References
11
43. Emig N, Gabbaï FP, Krautscheid H, Réau R, Bertrand G (1998) The azide-nitrilimine analogy
in aluminum chemistry. Angew Chemie Int Ed 37:989–992
44. Arthur M-P, Baceiredo A, Fischer J, De Cian A, Bertrand G (1992) Substitution reactions at
nitrilimine skeletons. Synthesis (Stuttg) 43–45
45. Uhl W, Hannemann F, Saak W, Wartchow R (1999) Diazomethane derivatives bearing
dialkylaluminium or dialkylgallium substituents—the isomeric diazomethane and nitrile imine
structures realized by the different coordination behavior of aluminium and gallium. Eur J Inorg
Chem 1999:771–776
46. Nunes CM, Reva I, Fausto R, Bégué D, Wentrup C (2015) Bond-shift isomers: the co-existence
of allenic and propargylic phenylnitrile imines. Chem Commun 51:14712–14715
47. Herges R (1994) Organizing principle of complex reactions and theory of coarctate transition
states. Angew Chemie Int Ed English 33:255–276
48. Bégué D, Wentrup C (2014) Carbenic nitrile imines: properties and reactivity. J Org Chem
79:1418–1426
49. Nunes CM, Reva I, Rosado MTS, Fausto R (2015) The Quest for carbenic nitrile imines:
experimental and computational characterization of C-amino nitrile imine. European J Org
Chem 7484–7493
50. Sieber W, Gilgen P, Chaloupka S, Hansen H-J, Schmid H (1973) Tieftemperaturbestrahlungen
von 3-Phenyl-2H-azirinen. Helv Chim Acta 56:1679–1690
51. Meier Hansruedi, Heinzelmann Willy, Heimgartner H (1980) Direct detection of
diphenylnitrilimine in the photolysis of 2,5-diphenyltetrazole. Chimia (Aarau) 34:504–506
52. Meier Hansruedi, Heinzelmann Willy, Heimgartner H (1980) Inter- and intramolecular trapping
reactions of photochemically generated diarylnitrilimines. Chimia (Aarau) 34:506–508
53. Toubro NH, Holm A (1980) Nitrilimines. J Am Chem Soc 102:2093–2094
54. Csongár C, Leihkauf P, Lohse V, Tomaschewski G (1984) Photochemistry of aryl-substituted
2H-Tetrazoles I. Direct spectroscopic detection of diarylnitrilimines. Zeitschrift für Chemie
24:96–97
55. Csongár C, Leihkauf P, Lohse V, Siegmund M, Tomaschewski G (1985) Photochemistry of
aryl-substituted 2 H-tetrazoles III. IR spectroscopic detection of diarylnitrilimines. Zeitschrift
für Chemie 25:106–107
56. Csongár C, Leihkauf P, Lohse V, Tomaschewski G (1985) Photochemistry of diarylsubstituted
2H-tetrazoles II, The influence of the substituents on the absorption properties of
diarylnitrilmines. J für Prakt Chemie 327:96–102
57. Leihkauf P, Lohse V, Csongár C, Siegmund M, Tomaschewski G (1987) Photochemistry of
diaryl-substituted 2H-tetrazoles V. On the influence of the substituents on the C = N-Valence
vibrations of diaryl-substituted nitrilimines. Zeitschrift für Chemie 27:371–372
58. Leihkauf P, Lohse V, Csongár C, Tomaschewski G (1985) Photochemistry of aryl-substituted
2H-tetrazoles IV. and Sydnone II. Flash photolysis of diaryl nitrilimines. Zeitschrift für Chemie
25:266–267
59. Bhattacharyya K, Ramalah D, Das PK, George MV (1987) Flash photolysis studies of
nitrile imines and related intermediates photogenerated from sydnones and tetrazoles in fluid
solutions. J Photochem 36:63–84
60. Wentrup C, Flammang R (1998) Studies of reactive intermediates using matrix and gas-phase
techniques. J Phys Org Chem 11:350–355
61. Wentrup C, Fischer S, Maquestiau A, Flammang R (1985) Nitrile imines: thermal generation,
direct observation, and subsequent trapping. Angew Chemie Int Ed English 24:56–57
62. Nunes CM, Araujo-Andrade C, Fausto R, Reva I (2014) Generation and characterization
of a 4π-electron three-membered ring 1H-diazirine: an elusive intermediate in nitrile
imine-carbodiimide isomerization. J Org Chem 79:3641–3646
63. von Locquenghien KH, Réau R, Bertrand G (1991) The first nitrogen NMR spectroscopic study
of nitrile imides (Nitrilimines). J Chem Soc, Chem Commun 1192–1193
64. Zheng S-L, Wang Y, Yu Z, Lin Q, Coppens P (2009) Direct observation of a photoinduced
nonstabilized nitrile imine structure in the solid state. J Am Chem Soc 131:18036–18037
