50. Roth WJ, Nachtigall P, Morris RE, Wheatley PS, Seymour VR, Ashbrook SE, Chlubná P,
Grajciar L, Položij M, Zukal A, Shvets O, Čejka J (2013) A family of zeolites with controlled
pore size prepared using a top-down method. Nat Chem 5:628–633
51. Grajciar L, Čejka J, Zukal A, Arean CO, Palomino GT, Nachtigall P (2012) Controlling the
adsorption enthalpy of CO 2 in zeolites by framework topology and composition.
ChemSusChem 5:2011–2022
52. Bellatreche S, Hasnaoui MA, Ghezini R, Bengueddach A (2018) Thermodynamic adsorptive
properties of exchanged chabazite-like aluminophosphate SAPO-34. Fluid Phase Equilib
459:230–237
53. Rivera-Ramos ME, Ruiz-Mercado GJ, Hernández-Maldonado AJ (2008) Separation of CO 2
from light gas mixtures using ion-exchanged silicoaluminophosphate nanoporous sorbents.
Ind Eng Chem Res 47:5602–5610
54. Arevalo-Hidalgo AG, Santana JA, Fu R, Ishikawa Y, Hernandez-Maldonado AJ (2010)
Separation of CO 2 from light gas mixtures using nanoporous silicoaluminophosphate sorbents:
effect of multiple-step ion exchange and adsorption mechanism via computational studies.
Microporous Mesoporous Mater 130:142–153
55. Cheung O, Liu Q, Bacsik Z, Hedin N (2012) Silicoaluminophosphates as CO 2 sorbents.
Microporous Mesoporous Mater 156:90–96
56. Su X, Tian P, Fan D, Xia Q, Yang Y, Xu S, Zhang L, Zhang Y, Wang D, Liu Z (2013)
Synthesis of DNL-6 with a high concentration of Si (4 Al) environments and its application in
CO 2 separation. ChemSusChem 6:911–918
57. Park SH, Choi W, Choi HJ, Hong SB (2018) Organic-free synthesis of
silicoaluminophosphate molecular sieves. Angew Chem Int Ed 57:9413–9418
58. Liu Q, Cheung NCO, Garcia-Bennett AE, Hedin N (2011) Aluminophosphates for CO 2
separation. ChemSusChem 4:91–97
59. Zhong S, Bu N, Zhou R, Jin W, Yu M, Li S (2016) Aluminophosphate-17 and
silicoaluminophosphate-17 membranes for CO 2 separations. J Membr Sci 520:507–514
60. Akhtar F, Keshavarzi N, Shaharova D, Cheung O, Hedin N, Bergström L (2014)
Aluminophosphate monoliths with high CO 2 -over-N 2 selectivity and CO 2 capture capacity.
RSC Adv 4:55877–55883
61. Georgieva VM, Bruce EL, Verbraeken MC, Scott AR, Casteel Jr WJ, Brandani S, Wright PA
(2019) Triggered gate opening and breathing effects during selective CO 2 adsorption by
merlinoite zeolite. J Am Chem Soc 141:12744–12759
62. Koros WJ, Mahajan R (2000) Pushing the limits on possibilities for large scale gas separation:
which strategies? J Memb Sci 175:181–196
63. He Y, Zhou W, Krishna R, Chen B (2012) Microporous metal–organic frameworks for storage
and separation of small hydrocarbons. Chem Commun 48:11813–11831
64. Li J-R, Kuppler RJ, Zhou H-C (2009) Selective gas adsorption and separation in metal–
organic frameworks. Chem Soc Rev 38:1477–1504
65. Faiz R, Li K (2012) Olefin/paraffin separation using membrane based facilitated transport/
chemical absorption techniques. Chem Eng Sci 73:261–284
66. Moliner M, Martinez C, Corma A (2013) Synthesis strategies for preparing useful small pore
zeolites and zeotypes for gas separations and catalysis. Chem Mater 26:246–258
67. Rege SU, Yang RT (2002) Propane/propylene separation by pressure swing adsorption:
sorbent comparison and multiplicity of cyclic steady states. Chem Eng Sci 57:1139–1149
68. Rege SU, Padin J, Yang RT (1998) Olefin/paraffin separations by adsorption:
π-Complexation vs. kinetic separation. AICHE J 44:799–809
69. Cadiau A, Adil K, Bhatt P, Belmabkhout Y, Eddaoudi M (2016) A metal-organic framework–
based splitter for separating propylene from propane. Science 353:137–140
70. Boucheffa Y, Thomazeau C, Cartraud P, Magnoux P, Guisnet M, Julian S (1997) Formation of
carbonaceous compounds from propene and isobutene over a 5A zeolite. Influence of temperature on their compositions and locations. Ind Eng Chem Res 36:3198–3204
Small Gas Adsorption and Separation in Small-Pore Zeolites
27
Grajciar L, Položij M, Zukal A, Shvets O, Čejka J (2013) A family of zeolites with controlled
pore size prepared using a top-down method. Nat Chem 5:628–633
51. Grajciar L, Čejka J, Zukal A, Arean CO, Palomino GT, Nachtigall P (2012) Controlling the
adsorption enthalpy of CO 2 in zeolites by framework topology and composition.
