23
Infrastructures,” funded by the Operational Program
“Competitiveness, Entrepreneurship and Innovation” (NSRF
2014–2020) and co-financed by Greece and the European Union
(European Regional Development Fund), is acknowledged.
References
1. Karousis I, Martinez IS, Ewels CP,
Tagmatarchis N (2016) Structure, properties,
functionalization, and applications of carbon
nanohorns. Chem Rev 116:4850–4883
2. Kostarelos K (2008) The long and short of
carbon nanotube toxicity. Nat Biotechnol
26:774–776
3. Tagmatarchis N, Maigne A, Yudasaka M,
Iijima S (2006) Functionalization of carbon
nanohorns with azomethine ylides: towards
solubility enhancement and electron-transfer
processes. Small 2:490–494
4. Cioffi C, Campidelli S, Brunetti FG, Meneghetti
M, Prato M (2006) Functionalisation of carbon
nanohorns. Chem Commun 20:2129–2131
5. Pagona G, Karousis N, Tagmatarchis N (2008)
Aryl diazonium functionalization of carbon
nanohorns. Carbon 46:604–610
6. Nakamura E, Koshino M, Tanaka T, Niimi Y,
Harano K, Nakamura Y et al (2018) Imaging
of conformational changes of biotinylated
triamide molecules covalently bonded to a
carbon nanotube surface. J Am Chem Soc
130:7808–7809
7. Lacotte S, Garcia A, Decossas M, Al-Jamal
WT, Li S, Kostarelos K et al (2008) Interfacing
functionalized carbon nanohorns with primary
phagocytic cells. Adv Mater 20:2421–2426
8. Economopoulos SP, Pagona G, Yudasaka M,
Iijima S, Tagmatarchis N (2009) Solvent-free
microwave-assisted Bingel reaction in carbon
nanohorns. J Mater Chem 19:7326–7331
9. Karousis N, Ichihashi T, Yudasaka M, Iijima
S, Tagmatarchis N (2011) Microwave-assisted
functionalization of carbon nanohorns via
[2+1] nitrenes cycloaddition. Chem Commun
47:1604–1606
10. Pagona G, Katerinopoulos HE, Tagmatarchis
N (2011) Synthesis, characterization, and photophysical properties of a carbon nanohorncoumarin hybrid material. Chem Phys Lett
516:76–81
11. Vizuete M, Gomez-Escalonilla MJ, Fierro
JLG, Yudasaka M, Iijima S, Vartanian M et al
(2011) A soluble hybrid material combining
carbon nanohorns and C 60 . Chem Commun
47:12771–12773
12. Karousis N, Sato Y, Suenaga K, Tagmatarchis
N (2012) Direct evidence for covalent functionalization of carbon nanohorns by highresolution electron microscopy imaging of
C 60 conjugated onto their skeleton. Carbon
50:3909–3914
13. Pagona G, Zervaki GE, Sandanayaka AD, Ito
O, Charalambidis G, Hasobe T et al (2012)
Carbon nanohorn-porphyrin dimer hybrid
material for enhancing light-energy conversion. J Phys Chem C 116:9439–9449
14. Chronopoulos D, Karousis N, Ichihashi T,
Yudasaka M, Iijima S, Tagmatarchis N (2013)
Benzyne cycloaddition onto carbon nanohorns. Nanoscale 5:6388–6394
15. Miyako E, Russier J, Mauro M, Cebrian C,
Yawo H, Menard-Moyon C et al (2014)
Photofunctional nanomodulators for bioexcitation. Angew Chem Int Ed 53:13121–13125
16. Chronopoulos DD, Liu Z, Suenaga K, Yudasaka
M, Tagmatarchis N (2016) [3 + 2] cycloaddition reaction of azomethine ylides generated
by thermal ring opening of aziridines onto carbon nanohorns. RSC Adv 6:44782–44787
17. Pagona G, Sandanayaka ASD, Maigne A, Fan
J, Papavassiliou GC, Petsalakis ID et al (2007)
Photoinduced electron transfer on aqueous
carbon
nanohorn–pyrene–tetrathiafulvalene
architectures. Chem Eur J 13:7600–7607
18. Vizuete M, Gomez-Escalonilla MJ, Fierro
JLG, Sandanayaka ASD, Hasobe T, Yudasaka
M et al (2010) A carbon nanohorn porphyrin supramolecular assembly for photoinduced electron-transfer processes. Chem Eur J
16:10752–107563
19. Jiang BP, Shen LFXC, Ji SC, Shi Z, Liu CJ,
Zhang L et al (2014) One-step preparation
of a water-soluble carbon nanohorn/phthalocyanine hybrid for dual-modality photothermal
and photodynamic therapy. ACS Appl Mater
Interfaces 6:18008–18017
20. Pagona G, Sandanayaka ASD, Araki Y, Fan
J, Tagmatarchis N, Yudasaka M et al (2006)
Electronic interplay on illuminated aqueous
carbon nanohorn-porphyrin ensembles. J Phys
Chem B 110:20729–20732
21. Pagona G, Fan J, Maigne A, Yudasaka M,
Iijima S, Tagmatarchis N (2007) Aqueous carbon nanohorn-pyrene-porphyrin nanoensembles: controlling charge-transfer interactions.
