Photoresponsive Supramolecular Polymers
Based on Host-Guest Interactions
16
Fan Gu and Xiang Ma
Contents
16.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 452
16.2 Photoresponsive Supramolecular Polymers Based on Cyclodextrin (CDs) . . . . . . . . . . . . 453
16.2.1 CD-Based Polymer Networks and Hydrogels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
16.2.2 CD-Based Polymer Self-Assemblies and Vesicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . 458
16.3 Photoresponsive Supramolecular Polymers Based on Cucurbituril (CBs) . . . . . . . . . . . . . 459
16.3.1 Adjustable Dynamic Photophysical Properties Based on CB . . . . . . . . . . . . . . . . . 460
16.3.2 Supramolecular Polymer with Photoisomerism Based on CB . . . . . . . . . . . . . . . . 460
16.3.3 Controllable Supramolecular Polymerization Based on CB . . . . . . . . . . . . . . . . . . 463
16.4 Photoresponsive Supramolecular Polymers Based on Crown Ether . . . . . . . . . . . . . . . . . . . . 464
16.4.1 Networks and Hydrogels of Supramolecular Polymer Based on
Crown Ether . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 465
16.4.2 Conjugated Polymer Network and Its Disassembly Induced by Different
Signals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 466
16.5 Photoresponsive Supramolecular Polymers Based on Calixarene . . . . . . . . . . . . . . . . . . . . . . 467
16.5.1 Supramolecular Polymer with Photoisomerism Based on Calixarene . . . . . . . . 468
16.5.2 Networks and Self-Assemblies of Supramolecular Polymer Based on
Calixarene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 468
16.6 Photoresponsive Supramolecular Polymers Based on Pillararene . . . . . . . . . . . . . . . . . . . . . . 470
16.6.1 Cross-Linked Polymer Networks Based on Pillararene . . . . . . . . . . . . . . . . . . . . . . . 470
16.6.2 Supramolecular Polymer with Photoisomerism Based on Pillararene . . . . . . . . 471
16.6.3 Supramolecular Polymer with Two Guest Monomers Based
on Pillararene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 475
16.7 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 479
16.8 Cross-References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 480
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 480
F. Gu · X. Ma (*)
Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center,
Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China
University of Science and Technology, Shanghai, China
e-mail: 2939179949@qq.com; maxiang@ecust.edu.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_18
451
Based on Host-Guest Interactions
16
Fan Gu and Xiang Ma
Contents
16.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 452
16.2 Photoresponsive Supramolecular Polymers Based on Cyclodextrin (CDs) . . . . . . . . . . . . 453
16.2.1 CD-Based Polymer Networks and Hydrogels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
16.2.2 CD-Based Polymer Self-Assemblies and Vesicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . 458
16.3 Photoresponsive Supramolecular Polymers Based on Cucurbituril (CBs) . . . . . . . . . . . . . 459
16.3.1 Adjustable Dynamic Photophysical Properties Based on CB . . . . . . . . . . . . . . . . . 460
16.3.2 Supramolecular Polymer with Photoisomerism Based on CB . . . . . . . . . . . . . . . . 460
16.3.3 Controllable Supramolecular Polymerization Based on CB . . . . . . . . . . . . . . . . . . 463
16.4 Photoresponsive Supramolecular Polymers Based on Crown Ether . . . . . . . . . . . . . . . . . . . . 464
16.4.1 Networks and Hydrogels of Supramolecular Polymer Based on
Crown Ether . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 465
16.4.2 Conjugated Polymer Network and Its Disassembly Induced by Different
Signals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 466
16.5 Photoresponsive Supramolecular Polymers Based on Calixarene . . . . . . . . . . . . . . . . . . . . . . 467
16.5.1 Supramolecular Polymer with Photoisomerism Based on Calixarene . . . . . . . . 468
16.5.2 Networks and Self-Assemblies of Supramolecular Polymer Based on
Calixarene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 468
16.6 Photoresponsive Supramolecular Polymers Based on Pillararene . . . . . . . . . . . . . . . . . . . . . . 470
16.6.1 Cross-Linked Polymer Networks Based on Pillararene . . . . . . . . . . . . . . . . . . . . . . . 470
16.6.2 Supramolecular Polymer with Photoisomerism Based on Pillararene . . . . . . . . 471
16.6.3 Supramolecular Polymer with Two Guest Monomers Based
on Pillararene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 475
16.7 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 479
16.8 Cross-References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 480
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 480
F. Gu · X. Ma (*)
Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center,
Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China
University of Science and Technology, Shanghai, China
e-mail: 2939179949@qq.com; maxiang@ecust.edu.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_18
451