21. Schaefer MV, Gorski CA, Scherer MM (2011) Spectroscopic evidence for interfacial Fe(II)ÀFe
(III) electron transfer in a clay mineral. Environ Sci Technol 45(2):540–545
22. Gibb TC, Greenwood NN (1971) Mössbauer spectroscopy. Chapman and Hall Ltd, London
23. Kuzmann E, Nagy S, Vértes A (2003) Critical review of analytical applications of Mössbauer
spectroscopy illustrated by mineralogical and geological examples (IUPAC Technical Report).
Pure Appl Chem 75:801–858
24. Parida KM, Mishra T, Das D et al (1999) Thermal transformation of trinuclear Fe(III) acetato
complex intercalated montmorillonite. Appl Clay Sci 15(5–6):463–475
25. Bustamante Mamani J, Fernel Gamarra L, Espósito de Souza Brito G (2014) Synthesis and
characterization of Fe 3 O 4 nanoparticles with perspectives in biomedical applications. Mat Res
17(3):542–549
26. Herojitsingh L, Govindaraja R, Amarendra G et al (2013) Local structure and magnetic
properties of cubic iron oxide nanoparticles formed in zeolite as deduced using Mössbauer
spectroscopy. Appl Phys Lett 103:193104
27. Johnson CE, Johnson JA, Hah HY et al (2016) Mössbauer studies of stoichiometry of Fe 3 O 4 :
characterization of nanoparticles for biomedical applications. Hyperfine Interact 237:27
28. Ahn T, Kim JH, Yang H-M et al (2012) Formation pathways of magnetite nanoparticles by
coprecipitation method. J Phys Chem C 116(10):6069–6076
29. Guyodo Y, Bonville P, Till JL et al (2016) Constraining the origins of the magnetism of
lepidocrocite (γ-FeOOH): a Mössbauer and magnetization study. Front Earth Sci 4:28
30. Lozano I, Casillas N, Ponce de León C et al (2017) New insights into the electrochemical
formation of magnetite nanoparticles. J Electrochem Soc 164(4):D184–D191
31. Hurtado L, Romero R, Mendoza A, Brewer S, Donkor K, Gómez-Espinosa RM, Natividad R
(2019) Paracetamol mineralization by Photo Fenton process catalyzed by a Cu/Fe-PILC under
circumneutral pH conditions. J Photochem Photobiol A Chem. 373:162–170
32. Undabeytia T, Galán-Jiménez MC, Gómez-Pantoja E et al (2013) Fe-pillared clay mineralbased formulations of imazaquin for reduced leaching in soil. Appl Clay Sci 80-81:382–389
33. SanJuan-Reyes N, Gomez-Olivan LM, Galar-Martinez M et al (2015) NSAID-manufacturing
plant effluent induces geno- and cytotoxicity in common carp (Cyprinus carpio). Sci Total
Environ 530-531C:1–10
34. Chen Q, Wu P, Dang Z et al (2010) Iron pillared vermiculite as a heterogeneous photo-Fenton
catalyst for photocatalytic degradation of azo dye reactive brilliant orange X-GN. Sep Purif
Technol 71:315–323
35. Michael I, Hapeshi E, Michael C et al (2012) Solar photo-Fenton process on the abatement of
antibiotics at a pilot scale: degradation kinetics, ecotoxicity and phytotoxicity assessment and
removal of antibiotic resistant enterococci. Water Res 46:5621–5634
36. Melero JA, Martinez F, Botas JA et al (2009) Heterogeneous catalytic wet peroxide oxidation
systems for the treatment of an industrial pharmaceutical wastewater. Water Res 43:4010–4018
37. Sun J, Feng J, Shi S et al (2012) Degradation of the antibiotic sulfamonomethoxine sodium in
aqueous solution by photo-Fenton oxidation. Chin Sci Bull 57:558–564
38. Ji F, Li C, Zhang J et al (2011) Heterogeneous photo-Fenton decolorization of methylene blue
over LiFe(WO 4 ) 2 catalyst. J Hazard Mater 186:1979–1984
39. Pariente M, Martinez F, Melero J et al (2008) Heterogeneous photo-Fenton oxidation of benzoic
acid in water: effect of operating conditions, reaction by-products and coupling with biological
treatment. Appl Catal B-Environ 85:24–32
40. Ayodele OB, Lim JK, Hameed BH (2012) Pillared montmorillonite supported ferric oxalate as
heterogeneous photo-Fenton catalyst for degradation of amoxicillin. Appl Catal A-Gen
413-414:301–309
41. Herney-Ramirez J, Vicente MA, Madeira LM (2010) Heterogeneous photo-Fenton oxidation
with pillared clay-based catalysts for wastewater treatment: a review. Appl Catal B-Environ
98:10–26
42. De León MA, Castiglioni J, Bussi J et al (2008) Catalytic activity of an iron-pillared montmorillonitic clay mineral in heterogeneous photo-Fenton process. Catal Today 133–135:600–605
258
R. Natividad et al.
(III) electron transfer in a clay mineral. Environ Sci Technol 45(2):540–545
22. Gibb TC, Greenwood NN (1971) Mössbauer spectroscopy. Chapman and Hall Ltd, London
23. Kuzmann E, Nagy S, Vértes A (2003) Critical review of analytical applications of Mössbauer
spectroscopy illustrated by mineralogical and geological examples (IUPAC Technical Report).