Diam Relat Mater 16:1150–1153
Functionalized Carbon Nanohorns
Infrastructures,” funded by the Operational Program
“Competitiveness, Entrepreneurship and Innovation” (NSRF
2014–2020) and co-financed by Greece and the European Union
(European Regional Development Fund), is acknowledged.
References
1. Karousis I, Martinez IS, Ewels CP,
Tagmatarchis N (2016) Structure, properties,
functionalization, and applications of carbon
nanohorns. Chem Rev 116:4850–4883
2. Kostarelos K (2008) The long and short of
carbon nanotube toxicity. Nat Biotechnol
26:774–776
3. Tagmatarchis N, Maigne A, Yudasaka M,
Iijima S (2006) Functionalization of carbon
nanohorns with azomethine ylides: towards
solubility enhancement and electron-transfer
processes. Small 2:490–494
4. Cioffi C, Campidelli S, Brunetti FG, Meneghetti
M, Prato M (2006) Functionalisation of carbon
nanohorns. Chem Commun 20:2129–2131
5. Pagona G, Karousis N, Tagmatarchis N (2008)
Aryl diazonium functionalization of carbon
nanohorns. Carbon 46:604–610
6. Nakamura E, Koshino M, Tanaka T, Niimi Y,
Harano K, Nakamura Y et al (2018) Imaging
of conformational changes of biotinylated
triamide molecules covalently bonded to a
carbon nanotube surface. J Am Chem Soc
130:7808–7809
7. Lacotte S, Garcia A, Decossas M, Al-Jamal
WT, Li S, Kostarelos K et al (2008) Interfacing
functionalized carbon nanohorns with primary
phagocytic cells. Adv Mater 20:2421–2426
8. Economopoulos SP, Pagona G, Yudasaka M,
Iijima S, Tagmatarchis N (2009) Solvent-free
microwave-assisted Bingel reaction in carbon
nanohorns. J Mater Chem 19:7326–7331
9. Karousis N, Ichihashi T, Yudasaka M, Iijima
S, Tagmatarchis N (2011) Microwave-assisted
functionalization of carbon nanohorns via
[2+1] nitrenes cycloaddition. Chem Commun
47:1604–1606
10. Pagona G, Katerinopoulos HE, Tagmatarchis
N (2011) Synthesis, characterization, and photophysical properties of a carbon nanohorncoumarin hybrid material. Chem Phys Lett
516:76–81
11. Vizuete M, Gomez-Escalonilla MJ, Fierro
JLG, Yudasaka M, Iijima S, Vartanian M et al
(2011) A soluble hybrid material combining
carbon nanohorns and C 60 . Chem Commun
47:12771–12773
12. Karousis N, Sato Y, Suenaga K, Tagmatarchis
N (2012) Direct evidence for covalent functionalization of carbon nanohorns by highresolution electron microscopy imaging of
C 60 conjugated onto their skeleton. Carbon
50:3909–3914
13. Pagona G, Zervaki GE, Sandanayaka AD, Ito
O, Charalambidis G, Hasobe T et al (2012)
Carbon nanohorn-porphyrin dimer hybrid
material for enhancing light-energy conversion. J Phys Chem C 116:9439–9449
14. Chronopoulos D, Karousis N, Ichihashi T,
Yudasaka M, Iijima S, Tagmatarchis N (2013)
Benzyne cycloaddition onto carbon nanohorns. Nanoscale 5:6388–6394
15. Miyako E, Russier J, Mauro M, Cebrian C,
Yawo H, Menard-Moyon C et al (2014)
Photofunctional nanomodulators for bioexcitation. Angew Chem Int Ed 53:13121–13125
16. Chronopoulos DD, Liu Z, Suenaga K, Yudasaka
M, Tagmatarchis N (2016) [3 + 2] cycloaddition reaction of azomethine ylides generated
by thermal ring opening of aziridines onto carbon nanohorns. RSC Adv 6:44782–44787
17. Pagona G, Sandanayaka ASD, Maigne A, Fan
J, Papavassiliou GC, Petsalakis ID et al (2007)
Photoinduced electron transfer on aqueous
carbon
nanohorn–pyrene–tetrathiafulvalene
architectures. Chem Eur J 13:7600–7607
18. Vizuete M, Gomez-Escalonilla MJ, Fierro
JLG, Sandanayaka ASD, Hasobe T, Yudasaka
M et al (2010) A carbon nanohorn porphyrin supramolecular assembly for photoinduced electron-transfer processes. Chem Eur J
16:10752–107563
19. Jiang BP, Shen LFXC, Ji SC, Shi Z, Liu CJ,
Zhang L et al (2014) One-step preparation
of a water-soluble carbon nanohorn/phthalocyanine hybrid for dual-modality photothermal
and photodynamic therapy. ACS Appl Mater
Interfaces 6:18008–18017
20. Pagona G, Sandanayaka ASD, Araki Y, Fan
J, Tagmatarchis N, Yudasaka M et al (2006)
Electronic interplay on illuminated aqueous
carbon nanohorn-porphyrin ensembles. J Phys
Chem B 110:20729–20732
21. Pagona G, Fan J, Maigne A, Yudasaka M,
Iijima S, Tagmatarchis N (2007) Aqueous carbon nanohorn-pyrene-porphyrin nanoensembles: controlling charge-transfer interactions.
Diam Relat Mater 16:1150–1153
Functionalized Carbon Nanohorns