Cyclodextrins-Based Shape Memory
Polymers and Self-Healing Polymers
22
Sheng Zhang, Shi-Lin Zeng, and Bang-Jing Li
Contents
22.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 587
22.2 SMPs Based on CDs-Guest Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 588
22.2.1 General Aspect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 588
22.2.2 SMPs Based on CDs-Polymer Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 589
22.2.3 SMPs Based on CDs-Guest Group Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 590
22.3 SHPs Based on CDs-Guest Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 592
22.3.1 General Aspect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 592
22.3.2 Self-Healing Hydrogels Based on CD-Guest Interactions . . . . . . . . . . . . . . . . . . . . 592
22.3.3 Self-Healing Composites Based on CD-Guest Interactions . . . . . . . . . . . . . . . . . . . 594
22.4 SMPs and SHPs Based on CD-Guest Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 596
22.5 Prospect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 598
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 598
22.1 Introduction
Natural materials exhibit the ordered structures assembled biomolecules by supramolecular interactions, and perform various biological functions. Inspired by nature,
smart and functional materials based on supramolecular chemistry have attracted
considerable attention [1–3]. Shape memory polymers (SMPs) and self-healing
polymers (SHPs) are two representative examples of biomimetic smart materials.
The former can change from one or more temporary shapes to a predetermined shape
in response to an external stimulus [4]; the latter are able to repair cracks or fracture
by themselves spontaneously or in response to external stimuli, such as humidity,
S. Zhang (*) · S.-L. Zeng
Sichuan University, Chengdu, China
e-mail: zslbj@163.com; 1578284978@qq.com
B.-J. Li
Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
e-mail: libj@cib.ac.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_24
587
Polymers and Self-Healing Polymers
22
Sheng Zhang, Shi-Lin Zeng, and Bang-Jing Li
Contents
22.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 587
22.2 SMPs Based on CDs-Guest Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 588
22.2.1 General Aspect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 588
22.2.2 SMPs Based on CDs-Polymer Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 589
22.2.3 SMPs Based on CDs-Guest Group Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 590
22.3 SHPs Based on CDs-Guest Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 592
22.3.1 General Aspect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 592
22.3.2 Self-Healing Hydrogels Based on CD-Guest Interactions . . . . . . . . . . . . . . . . . . . . 592
22.3.3 Self-Healing Composites Based on CD-Guest Interactions . . . . . . . . . . . . . . . . . . . 594
22.4 SMPs and SHPs Based on CD-Guest Interactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 596
22.5 Prospect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 598
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 598
22.1 Introduction
Natural materials exhibit the ordered structures assembled biomolecules by supramolecular interactions, and perform various biological functions. Inspired by nature,
smart and functional materials based on supramolecular chemistry have attracted
considerable attention [1–3]. Shape memory polymers (SMPs) and self-healing
polymers (SHPs) are two representative examples of biomimetic smart materials.
The former can change from one or more temporary shapes to a predetermined shape
in response to an external stimulus [4]; the latter are able to repair cracks or fracture
by themselves spontaneously or in response to external stimuli, such as humidity,
S. Zhang (*) · S.-L. Zeng
Sichuan University, Chengdu, China
e-mail: zslbj@163.com; 1578284978@qq.com
B.-J. Li
Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
e-mail: libj@cib.ac.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_24
587