11
43. Emig N, Gabbaï FP, Krautscheid H, Réau R, Bertrand G (1998) The azide-nitrilimine analogy
in aluminum chemistry. Angew Chemie Int Ed 37:989–992
44. Arthur M-P, Baceiredo A, Fischer J, De Cian A, Bertrand G (1992) Substitution reactions at
nitrilimine skeletons. Synthesis (Stuttg) 43–45
45. Uhl W, Hannemann F, Saak W, Wartchow R (1999) Diazomethane derivatives bearing
dialkylaluminium or dialkylgallium substituents—the isomeric diazomethane and nitrile imine
structures realized by the different coordination behavior of aluminium and gallium. Eur J Inorg
Chem 1999:771–776
46. Nunes CM, Reva I, Fausto R, Bégué D, Wentrup C (2015) Bond-shift isomers: the co-existence
of allenic and propargylic phenylnitrile imines. Chem Commun 51:14712–14715
47. Herges R (1994) Organizing principle of complex reactions and theory of coarctate transition
states. Angew Chemie Int Ed English 33:255–276
48. Bégué D, Wentrup C (2014) Carbenic nitrile imines: properties and reactivity. J Org Chem
79:1418–1426
49. Nunes CM, Reva I, Rosado MTS, Fausto R (2015) The Quest for carbenic nitrile imines:
experimental and computational characterization of C-amino nitrile imine. European J Org
Chem 7484–7493
50. Sieber W, Gilgen P, Chaloupka S, Hansen H-J, Schmid H (1973) Tieftemperaturbestrahlungen
von 3-Phenyl-2H-azirinen. Helv Chim Acta 56:1679–1690
51. Meier Hansruedi, Heinzelmann Willy, Heimgartner H (1980) Direct detection of
diphenylnitrilimine in the photolysis of 2,5-diphenyltetrazole. Chimia (Aarau) 34:504–506
52. Meier Hansruedi, Heinzelmann Willy, Heimgartner H (1980) Inter- and intramolecular trapping
reactions of photochemically generated diarylnitrilimines. Chimia (Aarau) 34:506–508
53. Toubro NH, Holm A (1980) Nitrilimines. J Am Chem Soc 102:2093–2094
54. Csongár C, Leihkauf P, Lohse V, Tomaschewski G (1984) Photochemistry of aryl-substituted
2H-Tetrazoles I. Direct spectroscopic detection of diarylnitrilimines. Zeitschrift für Chemie
24:96–97
55. Csongár C, Leihkauf P, Lohse V, Siegmund M, Tomaschewski G (1985) Photochemistry of
aryl-substituted 2 H-tetrazoles III. IR spectroscopic detection of diarylnitrilimines. Zeitschrift
für Chemie 25:106–107
56. Csongár C, Leihkauf P, Lohse V, Tomaschewski G (1985) Photochemistry of diarylsubstituted
2H-tetrazoles II, The influence of the substituents on the absorption properties of
diarylnitrilmines. J für Prakt Chemie 327:96–102
57. Leihkauf P, Lohse V, Csongár C, Siegmund M, Tomaschewski G (1987) Photochemistry of
diaryl-substituted 2H-tetrazoles V. On the influence of the substituents on the C = N-Valence
vibrations of diaryl-substituted nitrilimines. Zeitschrift für Chemie 27:371–372
58. Leihkauf P, Lohse V, Csongár C, Tomaschewski G (1985) Photochemistry of aryl-substituted
2H-tetrazoles IV. and Sydnone II. Flash photolysis of diaryl nitrilimines. Zeitschrift für Chemie
25:266–267
59. Bhattacharyya K, Ramalah D, Das PK, George MV (1987) Flash photolysis studies of
nitrile imines and related intermediates photogenerated from sydnones and tetrazoles in fluid
solutions. J Photochem 36:63–84
60. Wentrup C, Flammang R (1998) Studies of reactive intermediates using matrix and gas-phase
techniques. J Phys Org Chem 11:350–355
61. Wentrup C, Fischer S, Maquestiau A, Flammang R (1985) Nitrile imines: thermal generation,
direct observation, and subsequent trapping. Angew Chemie Int Ed English 24:56–57
62. Nunes CM, Araujo-Andrade C, Fausto R, Reva I (2014) Generation and characterization
of a 4π-electron three-membered ring 1H-diazirine: an elusive intermediate in nitrile
imine-carbodiimide isomerization. J Org Chem 79:3641–3646
63. von Locquenghien KH, Réau R, Bertrand G (1991) The first nitrogen NMR spectroscopic study
of nitrile imides (Nitrilimines). J Chem Soc, Chem Commun 1192–1193
64. Zheng S-L, Wang Y, Yu Z, Lin Q, Coppens P (2009) Direct observation of a photoinduced
nonstabilized nitrile imine structure in the solid state. J Am Chem Soc 131:18036–18037