γ-cyclodextrin and cucurbit[8]uril: a dramatic steric effect operating outside the binding site. J
Am Chem Soc 130(27):8574–8575
45. Yang C, Ke C, Liang W, Fukuhara G, Mori T, Liu Y, Inoue Y (2011) Dual supramolecular
photochirogenesis: ultimate stereocontrol of photocyclodimerization by a chiral scaffold and
confining host. J Am Chem Soc 133(35):13786–13789
46. Luo L, Cheng SF, Chen B, Tung CH, Wu LZ (2010) Stepwise photochemical chiral delivery in
γ-cyclodextrin-directed enantioselective photocyclodimerization of methyl 3-methoxyl-2naphthoate in aqueous solution. Langmuir 26(2):782–785
47. Liang W, Zhang HH, Wang JJ, Peng Y, Chen B, Yang C, Tung CH, Wu LZ, Fukuhara G,
Mori T, Inoue Y (2011) Supramolecular complexation and photocyclodimerization of methyl
3-methoxy-2-naphthoate with modified cyclodextrins. Pure Appl Chem 83(4):769–778
48. Luo L, Liao G, Wu X, Lei L, Tung C, Wu L (2009) γ-Cyclodextrin-directed enantioselective
photocyclodimerization of methyl 3-methoxyl-2-naphthoate. J Org Chem 74(9):3506–3515
49. Fukuhara G, Umehara H, Higashino S, Nishijima M, Yang C, Mori T, Wada T, Inoue Y (2014)
Supramolecular photocyclodimerization of 2-hydroxyanthracene with a chiral hydrogenbonding template, cyclodextrin and serum albumin. Photochem Photobiol Sci 13(2):162–171
50. Inoue Y, Kosaka S, Matsumoto K, Tsuneishi H, Hakushi T, Tai A, Nakagawa K, Tong L (1993)
Vacuum UV photochemistry in cyclodextrin cavities. Solid-state Z-E photoisomerization of a
cyclooctene-β-cyclodextrin inclusion complex. J Photochem Photobiol A Chem 71(1):61–64
51. Inoue Y, Dong F, Yamamoto Y, Tong L-H, Tsuneishi H, Hakushi T, Tai A (1995) Inclusionenhanced optical yield and E/Z ratio in enantiodifferentiating photoisomerization of cyclooctene
included and sensitized by β-cyclodextrin monobenzoate. J Am Chem Soc
117(44):11033–11034
52. Inoue Y, Wada T, Sugahara N, Yamamoto K, Kimura K, Tong LH, Gao XM, Hou ZJ, Liu Y
(2000) Supramolecular photochirogenesis. 2. Enantiodifferentiating photoisomerization of
cyclooctene included and sensitized by 6-O-modified cyclodextrins. J Org Chem
65(23):8041–8050
53. Fukuhara G, Mori T, Wada T, Inoue Y (2006) Entropy-controlled supramolecular photochirogenesis: enantiodifferentiating Z-E photoisomerization of cyclooctene included and sensitized by permethylated 6-O-modified β-cyclodextrins. J Org Chem 71(21):8233–8243
54. Lu R, Yang C, Cao Y, Wang Z, Wada T, Jiao W, Mori T, Inoue Y (2008) Supramolecular
enantiodifferentiating photoisomerization of cyclooctene with modified β-cyclodextrins: critical
control by a host structure. Chem Commun (3):374–376
55. Fukuhara G, Mori T, Wada T, Inoue Y (2005) Entropy-controlled supramolecular photochirogenesis: enantiodifferentiating Z-E photoisomerization of cyclooctene included and sensitized by permethylated 6-O-benzoyl-β-cyclodextrin. Chem Commun (33):4199–4201
56. Lu R, Yang C, Cao Y, Wang Z, Wada T, Jiao W, Mori T, Inoue Y (2008) Enantiodifferentiating
photoisomerization of cyclooctene included and sensitized by aroyl-β-cyclodextrins: a critical
enantioselectivity control by substituents. J Org Chem 73(19):7695–7701
57. Gao Y, Wada T, Yang K, Kim K, Inoue Y (2005) Supramolecular photochirogenesis in
sensitizing chiral nanopore: enantiodifferentiating photoisomerization of (Z )-cyclooctene
included and sensitized by POST-1. Chirality 17(S1):S19–S23
58. Gao Y, Inoue M, Wada T, Inoue Y (2004) Supramolecular photochirogenesis. 3. Enantiodifferentiating photoisomerization of cyclooctene included and sensitized by 6-O-mono(omethoxybenzoyl)cyclodextrin. J Incl Phenom Macrocycl Chem 50(1):111–114
59. Inoue Y, Yokoyama T, Yamasaki N, Tai A (1989) Temperature switching of product chirality
upon photosensitized enantiodifferentiating cis-trans isomerization of cyclooctene. J Am Chem
Soc 111(16):6480–6482
60. Inoue Y, Yamasaki N, Yokoyama T, Tai A (1993) Highly enantiodifferentiating photoisomerization of cyclooctene by congested and/or triplex-forming chiral sensitizers. J Org
