86. Bhattacharyya S, Jayachandrababu KC, Chiang Y et al (2017) Butanol separation from humid
CO 2 -containing multicomponent vapor mixtures by zeolitic imidazolate frameworks. ACS
Sustain Chem Eng 5:9467–9476. https://doi.org/10.1021/acssuschemeng.7b02604
87. Martin-Calvo A, Van der Perre S, Claessens B et al (2018) Unravelling the influence of carbon
dioxide on the adsorptive recovery of butanol from fermentation broth using ITQ-29 and
ZIF-8. Phys Chem Chem Phys 20:9957–9964. https://doi.org/10.1039/C8CP01034J
88. Raganati F, Procentese A, Olivieri G et al (2018) Separation and purification technology
bio-butanol separation by adsorption on various materials: assessment of isotherms and effects
of other ABE-fermentation compounds. Sep Purif Technol 191:328–339. https://doi.org/10.
1016/j.seppur.2017.09.059
89. Cousin-Saint-Remi J, Van der Perre S, Segato T et al (2019) Highly robust MOF polymeric
beads with a controllable size for molecular separations. ACS Appl Mater Interfaces
11:13694–13703. https://doi.org/10.1021/acsami.9b00521
90. Lefevere J, Claessens B, Mullens S et al (2019) 3D-printed zeolitic imidazolate framework
structures for adsorptive separations. ACS Appl Nano Mater 2:4991–4999. https://doi.org/10.
1021/acsanm.9b00934
91. Nalaparaju A, Zhao XS, Jiang JW (2010) Molecular understanding for the adsorption of water
and alcohols in hydrophilic and hydrophobic zeolitic metalÀ organic frameworks. J Phys
Chem C 114:11542–11550. https://doi.org/10.1021/jp1033273
92. Gee JA, Chung J, Nair S, Sholl DS (2013) Adsorption and diffusion of small alcohols in
zeolitic imidazolate frameworks ZIF-8 and ZIF-90. J Phys Chem C 117:3169–3176. https://
doi.org/10.1021/jp312489w
93. Zhang K, Lively RP, Zhang C et al (2013) Exploring the framework hydrophobicity and
flexibility of zif-8: from biofuel recovery to hydrocarbon separations. J Phys Chem Lett
4:3618–3622. https://doi.org/10.1021/jz402019d
94. Zhang K, Lively RP, Dose ME et al (2013) Alcohol and water adsorption in zeolitic
imidazolate frameworks. Chem Commun 49:3245–3247. https://doi.org/10.1039/c3cc39116g
95. Van Der Perre S, Van Assche T, Bozbiyik B et al (2014) Adsorptive characterization of the
ZIF-68 metal-organic framework: a complex structure with amphiphilic properties. Langmuir
30:8416–8424. https://doi.org/10.1021/la501594t
96. Zhang K, Nalaparaju A, Chen Y, Jiang J (2014) Biofuel purification in zeolitic imidazolate
frameworks: the significant role of functional groups. Phys Chem Chem Phys 16:9643–9655.
https://doi.org/10.1039/c4cp00739e
97. Gao C, Wu J, Shi Q et al (2017) Adsorption breakthrough behavior of 1-butanol from an ABE
model solution with high-silica zeolite: comparison with zeolitic imidazolate frameworks
(ZIF-8). Microporous Mesoporous Mater 243:119–129. https://doi.org/10.1016/j.micromeso.
2017.02.009
98. Castillo JM, Silvestre-Albero J, Rodriguez-Reinoso F et al (2013) Water adsorption in
hydrophilic zeolites: experiment and simulation. Phys Chem Chem Phys 15:17374–17382.
https://doi.org/10.1039/c3cp52910j
99. Calero S, Gómez-Álvarez P (2014) Effect of the confinement and presence of cations on
hydrogen bonding of water in LTA-type zeolite. J Phys Chem C 118:9056–9065. https://doi.
org/10.1021/jp5014847
100. Gabruś E, Downarowicz D (2016) Anhydrous ethanol recovery from wet air in TSA systems –
equilibrium and column studies. Chem Eng J 288:321–331. https://doi.org/10.1016/j.cej.2015.
11.110
101. Remy T, Cousin Saint Remi J, Singh R et al (2011) Adsorption and separation of C1 À C8
alcohols on SAPO-34. J Phys Chem C 115:8117–8125. https://doi.org/10.1021/jp111615e
102. Miyamoto M, Iwatsuka H, Oumi Y et al (2019) Effect of core-shell structuring of chabazite
zeolite with a siliceous zeolite thin layer on the separation of acetone-butanol-ethanol vapor in
humid vapor conditions. Chem Eng J 363:292–299. https://doi.org/10.1016/j.cej.2019.01.106
