44. Haider P, Baiker A (2007) Gold supported on Cu-Mg-Al-mixed oxides: strong enhancement
of activity in aerobic alcohol oxidation by concerted effect of copper and magnesium. J Catal
248:175–187. https://doi.org/10.1016/j.jcat.2007.03.007
45. Li S, Li W, Li Y, Fan G, Li F (2017) Structure-dependent base-free aerobic oxidation of benzyl
alcohol over high-surface-area Mg-doped ZnAl 2 O 4 spinel supported gold nanoparticles.
ChemPlusChem 82:270–279. https://doi.org/10.1002/cplu.201600500
46. De Moura EM, Garcia MAS, Gonçalves RV, Kiyohara PK, Jardim RF, Rossi LM (2015) Gold
nanoparticles supported on magnesium ferrite and magnesium oxide for the selective oxidation
of benzyl alcohol. RSC Adv 5:15035–15041. https://doi.org/10.1039/c4ra16159a
47. Mitsudome T, Noujima A, Mizugaki T, Jitsukawa K, Kaneda K (2009) Efficient aerobic
oxidation of alcohols using a hydrotalcite supported gold nanoparticle catalyst. Adv Synth
Catal 351:1890–1896. https://doi.org/10.1002/adsc.200900239
48. Chen J, Fang W, Zhang Q, Deng W, Wang Y (2014) A comparative study of size effects in the
au-catalyzed oxidative and non-oxidative dehydrogenation of benzyl alcohol. Chem Asian J
9:2187–2196. https://doi.org/10.1002/asia.201402238
49. Liu P, Guan Y, Santen RAV, Li C, Hensen EJM (2011) Aerobic oxidation of alcohols over
hydrotalcite-supported gold nanoparticles: the promotional effect of transition metal cations.
Chem Commun 47:11540–11542. https://doi.org/10.1039/c1cc15148g
50. Li L, Dou L, Zhang H (2014) Layered double hydroxide supported gold nanoclusters by
glutathione-capped Au nanoclusters precursor method for highly efficient aerobic oxidation of
alcohols. Nanoscale 6:3753–3763. https://doi.org/10.1039/c3nr05604j
51. Liu M, Fan G, Yu J, Yang L, Li F (2018) Defect-rich Ni-Ti layered double hydroxide as a
highly efficient support for Au nanoparticles in base-free and solvent-free selective oxidation
of benzyl alcohol. Dalton Trans 47:5226–5235. https://doi.org/10.1039/c7dt04229a
52. Tang H, Wei J, Liu F, Qiao B, Pan X, Li L, Liu J, Wang J, Zhang T (2016) Strong metalsupport interactions between gold nanoparticles and nonoxides. J Am Chem Soc 138:56–59.
https://doi.org/10.1021/jacs.5b11306
53. Haesuwannakij S, Poonsawat T, Noikham M, Somsook E, Yakiyama Y, Dhital RN, Sakurai H
(2017) Size-controlled preparation of gold nanoclusters on hydroxyapatite through transdeposition method. J Nanosci Nanotechnol 17:4649–4657. https://doi.org/10.1166/jnn.2017.
13777
54. Karimi B, Kabiri Esfahani F (2009) Gold nanoparticles supported on Cs 2 CO 3 as recyclable
catalyst system for selective aerobic oxidation of alcohols at room temperature. Chem
Commun 37:5555–5557. https://doi.org/10.1039/b908964k
55. Ishida T, Nagaoka M, Akita T, Haruta M (2008) Deposition of gold clusters on porous
coordination polymers by solid grinding and their catalytic activity in aerobic oxidation of
alcohols. Chem Eur J 14:8456–8460. https://doi.org/10.1002/chem.200800980
56. Liu H, Liu Y, Li Y, Tang Z, Jiang H (2010) Metal-organic framework supported gold
nanoparticles as a highly active heterogeneous catalyst for aerobic oxidation of alcohols. J
Phys Chem C 114:13362–13369. https://doi.org/10.1021/jp105666f
57. Zhu J, Wang PC, Lu M (2014) Selective oxidation of benzyl alcohol under solvent-free
condition with gold nanoparticles encapsulated in metal-organic framework. Appl Catal A
Gen 477:125–131. https://doi.org/10.1016/j.apcata.2014.03.013
58. Luan Y, Qi Y, Gao H, Zheng N, Wang G (2014) Synthesis of an amino-functionalized metalorganic framework at a nanoscale level for gold nanoparticle deposition and catalysis. J Mater
Chem A 2:20588–20596. https://doi.org/10.1039/c4ta04311a
59. Leus K, Concepcion P, Vandichel M, Meledina M, Grirrane A, Esquivel D, Turner S,
Poelman D, Waroquier M, Van Speybroeck V, Van Tendeloo G, García H, Van Der Voort
P (2015) Au@UiO-66: a base free oxidation catalyst. RSC Adv 5:22334–22342. https://doi.
org/10.1039/c4ra16800c
60. Wang JS, Jin FZ, Ma HC, Li XB, Liu MY, Kan JL, Chen GJ, Dong YB (2016) Au@Cu(II)MOF: highly efficient bifunctional heterogeneous catalyst for successive oxidationcondensation reactions. Inorg Chem 55:6685–6691. https://doi.org/10.1021/acs.inorgchem.
