braz
Chem Soc 14:503–509
62. Cuesta A (2017) Electrooxidation of C 1 organic molecules on Pt electrodes. Curr Opin Electrochem 4:32–38
63. Herrero E, Feliu JM (2018) Understanding formic acid oxidation mechanism on platinum single
crystal electrodes. Curr Opinion Electrochem 9:145–150
64. Grozovski V, Climent V, Herrero E, Feliu JM (2010) Intrinsic activity and poisoning rate for
HCOOH oxidation on platinum stepped surfaces. Phys Chem Chem Phys 12:8822–8831
65. Grozovski V, Climent V, Herrero E, Feliu JM (2011) The role of the surface structure in the oxidation mechanism of methanol. J Electroanal Chem 662:43–51
66. Miki A, Ye S, Osawa M (2002) Surface-enhanced IR absorption on platinum nanoparticles: an
application to real-time monitoring of electrocatalytic reactions. Chem Commun 150:1500–1501
67. Chen YX, Heinen M, Jusys Z, Behm RJ (2006) Bridge-bonded formate: active intermediate or
spectator species in formic acid oxidation on a Pt film electrode? Langmuir 22:10399–10408
68. Osawa M, Komatsu KI, Samjeské G, Uchida T, Ikeshoji T, Cuesta A, Gutiérrez C (2011) The role
of bridge-bonded adsorbed formate in the electrocatalytic oxidation of formic acid on platinum.
Angew Chem Int Ed 50:1159–1163
69. Iwasita T (2002) Electrocatalysis of methanol oxidation. Electrochim Acta 47:3663–3674
70. Cuesta A (2006) At least three contiguous atoms are necessary for CO formation during methanol
electrooxidation on platinum. J Am Chem Soc 128:13332–13333
71. Villegas I, Weaver MJ (1994) Carbon monoxide adlayer structures on platinum (111) electrodes:
a synergy between in situ scanning tunneling microscopy and infrared spectroscopy. J Chem Phys
101:1648–1660
72. Kim YG, Yau SL, Itaya K (1996) Direct observation of complexation of alkali cations on cyanidemodified Pt(111) by scanning tunneling microscopy. J Am Chem Soc 118:393–400
Reprinted from the journal
101