Chem 58(5):1011–1018
534
J. Yao et al.
Am Chem Soc 130(27):8574–8575
45. Yang C, Ke C, Liang W, Fukuhara G, Mori T, Liu Y, Inoue Y (2011) Dual supramolecular
photochirogenesis: ultimate stereocontrol of photocyclodimerization by a chiral scaffold and
confining host. J Am Chem Soc 133(35):13786–13789
46. Luo L, Cheng SF, Chen B, Tung CH, Wu LZ (2010) Stepwise photochemical chiral delivery in
γ-cyclodextrin-directed enantioselective photocyclodimerization of methyl 3-methoxyl-2naphthoate in aqueous solution. Langmuir 26(2):782–785
47. Liang W, Zhang HH, Wang JJ, Peng Y, Chen B, Yang C, Tung CH, Wu LZ, Fukuhara G,
Mori T, Inoue Y (2011) Supramolecular complexation and photocyclodimerization of methyl
3-methoxy-2-naphthoate with modified cyclodextrins. Pure Appl Chem 83(4):769–778
48. Luo L, Liao G, Wu X, Lei L, Tung C, Wu L (2009) γ-Cyclodextrin-directed enantioselective
photocyclodimerization of methyl 3-methoxyl-2-naphthoate. J Org Chem 74(9):3506–3515
49. Fukuhara G, Umehara H, Higashino S, Nishijima M, Yang C, Mori T, Wada T, Inoue Y (2014)
Supramolecular photocyclodimerization of 2-hydroxyanthracene with a chiral hydrogenbonding template, cyclodextrin and serum albumin. Photochem Photobiol Sci 13(2):162–171
50. Inoue Y, Kosaka S, Matsumoto K, Tsuneishi H, Hakushi T, Tai A, Nakagawa K, Tong L (1993)
Vacuum UV photochemistry in cyclodextrin cavities. Solid-state Z-E photoisomerization of a
cyclooctene-β-cyclodextrin inclusion complex. J Photochem Photobiol A Chem 71(1):61–64
51. Inoue Y, Dong F, Yamamoto Y, Tong L-H, Tsuneishi H, Hakushi T, Tai A (1995) Inclusionenhanced optical yield and E/Z ratio in enantiodifferentiating photoisomerization of cyclooctene
included and sensitized by β-cyclodextrin monobenzoate. J Am Chem Soc
117(44):11033–11034
52. Inoue Y, Wada T, Sugahara N, Yamamoto K, Kimura K, Tong LH, Gao XM, Hou ZJ, Liu Y
(2000) Supramolecular photochirogenesis. 2. Enantiodifferentiating photoisomerization of
cyclooctene included and sensitized by 6-O-modified cyclodextrins. J Org Chem
65(23):8041–8050
53. Fukuhara G, Mori T, Wada T, Inoue Y (2006) Entropy-controlled supramolecular photochirogenesis: enantiodifferentiating Z-E photoisomerization of cyclooctene included and sensitized by permethylated 6-O-modified β-cyclodextrins. J Org Chem 71(21):8233–8243
54. Lu R, Yang C, Cao Y, Wang Z, Wada T, Jiao W, Mori T, Inoue Y (2008) Supramolecular
enantiodifferentiating photoisomerization of cyclooctene with modified β-cyclodextrins: critical
control by a host structure. Chem Commun (3):374–376
55. Fukuhara G, Mori T, Wada T, Inoue Y (2005) Entropy-controlled supramolecular photochirogenesis: enantiodifferentiating Z-E photoisomerization of cyclooctene included and sensitized by permethylated 6-O-benzoyl-β-cyclodextrin. Chem Commun (33):4199–4201
56. Lu R, Yang C, Cao Y, Wang Z, Wada T, Jiao W, Mori T, Inoue Y (2008) Enantiodifferentiating
photoisomerization of cyclooctene included and sensitized by aroyl-β-cyclodextrins: a critical
enantioselectivity control by substituents. J Org Chem 73(19):7695–7701
57. Gao Y, Wada T, Yang K, Kim K, Inoue Y (2005) Supramolecular photochirogenesis in
sensitizing chiral nanopore: enantiodifferentiating photoisomerization of (Z )-cyclooctene
included and sensitized by POST-1. Chirality 17(S1):S19–S23
58. Gao Y, Inoue M, Wada T, Inoue Y (2004) Supramolecular photochirogenesis. 3. Enantiodifferentiating photoisomerization of cyclooctene included and sensitized by 6-O-mono(omethoxybenzoyl)cyclodextrin. J Incl Phenom Macrocycl Chem 50(1):111–114
59. Inoue Y, Yokoyama T, Yamasaki N, Tai A (1989) Temperature switching of product chirality
upon photosensitized enantiodifferentiating cis-trans isomerization of cyclooctene. J Am Chem
Soc 111(16):6480–6482
60. Inoue Y, Yamasaki N, Yokoyama T, Tai A (1993) Highly enantiodifferentiating photoisomerization of cyclooctene by congested and/or triplex-forming chiral sensitizers. J Org
Chem 58(5):1011–1018
534
J. Yao et al.