148
4 Applications of Nitrile Imine Derivatives
106. Liu B, Cong H, Li X, Yu B, Bao L, Cai W, Xie Y, Lu X (2014) Highly regioselective 1,3-dipolar
cycloaddition of diphenylnitrilimine to Sc 3 N@/ h -C 80 affording a very stable, unprecedented
pyrazole-ring fused derivative of Endohedral metallofullerenes. Chem Commun 50:12710–
12713
107. Kirner S, Sekita M, Guldi DM (2014) 25th anniversary article: 25 years of fullerene research
in electron transfer chemistry. Adv Mater 26:1482–1493
108. Guldi DM (2002) Fullerene-porphyrin architectures; photosynthetic antenna and reaction
center models. Chem Soc Rev 31:22–36
109. Gust D, Moore TA, Moore AL (2001) Mimicking photosynthetic solar energy transduction.
Acc Chem Res 34:40–48
110. Langa F, de la Cruz P, Delgado JL, Gómez-Escalonilla MJ, González-Cortés A, de la Hoz A,
López-Arza V (2002) The importance of the linking bridge in donor–C 60 electroactive dyads.
New J Chem 26:76–80
111. Espildora E, Delgado JL, de la Cruz P, de la Hoz A, Lopez-Arza V, Langa F (2002) Synthesis
and properties of Pyrazolino[60]fullerene-donor systems. Tetrahedron 58:5821–5826
112. Oviedo JJ, de la Cruz P, Garin J, Orduna J, Langa F (2005) Ruthenocene as a new donor
fragment in [60]fullerene–donor dyads. Tetrahedron Lett 46:4781–4784
113. Langa F, de la Cruz P, Espíldora E, de la Hoz A, Bourdelande JL, Sánchez L, Martín
N (2001) C 60 -based triads with improved electron-acceptor properties: Pyrazolylpyrazolino[60]fullerenes. J Org Chem 66:5033–5041
114. Delgado JL, Osuna S, Bouit P-A, Martínez-Alvarez R, Espíldora E, Solà M, Martín N
(2009) Competitive retro-cycloaddition reaction in fullerene dimers connected through
pyrrolidinopyrazolino rings. J Org Chem 74:8174–8180
115. Delgado JL, Oswald F, Cardinali F, Langa F, Martín N (2008) On the thermal stability of [60]fullerene cycloadducts: retro-cycloaddition reaction of
2-Pyrazolino[4,5:1,2][60]fullerenes. J Org Chem 73:3184–3188
116. Kennedy RD, Ayzner AL, Wanger DD, Day CT, Halim M, Khan SI, Tolbert SH, Schwartz
BJ, Rubin Y (2008) Self-assembling fullerenes for improved bulk-heterojunction photovoltaic
devices. J Am Chem Soc 130:17290–17292
117. Vorobiev AK, Gazizov RR, Borschevskii AY, Markov VY, Ioutsi VA, Brotsman VA, Sidorov
LN (2017) Fullerene as photocatalyst: visible-light induced reaction of perfluorinated α, ωDiiodoalkanes with C60. J Phys Chem A 121:113–121
118. Sibley SP, Argentine SM, Francis AH (1992) A photoluminescence study of C 60 and C 70 .
Chem Phys Lett 188:187–193
119. Castro E, Garcia AH, Zavala G, Echegoyen L (2017) Fullerenes in biology and medicine. J
Mater Chem B 5:6523–6535
120. Delgado Juan L, de la Cruz Pilar, López-Arza V, Langa F, Kimball DB, Haley MM, Araki
Y, Ito O (2004) The Isoindazole nucleus as a donor in fullerene-based dyads. Evidence for
electron transfer. J Org Chem 69:2661–2668
121. Langa F, Gomez-Escalonilla MJ, Diez-Barra E, Garcia-Martinez JC, de la Hoz A, RodriguezLopez J, Gonzalez-Cortes A, Lopez-Arza V (2001) Synthesis, electrochemistry and photophysical properties of phenylenevinylene fullerodendrimers. Tetrahedron Lett 42:3435–3438
122. Parra V, del Caño T, Gómez-Escalonilla MJ, Langa F, Rodríguez-Méndez ML, De Saja JA
(2005) Photophysics, electrochemistry and structure of a Pyrazolino[60]fullerene dendrimer
in solid molecular films. Synth Met 148:47–52
123. Armaroli N, Accorsi G, Gisselbrecht J-P, Gross M, Krasnikov V, Tsamouras D, Hadziioannou G, Gómez-Escalonilla MJ, Langa F, Eckert J-F, Nierengarten J-F (2002) Photoinduced
processes in Fullerenopyrrolidine and Fullerenopyrazoline derivatives substituted with an
Oligophenylenevinylene Moiety. J Mater Chem 12:2077–2087
124. Gómez-Escalonilla MJ, Langa F, Rueff JM, Oswald L, Nierengarten JF (2002) Synthesis of Dumbbell-Shaped bis-(pyrazolino[60]fullerene)-oligophenylenevinylene derivatives.
