123. Bai P, Tsapatsis M, Siepmann JI (2012) Multicomponent adsorption of alcohols onto silicalite1 from aqueous solution: isotherms, structural analysis, and assessment of ideal adsorbed
solution theory. Langmuir 28:15566–15576. https://doi.org/10.1021/la303247c
124. Águeda VI, Delgado JA, Uguina MA et al (2013) Column dynamics of an adsorption-dryingdesorption process for butanol recovery from aqueous solutions with silicalite pellets. Sep
Purif Technol 104:307–321. https://doi.org/10.1016/j.seppur.2012.11.036
125. DeJaco RF, Bai P, Tsapatsis M, Siepmann JI (2016) Adsorptive separation of 1-butanol from
aqueous solutions using MFI- and FER-type zeolite frameworks: a Monte Carlo study.
Langmuir 32:2093–2101. https://doi.org/10.1021/acs.langmuir.5b04483
126. Faisal A, Zhou M, Hedlund J, Grahn M (2018) Zeolite MFI adsorbent for recovery of butanol
from ABE fermentation broths produced from an inexpensive black liquor-derived hydrolyzate. Biomass Conv Bioref 8:679–687. https://doi.org/10.1007/s13399-018-0315-9
127. Rutkai G, Csányi É, Kristóf T (2008) Prediction of adsorption and separation of water–alcohol
mixtures with zeolite NaA. Microporous Mesoporous Mater 114:455–464. https://doi.org/10.
1016/j.micromeso.2008.01.044
128. Krishna R, Van Baten JM (2010) Hydrogen bonding effects in adsorption of water-alcohol
mixtures in zeolites and the consequences for the characteristics of the Maxwell-Stefan
diffusivities. Langmuir 26:10854–10867. https://doi.org/10.1021/la100737c
129. Yamamoto T, Kim YH, Kim BC et al (2012) Adsorption characteristics of zeolites for
dehydration of ethanol: evaluation of diffusivity of water in porous structure. Chem Eng J
181–182:443–448. https://doi.org/10.1016/j.cej.2011.11.110
130. Simo M, Sivashanmugam S, Brown CJ, Hlavacek V (2009) Adsorption/desorption of water
and ethanol on 3A zeolite in near-adiabatic fixed bed. Ind Eng Chem Res 48:9247–9260.
https://doi.org/10.1021/ie900446v
131. Bedard R, Liu C (2018) Recent advances in zeolitic membranes. Annu Rev Mater Res
48:83–110. https://doi.org/10.1146/annurev-matsci-070317-124605
132. Jyothi MS, Reddy KR, Soontarapa K et al (2019) Membranes for dehydration of alcohols via
pervaporation. J Environ Manag 242:415–429. https://doi.org/10.1016/j.jenvman.2019.04.
043
133. Khalid A, Aslam M, Qyyum MA et al (2019) Membrane separation processes for dehydration
of bioethanol from fermentation broths: recent developments, challenges, and prospects.
Renew Sust Energ Rev 105:427–443. https://doi.org/10.1016/j.rser.2019.02.002
134. Couck S, Lefevere J, Mullens S et al (2017) CO 2, CH 4 and N 2 separation with a 3DFDprinted ZSM-5 monolith. Chem Eng J 308:719–726. https://doi.org/10.1016/j.cej.2016.09.046
135. Kokotailo GT, Lawton SL, Olson DH, Meier WM (1978) Structure of synthetic zeolite
ZSM-5. Nature 272:437–438. https://doi.org/10.1038/272437a0
136. Farzaneh A, Zhou M, Potapova E et al (2015) Adsorption of water and butanol in silicalite-1
film studied with in situ attenuated total reflectance-Fourier transform infrared spectroscopy.
Langmuir 31:4887–4894. https://doi.org/10.1021/acs.langmuir.5b00489
137. Flanigen EM, Bennett JM, Grose RW et al (1978) Silicalite, a new hydrophobic crystalline
silica molecular sieve. Nature 271:512–516. https://doi.org/10.1038/271512a0
138. Milestone NB, Bibby DM (1981) Concentration of alcohols by adsorption on silicalite. J
Chem Technol Biotechnol 31:732–736. https://doi.org/10.1002/jctb.503310198
139. Olson DH, Kokotailo GT, Lawton SL, Meier WM (1981) Crystal structure and structurerelated properties of ZSM-5. J Phys Chem 85:2238–2243. https://doi.org/10.1021/
j150615a020
140. Baerlocher C, McCusker LB. Database of zeolite structures. http://www.iza-structure.org/
databases/
141. Kooyman PJ, van der Waal P, van Bekkum H (1997) Acid dealumination of ZSM-5. Zeolites
18:50–53. https://doi.org/10.1016/S0144-2449(96)00106-6
142. Thamm H (1987) Adsorption site heterogeneity in silicalite: a calorimetric study. Zeolites
7:341–346. https://doi.org/10.1016/0144-2449(87)90037-6
Efficient Downstream Processing of Renewable Alcohols Using Zeolite Adsorbents
115
solution theory. Langmuir 28:15566–15576. https://doi.org/10.1021/la303247c
124. Águeda VI, Delgado JA, Uguina MA et al (2013) Column dynamics of an adsorption-dryingdesorption process for butanol recovery from aqueous solutions with silicalite pellets. Sep
Purif Technol 104:307–321. https://doi.org/10.1016/j.seppur.2012.11.036
125. DeJaco RF, Bai P, Tsapatsis M, Siepmann JI (2016) Adsorptive separation of 1-butanol from
aqueous solutions using MFI- and FER-type zeolite frameworks: a Monte Carlo study.