Pure Appl Chem 75:801–858
24. Parida KM, Mishra T, Das D et al (1999) Thermal transformation of trinuclear Fe(III) acetato
complex intercalated montmorillonite. Appl Clay Sci 15(5–6):463–475
25. Bustamante Mamani J, Fernel Gamarra L, Espósito de Souza Brito G (2014) Synthesis and
characterization of Fe 3 O 4 nanoparticles with perspectives in biomedical applications. Mat Res
17(3):542–549
26. Herojitsingh L, Govindaraja R, Amarendra G et al (2013) Local structure and magnetic
properties of cubic iron oxide nanoparticles formed in zeolite as deduced using Mössbauer
spectroscopy. Appl Phys Lett 103:193104
27. Johnson CE, Johnson JA, Hah HY et al (2016) Mössbauer studies of stoichiometry of Fe 3 O 4 :
characterization of nanoparticles for biomedical applications. Hyperfine Interact 237:27
28. Ahn T, Kim JH, Yang H-M et al (2012) Formation pathways of magnetite nanoparticles by
coprecipitation method. J Phys Chem C 116(10):6069–6076
29. Guyodo Y, Bonville P, Till JL et al (2016) Constraining the origins of the magnetism of
lepidocrocite (γ-FeOOH): a Mössbauer and magnetization study. Front Earth Sci 4:28
30. Lozano I, Casillas N, Ponce de León C et al (2017) New insights into the electrochemical
formation of magnetite nanoparticles. J Electrochem Soc 164(4):D184–D191
31. Hurtado L, Romero R, Mendoza A, Brewer S, Donkor K, Gómez-Espinosa RM, Natividad R
(2019) Paracetamol mineralization by Photo Fenton process catalyzed by a Cu/Fe-PILC under
circumneutral pH conditions. J Photochem Photobiol A Chem. 373:162–170
32. Undabeytia T, Galán-Jiménez MC, Gómez-Pantoja E et al (2013) Fe-pillared clay mineralbased formulations of imazaquin for reduced leaching in soil. Appl Clay Sci 80-81:382–389
33. SanJuan-Reyes N, Gomez-Olivan LM, Galar-Martinez M et al (2015) NSAID-manufacturing
plant effluent induces geno- and cytotoxicity in common carp (Cyprinus carpio). Sci Total
Environ 530-531C:1–10
34. Chen Q, Wu P, Dang Z et al (2010) Iron pillared vermiculite as a heterogeneous photo-Fenton
catalyst for photocatalytic degradation of azo dye reactive brilliant orange X-GN. Sep Purif
Technol 71:315–323
35. Michael I, Hapeshi E, Michael C et al (2012) Solar photo-Fenton process on the abatement of
antibiotics at a pilot scale: degradation kinetics, ecotoxicity and phytotoxicity assessment and
removal of antibiotic resistant enterococci. Water Res 46:5621–5634
36. Melero JA, Martinez F, Botas JA et al (2009) Heterogeneous catalytic wet peroxide oxidation
systems for the treatment of an industrial pharmaceutical wastewater. Water Res 43:4010–4018
37. Sun J, Feng J, Shi S et al (2012) Degradation of the antibiotic sulfamonomethoxine sodium in
aqueous solution by photo-Fenton oxidation. Chin Sci Bull 57:558–564
38. Ji F, Li C, Zhang J et al (2011) Heterogeneous photo-Fenton decolorization of methylene blue
over LiFe(WO 4 ) 2 catalyst. J Hazard Mater 186:1979–1984
39. Pariente M, Martinez F, Melero J et al (2008) Heterogeneous photo-Fenton oxidation of benzoic
acid in water: effect of operating conditions, reaction by-products and coupling with biological
treatment. Appl Catal B-Environ 85:24–32
40. Ayodele OB, Lim JK, Hameed BH (2012) Pillared montmorillonite supported ferric oxalate as
heterogeneous photo-Fenton catalyst for degradation of amoxicillin. Appl Catal A-Gen
413-414:301–309
41. Herney-Ramirez J, Vicente MA, Madeira LM (2010) Heterogeneous photo-Fenton oxidation
with pillared clay-based catalysts for wastewater treatment: a review. Appl Catal B-Environ
98:10–26
42. De León MA, Castiglioni J, Bussi J et al (2008) Catalytic activity of an iron-pillared montmorillonitic clay mineral in heterogeneous photo-Fenton process. Catal Today 133–135:600–605
258
R. Natividad et al.