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resin. Biotechnol Prog 28:962–972. https://doi.org/10.1002/btpr.1553
51. Lin X, Xiong L, Qi G et al (2015) Using butanol fermentation wastewater for biobutanol
production after removal of inhibitory compounds by micro/mesoporous hyper-cross-linked
polymeric adsorbent. ACS Sustain Chem Eng 3:702–709. https://doi.org/10.1021/
acssuschemeng.5b00010
52. Oudshoorn A, van der Wielen LAM, Straathof AJJ (2009) Adsorption equilibria of bio-based
butanol solutions using zeolite. Biochem Eng J 48:99–103. https://doi.org/10.1016/j.bej.2009.
08.014
53. Qureshi N, Hughes S, Maddox IS, Cotta MA (2005) Energy-efficient recovery of butanol from
model solutions and fermentation broth by adsorption. Bioprocess Biosyst Eng 27:215–222.
https://doi.org/10.1007/s00449-005-0402-8
54. Abdehagh N, Tezel FH, Thibault J (2014) Separation techniques in butanol production:
challenges and developments. Biomass Bioenergy 60:222–246. https://doi.org/10.1016/j.
biombioe.2013.10.003
55. Abdehagh N, Gurnani P, Tezel FH, Thibault J (2015) Adsorptive separation and recovery of
biobutanol from ABE model solutions. Adsorption 21:185–194. https://doi.org/10.1007/
s10450-015-9661-0
56. Cousin Saint Remi J, Remy T, Vanhunskerken V et al (2011) Biobutanol separation with the
metal-organic framework ZIF-8. ChemSusChem 4:1074–1077. https://doi.org/10.1002/cssc.
201100261
57. Cousin Saint Remi J, Baron G, Denayer J (2012) Adsorptive separations for the recovery and
purification of biobutanol. Adsorption 18:367–373. https://doi.org/10.1007/s10450-012-94151
58. Cousin-Saint-Remi J, Finoulst A-L, Jabbour C et al (2019) Selection of binder recipes for the
formulation of MOFs into resistant pellets for molecular separations by fixed-bed adsorption.
Microporous Mesoporous Mater. https://doi.org/10.1016/j.micromeso.2019.02.009
59. Van der Perre S, Gelin P, Claessens B et al (2017) Intensified biobutanol recovery by using
zeolites with complementary selectivity. ChemSusChem 10:2968–2977. https://doi.org/10.
1002/cssc.201700667
60. Cousin-Saint-Remi J, Van Der Perre S, Segato T et al (2019) Highly robust MOF polymeric
beads with controllable size for molecular separations. ACS Appl Mater Interfaces
11:13694–13703. https://doi.org/10.1021/acsami.9b00521
61. Faisal A, Zarebska A, Saremi P et al (2014) MFI zeolite as adsorbent for selective recovery of
hydrocarbons from ABE fermentation broths. Adsorption 20:465–470. https://doi.org/10.
1007/s10450-013-9576-6
62. Li SY, Chiang CJ, Tseng IT et al (2016) Bioreactors and in situ product recovery techniques
for acetone-butanol-ethanol fermentation. FEMS Microbiol Lett 363:1–7. https://doi.org/10.
1093/femsle/fnw107
63. Qureshi N, Blaschek H (2001) Evaluation of recent advances in butanol fermentation,
upstream, and downstream processing. Bioprocess Biosyst Eng 24:219–226. https://doi.org/
10.1007/s004490100257
64. Roffler S, Blanch HW, Wilke CR (1987) Extractive fermentation of acetone and butanol:
process design and economic evaluation. Biotechnol Prog 3:131–140. https://doi.org/10.1002/
btpr.5420030304
65. Sánchez-Ramírez E, Quiroz-Ramírez JJ, Segovia-Hernández JG et al (2015) Process alternatives for biobutanol purification: design and optimization. Ind Eng Chem Res 54:351–358.