103. Maddox IS (1982) Use of silicalite for the adsorption of n-butanol from fermentation liquors.
Biotechnol Lett 4:759–760. https://doi.org/10.1007/BF00134673
Efficient Downstream Processing of Renewable Alcohols Using Zeolite Adsorbents
113
CO 2 -containing multicomponent vapor mixtures by zeolitic imidazolate frameworks. ACS
Sustain Chem Eng 5:9467–9476. https://doi.org/10.1021/acssuschemeng.7b02604
87. Martin-Calvo A, Van der Perre S, Claessens B et al (2018) Unravelling the influence of carbon
dioxide on the adsorptive recovery of butanol from fermentation broth using ITQ-29 and
ZIF-8. Phys Chem Chem Phys 20:9957–9964. https://doi.org/10.1039/C8CP01034J
88. Raganati F, Procentese A, Olivieri G et al (2018) Separation and purification technology
bio-butanol separation by adsorption on various materials: assessment of isotherms and effects
of other ABE-fermentation compounds. Sep Purif Technol 191:328–339. https://doi.org/10.
1016/j.seppur.2017.09.059
89. Cousin-Saint-Remi J, Van der Perre S, Segato T et al (2019) Highly robust MOF polymeric
beads with a controllable size for molecular separations. ACS Appl Mater Interfaces
11:13694–13703. https://doi.org/10.1021/acsami.9b00521
90. Lefevere J, Claessens B, Mullens S et al (2019) 3D-printed zeolitic imidazolate framework
structures for adsorptive separations. ACS Appl Nano Mater 2:4991–4999. https://doi.org/10.
1021/acsanm.9b00934
91. Nalaparaju A, Zhao XS, Jiang JW (2010) Molecular understanding for the adsorption of water
and alcohols in hydrophilic and hydrophobic zeolitic metalÀ organic frameworks. J Phys
Chem C 114:11542–11550. https://doi.org/10.1021/jp1033273
92. Gee JA, Chung J, Nair S, Sholl DS (2013) Adsorption and diffusion of small alcohols in
zeolitic imidazolate frameworks ZIF-8 and ZIF-90. J Phys Chem C 117:3169–3176. https://
doi.org/10.1021/jp312489w
93. Zhang K, Lively RP, Zhang C et al (2013) Exploring the framework hydrophobicity and
flexibility of zif-8: from biofuel recovery to hydrocarbon separations. J Phys Chem Lett
4:3618–3622. https://doi.org/10.1021/jz402019d
94. Zhang K, Lively RP, Dose ME et al (2013) Alcohol and water adsorption in zeolitic
imidazolate frameworks. Chem Commun 49:3245–3247. https://doi.org/10.1039/c3cc39116g
95. Van Der Perre S, Van Assche T, Bozbiyik B et al (2014) Adsorptive characterization of the
ZIF-68 metal-organic framework: a complex structure with amphiphilic properties. Langmuir
30:8416–8424. https://doi.org/10.1021/la501594t
96. Zhang K, Nalaparaju A, Chen Y, Jiang J (2014) Biofuel purification in zeolitic imidazolate
frameworks: the significant role of functional groups. Phys Chem Chem Phys 16:9643–9655.
https://doi.org/10.1039/c4cp00739e
97. Gao C, Wu J, Shi Q et al (2017) Adsorption breakthrough behavior of 1-butanol from an ABE
model solution with high-silica zeolite: comparison with zeolitic imidazolate frameworks
(ZIF-8). Microporous Mesoporous Mater 243:119–129. https://doi.org/10.1016/j.micromeso.
2017.02.009
98. Castillo JM, Silvestre-Albero J, Rodriguez-Reinoso F et al (2013) Water adsorption in
hydrophilic zeolites: experiment and simulation. Phys Chem Chem Phys 15:17374–17382.
https://doi.org/10.1039/c3cp52910j
99. Calero S, Gómez-Álvarez P (2014) Effect of the confinement and presence of cations on
hydrogen bonding of water in LTA-type zeolite. J Phys Chem C 118:9056–9065. https://doi.
org/10.1021/jp5014847
100. Gabruś E, Downarowicz D (2016) Anhydrous ethanol recovery from wet air in TSA systems –
equilibrium and column studies. Chem Eng J 288:321–331. https://doi.org/10.1016/j.cej.2015.
11.110
101. Remy T, Cousin Saint Remi J, Singh R et al (2011) Adsorption and separation of C1 À C8
alcohols on SAPO-34. J Phys Chem C 115:8117–8125. https://doi.org/10.1021/jp111615e
102. Miyamoto M, Iwatsuka H, Oumi Y et al (2019) Effect of core-shell structuring of chabazite
zeolite with a siliceous zeolite thin layer on the separation of acetone-butanol-ethanol vapor in
humid vapor conditions. Chem Eng J 363:292–299. https://doi.org/10.1016/j.cej.2019.01.106
103. Maddox IS (1982) Use of silicalite for the adsorption of n-butanol from fermentation liquors.
Biotechnol Lett 4:759–760. https://doi.org/10.1007/BF00134673
Efficient Downstream Processing of Renewable Alcohols Using Zeolite Adsorbents
113