ChemSusChem 5:2011–2022
52. Bellatreche S, Hasnaoui MA, Ghezini R, Bengueddach A (2018) Thermodynamic adsorptive
properties of exchanged chabazite-like aluminophosphate SAPO-34. Fluid Phase Equilib
459:230–237
53. Rivera-Ramos ME, Ruiz-Mercado GJ, Hernández-Maldonado AJ (2008) Separation of CO 2
from light gas mixtures using ion-exchanged silicoaluminophosphate nanoporous sorbents.
Ind Eng Chem Res 47:5602–5610
54. Arevalo-Hidalgo AG, Santana JA, Fu R, Ishikawa Y, Hernandez-Maldonado AJ (2010)
Separation of CO 2 from light gas mixtures using nanoporous silicoaluminophosphate sorbents:
effect of multiple-step ion exchange and adsorption mechanism via computational studies.
Microporous Mesoporous Mater 130:142–153
55. Cheung O, Liu Q, Bacsik Z, Hedin N (2012) Silicoaluminophosphates as CO 2 sorbents.
Microporous Mesoporous Mater 156:90–96
56. Su X, Tian P, Fan D, Xia Q, Yang Y, Xu S, Zhang L, Zhang Y, Wang D, Liu Z (2013)
Synthesis of DNL-6 with a high concentration of Si (4 Al) environments and its application in
CO 2 separation. ChemSusChem 6:911–918
57. Park SH, Choi W, Choi HJ, Hong SB (2018) Organic-free synthesis of
silicoaluminophosphate molecular sieves. Angew Chem Int Ed 57:9413–9418
58. Liu Q, Cheung NCO, Garcia-Bennett AE, Hedin N (2011) Aluminophosphates for CO 2
separation. ChemSusChem 4:91–97
59. Zhong S, Bu N, Zhou R, Jin W, Yu M, Li S (2016) Aluminophosphate-17 and
silicoaluminophosphate-17 membranes for CO 2 separations. J Membr Sci 520:507–514
60. Akhtar F, Keshavarzi N, Shaharova D, Cheung O, Hedin N, Bergström L (2014)
Aluminophosphate monoliths with high CO 2 -over-N 2 selectivity and CO 2 capture capacity.
RSC Adv 4:55877–55883
61. Georgieva VM, Bruce EL, Verbraeken MC, Scott AR, Casteel Jr WJ, Brandani S, Wright PA
(2019) Triggered gate opening and breathing effects during selective CO 2 adsorption by
merlinoite zeolite. J Am Chem Soc 141:12744–12759
62. Koros WJ, Mahajan R (2000) Pushing the limits on possibilities for large scale gas separation:
which strategies? J Memb Sci 175:181–196
63. He Y, Zhou W, Krishna R, Chen B (2012) Microporous metal–organic frameworks for storage
and separation of small hydrocarbons. Chem Commun 48:11813–11831
64. Li J-R, Kuppler RJ, Zhou H-C (2009) Selective gas adsorption and separation in metal–
organic frameworks. Chem Soc Rev 38:1477–1504
65. Faiz R, Li K (2012) Olefin/paraffin separation using membrane based facilitated transport/
chemical absorption techniques. Chem Eng Sci 73:261–284
66. Moliner M, Martinez C, Corma A (2013) Synthesis strategies for preparing useful small pore
zeolites and zeotypes for gas separations and catalysis. Chem Mater 26:246–258
67. Rege SU, Yang RT (2002) Propane/propylene separation by pressure swing adsorption:
sorbent comparison and multiplicity of cyclic steady states. Chem Eng Sci 57:1139–1149
68. Rege SU, Padin J, Yang RT (1998) Olefin/paraffin separations by adsorption:
π-Complexation vs. kinetic separation. AICHE J 44:799–809
69. Cadiau A, Adil K, Bhatt P, Belmabkhout Y, Eddaoudi M (2016) A metal-organic framework–
based splitter for separating propylene from propane. Science 353:137–140
70. Boucheffa Y, Thomazeau C, Cartraud P, Magnoux P, Guisnet M, Julian S (1997) Formation of
carbonaceous compounds from propene and isobutene over a 5A zeolite. Influence of temperature on their compositions and locations. Ind Eng Chem Res 36:3198–3204
Small Gas Adsorption and Separation in Small-Pore Zeolites
27