Photoluminescent Crown Ether Assembly
5
Yan Zhou, Bang-Tun Zhao, and Yu Liu
Contents
5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
5.2 Luminescent Assemblies Based on Organic Dyes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108
5.3 Crown Ether Assembly Based on Lanthanide Metal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
5.3.1 A Highly Selective Luminescent Sensor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
5.3.2 Luminescent Lanthanide Assemblies Based on Pseudorotaxanes/
Pseudopolyrotaxanes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118
5.4 Luminescent Supramolecular Polymers Based on Crown Ether . . . . . . . . . . . . . . . . . . . . . . . . . 123
5.5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
5.1
Introduction
Crown ether, as cyclic compound composed of several repeating ether units, is
discovered by the winner of the Nobel Prize Pedersen in 1967 [1]. Subsequently,
the concepts of supramolecular chemistry and host-guest chemistry were put
Y. Zhou
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented
Porous Materials, Luoyang Normal University, Luoyang, China
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
B.-T. Zhao
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented
Porous Materials, Luoyang Normal University, Luoyang, China
Y. Liu (*)
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, China
e-mail: yuliu@nankai.edu.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_6
107
5
Yan Zhou, Bang-Tun Zhao, and Yu Liu
Contents
5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
5.2 Luminescent Assemblies Based on Organic Dyes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108
5.3 Crown Ether Assembly Based on Lanthanide Metal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
5.3.1 A Highly Selective Luminescent Sensor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
5.3.2 Luminescent Lanthanide Assemblies Based on Pseudorotaxanes/
Pseudopolyrotaxanes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118
5.4 Luminescent Supramolecular Polymers Based on Crown Ether . . . . . . . . . . . . . . . . . . . . . . . . . 123
5.5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
5.1
Introduction
Crown ether, as cyclic compound composed of several repeating ether units, is
discovered by the winner of the Nobel Prize Pedersen in 1967 [1]. Subsequently,
the concepts of supramolecular chemistry and host-guest chemistry were put
Y. Zhou
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented
Porous Materials, Luoyang Normal University, Luoyang, China
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
B.-T. Zhao
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented
Porous Materials, Luoyang Normal University, Luoyang, China
Y. Liu (*)
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, China
e-mail: yuliu@nankai.edu.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_6
107