Langmuir 32:2093–2101. https://doi.org/10.1021/acs.langmuir.5b04483
126. Faisal A, Zhou M, Hedlund J, Grahn M (2018) Zeolite MFI adsorbent for recovery of butanol
from ABE fermentation broths produced from an inexpensive black liquor-derived hydrolyzate. Biomass Conv Bioref 8:679–687. https://doi.org/10.1007/s13399-018-0315-9
127. Rutkai G, Csányi É, Kristóf T (2008) Prediction of adsorption and separation of water–alcohol
mixtures with zeolite NaA. Microporous Mesoporous Mater 114:455–464. https://doi.org/10.
1016/j.micromeso.2008.01.044
128. Krishna R, Van Baten JM (2010) Hydrogen bonding effects in adsorption of water-alcohol
mixtures in zeolites and the consequences for the characteristics of the Maxwell-Stefan
diffusivities. Langmuir 26:10854–10867. https://doi.org/10.1021/la100737c
129. Yamamoto T, Kim YH, Kim BC et al (2012) Adsorption characteristics of zeolites for
dehydration of ethanol: evaluation of diffusivity of water in porous structure. Chem Eng J
181–182:443–448. https://doi.org/10.1016/j.cej.2011.11.110
130. Simo M, Sivashanmugam S, Brown CJ, Hlavacek V (2009) Adsorption/desorption of water
and ethanol on 3A zeolite in near-adiabatic fixed bed. Ind Eng Chem Res 48:9247–9260.
https://doi.org/10.1021/ie900446v
131. Bedard R, Liu C (2018) Recent advances in zeolitic membranes. Annu Rev Mater Res
48:83–110. https://doi.org/10.1146/annurev-matsci-070317-124605
132. Jyothi MS, Reddy KR, Soontarapa K et al (2019) Membranes for dehydration of alcohols via
pervaporation. J Environ Manag 242:415–429. https://doi.org/10.1016/j.jenvman.2019.04.
043
133. Khalid A, Aslam M, Qyyum MA et al (2019) Membrane separation processes for dehydration
of bioethanol from fermentation broths: recent developments, challenges, and prospects.
Renew Sust Energ Rev 105:427–443. https://doi.org/10.1016/j.rser.2019.02.002
134. Couck S, Lefevere J, Mullens S et al (2017) CO 2, CH 4 and N 2 separation with a 3DFDprinted ZSM-5 monolith. Chem Eng J 308:719–726. https://doi.org/10.1016/j.cej.2016.09.046
135. Kokotailo GT, Lawton SL, Olson DH, Meier WM (1978) Structure of synthetic zeolite
ZSM-5. Nature 272:437–438. https://doi.org/10.1038/272437a0
136. Farzaneh A, Zhou M, Potapova E et al (2015) Adsorption of water and butanol in silicalite-1
film studied with in situ attenuated total reflectance-Fourier transform infrared spectroscopy.
Langmuir 31:4887–4894. https://doi.org/10.1021/acs.langmuir.5b00489
137. Flanigen EM, Bennett JM, Grose RW et al (1978) Silicalite, a new hydrophobic crystalline
silica molecular sieve. Nature 271:512–516. https://doi.org/10.1038/271512a0
138. Milestone NB, Bibby DM (1981) Concentration of alcohols by adsorption on silicalite. J
Chem Technol Biotechnol 31:732–736. https://doi.org/10.1002/jctb.503310198
139. Olson DH, Kokotailo GT, Lawton SL, Meier WM (1981) Crystal structure and structurerelated properties of ZSM-5. J Phys Chem 85:2238–2243. https://doi.org/10.1021/
j150615a020
140. Baerlocher C, McCusker LB. Database of zeolite structures. http://www.iza-structure.org/
databases/
141. Kooyman PJ, van der Waal P, van Bekkum H (1997) Acid dealumination of ZSM-5. Zeolites
18:50–53. https://doi.org/10.1016/S0144-2449(96)00106-6
142. Thamm H (1987) Adsorption site heterogeneity in silicalite: a calorimetric study. Zeolites
7:341–346. https://doi.org/10.1016/0144-2449(87)90037-6
Efficient Downstream Processing of Renewable Alcohols Using Zeolite Adsorbents
115