Tetrahedron Lett 43:7507–7511
4 Applications of Nitrile Imine Derivatives
106. Liu B, Cong H, Li X, Yu B, Bao L, Cai W, Xie Y, Lu X (2014) Highly regioselective 1,3-dipolar
cycloaddition of diphenylnitrilimine to Sc 3 N@/ h -C 80 affording a very stable, unprecedented
pyrazole-ring fused derivative of Endohedral metallofullerenes. Chem Commun 50:12710–
12713
107. Kirner S, Sekita M, Guldi DM (2014) 25th anniversary article: 25 years of fullerene research
in electron transfer chemistry. Adv Mater 26:1482–1493
108. Guldi DM (2002) Fullerene-porphyrin architectures; photosynthetic antenna and reaction
center models. Chem Soc Rev 31:22–36
109. Gust D, Moore TA, Moore AL (2001) Mimicking photosynthetic solar energy transduction.
Acc Chem Res 34:40–48
110. Langa F, de la Cruz P, Delgado JL, Gómez-Escalonilla MJ, González-Cortés A, de la Hoz A,
López-Arza V (2002) The importance of the linking bridge in donor–C 60 electroactive dyads.
New J Chem 26:76–80
111. Espildora E, Delgado JL, de la Cruz P, de la Hoz A, Lopez-Arza V, Langa F (2002) Synthesis
and properties of Pyrazolino[60]fullerene-donor systems. Tetrahedron 58:5821–5826
112. Oviedo JJ, de la Cruz P, Garin J, Orduna J, Langa F (2005) Ruthenocene as a new donor
fragment in [60]fullerene–donor dyads. Tetrahedron Lett 46:4781–4784
113. Langa F, de la Cruz P, Espíldora E, de la Hoz A, Bourdelande JL, Sánchez L, Martín
N (2001) C 60 -based triads with improved electron-acceptor properties: Pyrazolylpyrazolino[60]fullerenes. J Org Chem 66:5033–5041
114. Delgado JL, Osuna S, Bouit P-A, Martínez-Alvarez R, Espíldora E, Solà M, Martín N
(2009) Competitive retro-cycloaddition reaction in fullerene dimers connected through
pyrrolidinopyrazolino rings. J Org Chem 74:8174–8180
115. Delgado JL, Oswald F, Cardinali F, Langa F, Martín N (2008) On the thermal stability of [60]fullerene cycloadducts: retro-cycloaddition reaction of
2-Pyrazolino[4,5:1,2][60]fullerenes. J Org Chem 73:3184–3188
116. Kennedy RD, Ayzner AL, Wanger DD, Day CT, Halim M, Khan SI, Tolbert SH, Schwartz
BJ, Rubin Y (2008) Self-assembling fullerenes for improved bulk-heterojunction photovoltaic
devices. J Am Chem Soc 130:17290–17292
117. Vorobiev AK, Gazizov RR, Borschevskii AY, Markov VY, Ioutsi VA, Brotsman VA, Sidorov
LN (2017) Fullerene as photocatalyst: visible-light induced reaction of perfluorinated α, ωDiiodoalkanes with C60. J Phys Chem A 121:113–121
118. Sibley SP, Argentine SM, Francis AH (1992) A photoluminescence study of C 60 and C 70 .
Chem Phys Lett 188:187–193
119. Castro E, Garcia AH, Zavala G, Echegoyen L (2017) Fullerenes in biology and medicine. J
Mater Chem B 5:6523–6535
120. Delgado Juan L, de la Cruz Pilar, López-Arza V, Langa F, Kimball DB, Haley MM, Araki
Y, Ito O (2004) The Isoindazole nucleus as a donor in fullerene-based dyads. Evidence for
electron transfer. J Org Chem 69:2661–2668
121. Langa F, Gomez-Escalonilla MJ, Diez-Barra E, Garcia-Martinez JC, de la Hoz A, RodriguezLopez J, Gonzalez-Cortes A, Lopez-Arza V (2001) Synthesis, electrochemistry and photophysical properties of phenylenevinylene fullerodendrimers. Tetrahedron Lett 42:3435–3438
122. Parra V, del Caño T, Gómez-Escalonilla MJ, Langa F, Rodríguez-Méndez ML, De Saja JA
(2005) Photophysics, electrochemistry and structure of a Pyrazolino[60]fullerene dendrimer
in solid molecular films. Synth Met 148:47–52
123. Armaroli N, Accorsi G, Gisselbrecht J-P, Gross M, Krasnikov V, Tsamouras D, Hadziioannou G, Gómez-Escalonilla MJ, Langa F, Eckert J-F, Nierengarten J-F (2002) Photoinduced
processes in Fullerenopyrrolidine and Fullerenopyrazoline derivatives substituted with an
Oligophenylenevinylene Moiety. J Mater Chem 12:2077–2087
124. Gómez-Escalonilla MJ, Langa F, Rueff JM, Oswald L, Nierengarten JF (2002) Synthesis of Dumbbell-Shaped bis-(pyrazolino[60]fullerene)-oligophenylenevinylene derivatives.
Tetrahedron Lett 43:7507–7511
