157. Jameel U, Zhu M, Chen X, Chen H, Iqbal N, Tong Z, Timayo SJ (2017) Novel gallium
polyoxometalate/nano-gold hybrid material supported on nano-sized silica for mild
cyclohexene oxidation using molecular oxygen. Bull Korean Chem Soc 38:614–624. https://
doi.org/10.1002/bkcs.11135
158. Ovoshchnikov DS, Donoeva BG, Williamson BE, Golovko VB (2014) Tuning the selectivity
of a supported gold catalyst in solvent- and radical initiator-free aerobic oxidation of
cyclohexene. Catal Sci Technol 4:752–757. https://doi.org/10.1039/C3CY01011B
159. Donoeva BG, Ovoshchnikov DS, Golovko VB (2013) Establishing a Au nanoparticle size
effect in the oxidation of cyclohexene using gradually changing Au catalysts. ACS Catal
3:2986–2991. https://doi.org/10.1021/cs400701j
160. Dias Ribeiro de Sousa Martins LM, Carabineiro SAC, Wang J, Rocha BGM, MaldonadoHódar FJ, Latourrette de Oliveira Pombeiro AJ (2017) Supported gold nanoparticles as
reusable catalysts for oxidation reactions of industrial significance. ChemCatChem
9:1211–1221. https://doi.org/10.1002/cctc.201601442
161. Zhang B, Kaziz S, Li H, Hevia MG, Wodka D, Mazet C, Bürgi T, Barrabés N (2015)
Modulation of active sites in supported Au 38 (SC 2 H 4 Ph) 24 cluster catalysts: effect of atmosphere and support material. J Phys Chem C 119:11193–11199. https://doi.org/10.1021/
jp512022v
162. Liu Y, Tsunoyama H, Akita T, Xie S, Tsukuda T (2011) Aerobic oxidation of cyclohexane
catalyzed by size-controlled au clusters on hydroxyapatite: size effect in the sub-2 nm regime.
ACS Catal 1:2–6. https://doi.org/10.1021/cs100043j
163. Xu LX, He CH, Zhu MQ, Fang S (2007) A highly active Au/Al 2 O 3 catalyst for cyclohexane
oxidation using molecular oxygen. Catal Lett 114:202–205. https://doi.org/10.1007/s10562007-9058-0
164. Lu GM, Zhao R, Qian G, Qi YX, Wang XL, Suo JS (2004) A highly efficient catalyst Au/
MCM-41 for selective oxidation cyclohexane using oxygen. Catal Lett 97:115–118. https://
doi.org/10.1023/B:CATL.0000038571.97121.b7
165. Zhao R, Ji D, Lv G, Qian G, Yan L, Wang X, Suo J (2004) A highly efficient oxidation of
cyclohexane over Au/ZSM-5 molecular sieve catalyst with oxygen as oxidant. Chem Commun
7:904–905. https://doi.org/10.1039/B315098D
166. Saxena S, Singh R, Pala RGS, Sivakumar S (2016) Sinter-resistant gold nanoparticles encapsulated by zeolite nanoshell for oxidation of cyclohexane. RSC Adv 6:8015–8020. https://doi.
org/10.1039/c5ra20734g
167. Liu L, Arenal R, Meira DM, Corma A (2019) Generation of gold nanoclusters encapsulated in
an MCM-22 zeolite for the aerobic oxidation of cyclohexane. Chem Commun 55:1607–1610.
https://doi.org/10.1039/c8cc07185c
168. Leyva-Pérez A, Oliver-Meseguer J, Cabrero-Antonino JR, Rubio-Marqués P, Serna P,
Al-Resayes SI, Corma A (2013) Reactivity of electron-deficient alkynes on gold nanoparticles.
ACS Catal 3:1865–1873. https://doi.org/10.1021/cs400362c
169. Serna P, Corma A (2014) Towards a zero-waste oxidative coupling of nonactivated aromatics
by supported gold nanoparticles. ChemSusChem 7:2136–2139. https://doi.org/10.1002/cssc.
