452
Index
K
KA 2 (ketone-alkyne-amine) coupling, 266
Kinetic Isotope Effect (KIE), 282, 283
Knight shift, 408
Knoevenagel condensation, 253, 255
Kumada–Tamao–Corriu reaction, 261
L
Langmuir–Blodgett method (LB), 130, 146
Layer-by-layer method (LBL), 130, 132,
133, 144, 175–177, 182
Lewis-acid, 348, 349
Lewis acid base-adduct, 272
Lewis acid-catalyzed coupling reactions,
252
Ligand-free, 111
Ligand-free clusters, 1, 5, 9–12, 15, 17, 18,
23, 33
Ligand-free NPs, 107, 111
Light-induced reversible self-assembly, 172
Light-induced self-assembly, 164, 165
L-lysine, 294, 296, 297
M
Magnetite (Fe 3 O 4 ), 359, 441
Magnetron sputtering, 107, 116, 118
Mass spectrometry, 7, 9, 21, 26
MCM-41, 389, 390
Mechanistic insights, 272
Mechanistic selectivity, 306, 314, 315
Mechanistic studies, 299
Mechanistic vs. thermodynamic, 306
MeCpPtMe 3 , 73, 75, 80
Metal clusters, 304, 305, 308, 309, 331, 334
Metal nanoparticles, 221–233, 236–244
Metal–Organic Frameworks (MOFs), 221,
223–239, 241–244, 364, 370–372,
394
Methanol electrooxidation, 144
Methylene blue, 176–179
Methyl propiolate, 317
MgO, 415, 416
Michael addition, 255
Microwave irradiation, 257, 268
MIL-100, 224–226, 229
MIL-101, 225–228, 230–234, 236, 237, 240,
242
Molecular catalysts, 281, 286, 293
Molecular layer deposition, 90
Molten salts, 107
Monometallacycle, 293
Montmorillonite, 256, 258
Morphology effect, 41, 58, 64
Multicomponent reactions, 252, 253, 266,
267
Multi-Walled
Carbon
Nanotubes
(MWCNT), 321, 329, 356, 375–379,
383, 388, 439
N
Nabumetone, 390, 392
Nanocluster, 39–51, 53–59, 61–64
N-aryl amines, 265
(n-C 4 H 9 ) 3 SnH, 421
NH, 297
N-Heterocyclic Carbene (NHC), 290, 294,
296, 297, 312, 409, 414, 427–431,
436–438, 441, 442
Ni, 290, 299, 392, 395, 396
Ni(acac) 2 , 76
Ni ALD, 76
Ni(Cp) 2 , 76, 87, 89, 93
Ni NPs, 272, 415
Nitrides, 310, 314, 315
Nitrobenzene reduction, 179
Non-bonding interactions, 373
O
Olefin hydrogenation, 31
Olefin metathesis, 429, 436
Oleylamine, 367, 368, 379, 396, 409
Oligomerization, 304, 305, 331
1,10-bis(diphenylphosphino)decane (dppd),
420
1,3-butadiene, 73, 78, 79, 85, 87
1,3-dicyclohexylimidazolium-2-di-ptolylcarbodiimide (ICy.(p-tol)NCN),
414
1-n-butyl-3-methylimidazolium, 114, 119,
120
1-octylamine, 410, 412
1,3-propanediol, 257
1,3,5-triaza-7-phosphaadamantane (PTA),
424, 425
Over-hydrogenation, 304, 306, 308, 310,
311, 313, 316–318, 321, 324, 325,
329, 331, 332
Oxidation, 408, 410, 430, 431, 436, 438
Oxidation of alcohols, 202
Oxidation of amines, 202
Oxidative addition, 286, 293
Oxide overcoating, 89
Oxygen evolution reaction, 40, 46, 48–50,
64
Index
K
KA 2 (ketone-alkyne-amine) coupling, 266
Kinetic Isotope Effect (KIE), 282, 283
Knight shift, 408
Knoevenagel condensation, 253, 255
Kumada–Tamao–Corriu reaction, 261
L
Langmuir–Blodgett method (LB), 130, 146
Layer-by-layer method (LBL), 130, 132,
133, 144, 175–177, 182
Lewis-acid, 348, 349
Lewis acid base-adduct, 272
Lewis acid-catalyzed coupling reactions,
252
Ligand-free, 111
Ligand-free clusters, 1, 5, 9–12, 15, 17, 18,
23, 33
Ligand-free NPs, 107, 111
Light-induced reversible self-assembly, 172
Light-induced self-assembly, 164, 165
L-lysine, 294, 296, 297
M
Magnetite (Fe 3 O 4 ), 359, 441
Magnetron sputtering, 107, 116, 118
Mass spectrometry, 7, 9, 21, 26
MCM-41, 389, 390
Mechanistic insights, 272
Mechanistic selectivity, 306, 314, 315
Mechanistic studies, 299
Mechanistic vs. thermodynamic, 306
MeCpPtMe 3 , 73, 75, 80
Metal clusters, 304, 305, 308, 309, 331, 334
Metal nanoparticles, 221–233, 236–244
Metal–Organic Frameworks (MOFs), 221,
223–239, 241–244, 364, 370–372,
394
Methanol electrooxidation, 144
Methylene blue, 176–179
Methyl propiolate, 317
MgO, 415, 416
Michael addition, 255
Microwave irradiation, 257, 268
MIL-100, 224–226, 229
MIL-101, 225–228, 230–234, 236, 237, 240,
242
Molecular catalysts, 281, 286, 293
Molecular layer deposition, 90
Molten salts, 107
Monometallacycle, 293
Montmorillonite, 256, 258
Morphology effect, 41, 58, 64
Multicomponent reactions, 252, 253, 266,
267
Multi-Walled
Carbon
Nanotubes
(MWCNT), 321, 329, 356, 375–379,
383, 388, 439
N
Nabumetone, 390, 392
Nanocluster, 39–51, 53–59, 61–64
N-aryl amines, 265
(n-C 4 H 9 ) 3 SnH, 421
NH, 297
N-Heterocyclic Carbene (NHC), 290, 294,
296, 297, 312, 409, 414, 427–431,
436–438, 441, 442
Ni, 290, 299, 392, 395, 396
Ni(acac) 2 , 76
Ni ALD, 76
Ni(Cp) 2 , 76, 87, 89, 93
Ni NPs, 272, 415
Nitrides, 310, 314, 315
Nitrobenzene reduction, 179
Non-bonding interactions, 373
O
Olefin hydrogenation, 31
Olefin metathesis, 429, 436
Oleylamine, 367, 368, 379, 396, 409
Oligomerization, 304, 305, 331
1,10-bis(diphenylphosphino)decane (dppd),
420
1,3-butadiene, 73, 78, 79, 85, 87
1,3-dicyclohexylimidazolium-2-di-ptolylcarbodiimide (ICy.(p-tol)NCN),
414
1-n-butyl-3-methylimidazolium, 114, 119,
120
1-octylamine, 410, 412
1,3-propanediol, 257
1,3,5-triaza-7-phosphaadamantane (PTA),
424, 425
Over-hydrogenation, 304, 306, 308, 310,
311, 313, 316–318, 321, 324, 325,
329, 331, 332
Oxidation, 408, 410, 430, 431, 436, 438
Oxidation of alcohols, 202
Oxidation of amines, 202
Oxidative addition, 286, 293
Oxide overcoating, 89
Oxygen evolution reaction, 40, 46, 48–50,
64