6b00925
Gold Nanoparticles for Oxidation Reactions: Critical Role of Supports and Au. . .
41
of activity in aerobic alcohol oxidation by concerted effect of copper and magnesium. J Catal
248:175–187. https://doi.org/10.1016/j.jcat.2007.03.007
45. Li S, Li W, Li Y, Fan G, Li F (2017) Structure-dependent base-free aerobic oxidation of benzyl
alcohol over high-surface-area Mg-doped ZnAl 2 O 4 spinel supported gold nanoparticles.
ChemPlusChem 82:270–279. https://doi.org/10.1002/cplu.201600500
46. De Moura EM, Garcia MAS, Gonçalves RV, Kiyohara PK, Jardim RF, Rossi LM (2015) Gold
nanoparticles supported on magnesium ferrite and magnesium oxide for the selective oxidation
of benzyl alcohol. RSC Adv 5:15035–15041. https://doi.org/10.1039/c4ra16159a
47. Mitsudome T, Noujima A, Mizugaki T, Jitsukawa K, Kaneda K (2009) Efficient aerobic
oxidation of alcohols using a hydrotalcite supported gold nanoparticle catalyst. Adv Synth
Catal 351:1890–1896. https://doi.org/10.1002/adsc.200900239
48. Chen J, Fang W, Zhang Q, Deng W, Wang Y (2014) A comparative study of size effects in the
au-catalyzed oxidative and non-oxidative dehydrogenation of benzyl alcohol. Chem Asian J
9:2187–2196. https://doi.org/10.1002/asia.201402238
49. Liu P, Guan Y, Santen RAV, Li C, Hensen EJM (2011) Aerobic oxidation of alcohols over
hydrotalcite-supported gold nanoparticles: the promotional effect of transition metal cations.
Chem Commun 47:11540–11542. https://doi.org/10.1039/c1cc15148g
50. Li L, Dou L, Zhang H (2014) Layered double hydroxide supported gold nanoclusters by
glutathione-capped Au nanoclusters precursor method for highly efficient aerobic oxidation of
alcohols. Nanoscale 6:3753–3763. https://doi.org/10.1039/c3nr05604j
51. Liu M, Fan G, Yu J, Yang L, Li F (2018) Defect-rich Ni-Ti layered double hydroxide as a
highly efficient support for Au nanoparticles in base-free and solvent-free selective oxidation
of benzyl alcohol. Dalton Trans 47:5226–5235. https://doi.org/10.1039/c7dt04229a
52. Tang H, Wei J, Liu F, Qiao B, Pan X, Li L, Liu J, Wang J, Zhang T (2016) Strong metalsupport interactions between gold nanoparticles and nonoxides. J Am Chem Soc 138:56–59.
https://doi.org/10.1021/jacs.5b11306
53. Haesuwannakij S, Poonsawat T, Noikham M, Somsook E, Yakiyama Y, Dhital RN, Sakurai H
(2017) Size-controlled preparation of gold nanoclusters on hydroxyapatite through transdeposition method. J Nanosci Nanotechnol 17:4649–4657. https://doi.org/10.1166/jnn.2017.
13777
54. Karimi B, Kabiri Esfahani F (2009) Gold nanoparticles supported on Cs 2 CO 3 as recyclable
catalyst system for selective aerobic oxidation of alcohols at room temperature. Chem
Commun 37:5555–5557. https://doi.org/10.1039/b908964k
55. Ishida T, Nagaoka M, Akita T, Haruta M (2008) Deposition of gold clusters on porous
coordination polymers by solid grinding and their catalytic activity in aerobic oxidation of
alcohols. Chem Eur J 14:8456–8460. https://doi.org/10.1002/chem.200800980
56. Liu H, Liu Y, Li Y, Tang Z, Jiang H (2010) Metal-organic framework supported gold
nanoparticles as a highly active heterogeneous catalyst for aerobic oxidation of alcohols. J
Phys Chem C 114:13362–13369. https://doi.org/10.1021/jp105666f
57. Zhu J, Wang PC, Lu M (2014) Selective oxidation of benzyl alcohol under solvent-free
condition with gold nanoparticles encapsulated in metal-organic framework. Appl Catal A
Gen 477:125–131. https://doi.org/10.1016/j.apcata.2014.03.013
58. Luan Y, Qi Y, Gao H, Zheng N, Wang G (2014) Synthesis of an amino-functionalized metalorganic framework at a nanoscale level for gold nanoparticle deposition and catalysis. J Mater
Chem A 2:20588–20596. https://doi.org/10.1039/c4ta04311a
59. Leus K, Concepcion P, Vandichel M, Meledina M, Grirrane A, Esquivel D, Turner S,
Poelman D, Waroquier M, Van Speybroeck V, Van Tendeloo G, García H, Van Der Voort
P (2015) Au@UiO-66: a base free oxidation catalyst. RSC Adv 5:22334–22342. https://doi.
org/10.1039/c4ra16800c
60. Wang JS, Jin FZ, Ma HC, Li XB, Liu MY, Kan JL, Chen GJ, Dong YB (2016) Au@Cu(II)MOF: highly efficient bifunctional heterogeneous catalyst for successive oxidationcondensation reactions. Inorg Chem 55:6685–6691. https://doi.org/10.1021/acs.inorgchem.
6b00925
Gold Nanoparticles for Oxidation Reactions: Critical Role of Supports and Au. . .
41