https://doi.org/10.1021/ie503975g
66. Patraşcu I, Bîldea CS, Kiss AA (2017) Eco-efficient butanol separation in the ABE fermentation process. Sep Purif Technol 177:49–61. https://doi.org/10.1016/j.seppur.2016.12.008
67. Hahn H-D, Dämbkes G, Rupprich N et al (2013) Butanols. Ullmann’s Encycl Ind Chem.
https://doi.org/10.1002/14356007.a04_463.pub3
Efficient Downstream Processing of Renewable Alcohols Using Zeolite Adsorbents
111
resin. Biotechnol Prog 28:962–972. https://doi.org/10.1002/btpr.1553
51. Lin X, Xiong L, Qi G et al (2015) Using butanol fermentation wastewater for biobutanol
production after removal of inhibitory compounds by micro/mesoporous hyper-cross-linked
polymeric adsorbent. ACS Sustain Chem Eng 3:702–709. https://doi.org/10.1021/
acssuschemeng.5b00010
52. Oudshoorn A, van der Wielen LAM, Straathof AJJ (2009) Adsorption equilibria of bio-based
butanol solutions using zeolite. Biochem Eng J 48:99–103. https://doi.org/10.1016/j.bej.2009.
08.014
53. Qureshi N, Hughes S, Maddox IS, Cotta MA (2005) Energy-efficient recovery of butanol from
model solutions and fermentation broth by adsorption. Bioprocess Biosyst Eng 27:215–222.
https://doi.org/10.1007/s00449-005-0402-8
54. Abdehagh N, Tezel FH, Thibault J (2014) Separation techniques in butanol production:
challenges and developments. Biomass Bioenergy 60:222–246. https://doi.org/10.1016/j.
biombioe.2013.10.003
55. Abdehagh N, Gurnani P, Tezel FH, Thibault J (2015) Adsorptive separation and recovery of
biobutanol from ABE model solutions. Adsorption 21:185–194. https://doi.org/10.1007/
s10450-015-9661-0
56. Cousin Saint Remi J, Remy T, Vanhunskerken V et al (2011) Biobutanol separation with the
metal-organic framework ZIF-8. ChemSusChem 4:1074–1077. https://doi.org/10.1002/cssc.
201100261
57. Cousin Saint Remi J, Baron G, Denayer J (2012) Adsorptive separations for the recovery and
purification of biobutanol. Adsorption 18:367–373. https://doi.org/10.1007/s10450-012-94151
58. Cousin-Saint-Remi J, Finoulst A-L, Jabbour C et al (2019) Selection of binder recipes for the
formulation of MOFs into resistant pellets for molecular separations by fixed-bed adsorption.
Microporous Mesoporous Mater. https://doi.org/10.1016/j.micromeso.2019.02.009
59. Van der Perre S, Gelin P, Claessens B et al (2017) Intensified biobutanol recovery by using
zeolites with complementary selectivity. ChemSusChem 10:2968–2977. https://doi.org/10.
1002/cssc.201700667
60. Cousin-Saint-Remi J, Van Der Perre S, Segato T et al (2019) Highly robust MOF polymeric
beads with controllable size for molecular separations. ACS Appl Mater Interfaces
11:13694–13703. https://doi.org/10.1021/acsami.9b00521
61. Faisal A, Zarebska A, Saremi P et al (2014) MFI zeolite as adsorbent for selective recovery of
hydrocarbons from ABE fermentation broths. Adsorption 20:465–470. https://doi.org/10.
1007/s10450-013-9576-6
62. Li SY, Chiang CJ, Tseng IT et al (2016) Bioreactors and in situ product recovery techniques
for acetone-butanol-ethanol fermentation. FEMS Microbiol Lett 363:1–7. https://doi.org/10.
1093/femsle/fnw107
63. Qureshi N, Blaschek H (2001) Evaluation of recent advances in butanol fermentation,
upstream, and downstream processing. Bioprocess Biosyst Eng 24:219–226. https://doi.org/
10.1007/s004490100257
64. Roffler S, Blanch HW, Wilke CR (1987) Extractive fermentation of acetone and butanol:
process design and economic evaluation. Biotechnol Prog 3:131–140. https://doi.org/10.1002/
btpr.5420030304
65. Sánchez-Ramírez E, Quiroz-Ramírez JJ, Segovia-Hernández JG et al (2015) Process alternatives for biobutanol purification: design and optimization. Ind Eng Chem Res 54:351–358.
https://doi.org/10.1021/ie503975g
66. Patraşcu I, Bîldea CS, Kiss AA (2017) Eco-efficient butanol separation in the ABE fermentation process. Sep Purif Technol 177:49–61. https://doi.org/10.1016/j.seppur.2016.12.008
67. Hahn H-D, Dämbkes G, Rupprich N et al (2013) Butanols. Ullmann’s Encycl Ind Chem.
https://doi.org/10.1002/14356007.a04_463.pub3
Efficient Downstream Processing of Renewable Alcohols Using Zeolite Adsorbents
111