201402061
170. Ishida T, Aikawa S, Mise Y, Akebi R, Hamasaki A, Honma T, Ohashi H, Tsuji T,
Yamamoto Y, Miyasaka M, Yokoyama T, Tokunaga M (2015) Direct C-H arene
homocoupling over gold nanoparticles supported on metal oxides. ChemSusChem
8:695–701. https://doi.org/10.1002/cssc.201402822
48
T. Ishida et al.
polyoxometalate/nano-gold hybrid material supported on nano-sized silica for mild
cyclohexene oxidation using molecular oxygen. Bull Korean Chem Soc 38:614–624. https://
doi.org/10.1002/bkcs.11135
158. Ovoshchnikov DS, Donoeva BG, Williamson BE, Golovko VB (2014) Tuning the selectivity
of a supported gold catalyst in solvent- and radical initiator-free aerobic oxidation of
cyclohexene. Catal Sci Technol 4:752–757. https://doi.org/10.1039/C3CY01011B
159. Donoeva BG, Ovoshchnikov DS, Golovko VB (2013) Establishing a Au nanoparticle size
effect in the oxidation of cyclohexene using gradually changing Au catalysts. ACS Catal
3:2986–2991. https://doi.org/10.1021/cs400701j
160. Dias Ribeiro de Sousa Martins LM, Carabineiro SAC, Wang J, Rocha BGM, MaldonadoHódar FJ, Latourrette de Oliveira Pombeiro AJ (2017) Supported gold nanoparticles as
reusable catalysts for oxidation reactions of industrial significance. ChemCatChem
9:1211–1221. https://doi.org/10.1002/cctc.201601442
161. Zhang B, Kaziz S, Li H, Hevia MG, Wodka D, Mazet C, Bürgi T, Barrabés N (2015)
Modulation of active sites in supported Au 38 (SC 2 H 4 Ph) 24 cluster catalysts: effect of atmosphere and support material. J Phys Chem C 119:11193–11199. https://doi.org/10.1021/
jp512022v
162. Liu Y, Tsunoyama H, Akita T, Xie S, Tsukuda T (2011) Aerobic oxidation of cyclohexane
catalyzed by size-controlled au clusters on hydroxyapatite: size effect in the sub-2 nm regime.
ACS Catal 1:2–6. https://doi.org/10.1021/cs100043j
163. Xu LX, He CH, Zhu MQ, Fang S (2007) A highly active Au/Al 2 O 3 catalyst for cyclohexane
oxidation using molecular oxygen. Catal Lett 114:202–205. https://doi.org/10.1007/s10562007-9058-0
164. Lu GM, Zhao R, Qian G, Qi YX, Wang XL, Suo JS (2004) A highly efficient catalyst Au/
MCM-41 for selective oxidation cyclohexane using oxygen. Catal Lett 97:115–118. https://
doi.org/10.1023/B:CATL.0000038571.97121.b7
165. Zhao R, Ji D, Lv G, Qian G, Yan L, Wang X, Suo J (2004) A highly efficient oxidation of
cyclohexane over Au/ZSM-5 molecular sieve catalyst with oxygen as oxidant. Chem Commun
7:904–905. https://doi.org/10.1039/B315098D
166. Saxena S, Singh R, Pala RGS, Sivakumar S (2016) Sinter-resistant gold nanoparticles encapsulated by zeolite nanoshell for oxidation of cyclohexane. RSC Adv 6:8015–8020. https://doi.
org/10.1039/c5ra20734g
167. Liu L, Arenal R, Meira DM, Corma A (2019) Generation of gold nanoclusters encapsulated in
an MCM-22 zeolite for the aerobic oxidation of cyclohexane. Chem Commun 55:1607–1610.
https://doi.org/10.1039/c8cc07185c
168. Leyva-Pérez A, Oliver-Meseguer J, Cabrero-Antonino JR, Rubio-Marqués P, Serna P,
Al-Resayes SI, Corma A (2013) Reactivity of electron-deficient alkynes on gold nanoparticles.
ACS Catal 3:1865–1873. https://doi.org/10.1021/cs400362c
169. Serna P, Corma A (2014) Towards a zero-waste oxidative coupling of nonactivated aromatics
by supported gold nanoparticles. ChemSusChem 7:2136–2139. https://doi.org/10.1002/cssc.
201402061
170. Ishida T, Aikawa S, Mise Y, Akebi R, Hamasaki A, Honma T, Ohashi H, Tsuji T,
Yamamoto Y, Miyasaka M, Yokoyama T, Tokunaga M (2015) Direct C-H arene
homocoupling over gold nanoparticles supported on metal oxides. ChemSusChem
8:695–701. https://doi.org/10.1002/cssc.201402822
48
T. Ishida et al.