450
Index
Carbon microfibers (CFs), 439, 440
Carbon nanofibers, 304, 307, 323, 331
Carbon Nanotubes (CNTs), 312, 313, 316,
331, 356, 357, 376–379, 389
Carbon supports, 356, 357, 374, 376, 377
Carbonylative Suzuki coupling, 260
Carboxylic acid, 293
C-D, 282, 283
CeO 2 , 78, 91, 92, 358–361, 364, 375
C-H, 282, 283, 286, 289, 290, 293, 294, 299
C-H activation, 286, 289, 293, 408, 429
Charge-state-dependent catalytic activity,
44, 45
Chemical Shift Perturbation - Nuclear Magnetic Resonance (CSP-NMR), 294
Chemical Shift Perturbations (CSP), 429,
430, 436
Chemical vapour deposition, 390
C-heteroatom couplings, 264, 269, 272
Chitosan, 254, 255, 258, 260–262, 269, 271
Cinnamaldehyde (CAL), 347, 349, 351, 354,
356–358, 364, 366–368, 370, 372,
373, 377, 383, 385, 389, 390, 394
Cinnamyl alcohol (COL), 347, 349, 356,
360, 364, 367, 368, 370–379, 381–
383, 388, 389, 393–397
Citral, 351, 353, 354, 358, 366, 368, 373,
374, 379, 380, 383, 389, 394, 395
Citronellal, 346, 347, 353, 367, 380, 395
Click chemistry, 151–154, 177, 182, 183
Clusters, 290, 349–351, 363, 370, 384, 386
C-N couplings, 264–267
Co, 369, 374–376, 392–394
Co(acac) 2 , 74, 76
Cobalt single sites, 210
CO 2 methanation, 31
Complex reducing agents, 321
Confined structure, 93–95
Conia–ene reaction, 19
CO oxidation, 243
CO 2 reduction, 39, 56, 57, 59–63
Core–shell, 116, 125
Covalent organic frameworks, 149, 150, 176,
177, 180
Cross-dehydrogenative couplings, 266
Crosslinker, 158
Cross-linking, 129, 130, 132, 133, 140, 143,
146, 151, 152, 155, 156, 158–160,
168, 171, 173, 176, 182
Crotonaldehyde, 346, 348, 353, 355, 356,
358–360, 362–364, 366, 367, 374,
379, 381, 384–389, 393, 395, 397
C-S couplings, 269, 271
Cu, 356, 392, 396, 397
Cu ALD, 76
Cu 2 O NPs, 257, 269–271
Cu(thd)2, 74, 76
Cyclodextrin, 412, 418, 424, 425, 434
Cyclodextrinevidenced the strong coordination of the phosphine, 425
D
D 2 , 286, 289–292, 298
Dehydrogenation, 203, 210, 211
Dehydrogenation of ammonia-borane, 410
Dehydrogenation of formic acid, 209, 211,
212
Dehydrolinalool, 311, 328
Deryagin–Landau–Verwey–Overbeek
(DLVO), 109, 110, 113
Deuterated, 282–286, 291, 292, 294, 298
Deuteration, 283, 288–294, 296–299
Deuterium, 282–284, 288, 291–293, 296,
298
Deuterium incorporation, 293, 294, 299
DFT calculations, 293, 295
Dialkyne ligand, 151, 153
Dicarboxylic ligand, 135
Diels Alder reaction, 151
Dithiol ligand, 136, 143
DNA, 130, 150, 158–161, 172, 175–178, 181
Doping effect, 41, 43, 46, 64
Double solvent adsorption, 228, 230, 231,
236, 237
Dynamic covalent chemistry, 166, 167, 172
E
Earth-abundant, 249, 250, 252, 264, 269
Electrochemical catalysis, 39–42, 55
Encapsulation, 221, 227, 228, 309, 329–331
(Ester–assisted) hydration of alkynes (C–O),
13, 20, 21, 23, 27
EtCpIr(COD), 76
Ethylenediamine, 326, 410
Ethylene Glycol (EG), 251–253, 257, 258,
268, 269
F
Faradaic efficiency, 59, 61, 63
Fe 3 O 4 NPs, 257, 258, 261, 265
Film thickness, 70, 83
First row transition metal nanocatalysts, 251
Fischer–Tropsch, 107, 119, 122, 124
Fischer–Tropsch Synthesis, 408
Index
Carbon microfibers (CFs), 439, 440
Carbon nanofibers, 304, 307, 323, 331
Carbon Nanotubes (CNTs), 312, 313, 316,
331, 356, 357, 376–379, 389
Carbon supports, 356, 357, 374, 376, 377
Carbonylative Suzuki coupling, 260
Carboxylic acid, 293
C-D, 282, 283
CeO 2 , 78, 91, 92, 358–361, 364, 375
C-H, 282, 283, 286, 289, 290, 293, 294, 299
C-H activation, 286, 289, 293, 408, 429
Charge-state-dependent catalytic activity,
44, 45
Chemical Shift Perturbation - Nuclear Magnetic Resonance (CSP-NMR), 294
Chemical Shift Perturbations (CSP), 429,
430, 436
Chemical vapour deposition, 390
C-heteroatom couplings, 264, 269, 272
Chitosan, 254, 255, 258, 260–262, 269, 271
Cinnamaldehyde (CAL), 347, 349, 351, 354,
356–358, 364, 366–368, 370, 372,
373, 377, 383, 385, 389, 390, 394
Cinnamyl alcohol (COL), 347, 349, 356,
360, 364, 367, 368, 370–379, 381–
383, 388, 389, 393–397
Citral, 351, 353, 354, 358, 366, 368, 373,
374, 379, 380, 383, 389, 394, 395
Citronellal, 346, 347, 353, 367, 380, 395
Click chemistry, 151–154, 177, 182, 183
Clusters, 290, 349–351, 363, 370, 384, 386
C-N couplings, 264–267
Co, 369, 374–376, 392–394
Co(acac) 2 , 74, 76
Cobalt single sites, 210
CO 2 methanation, 31
Complex reducing agents, 321
Confined structure, 93–95
Conia–ene reaction, 19
CO oxidation, 243
CO 2 reduction, 39, 56, 57, 59–63
Core–shell, 116, 125
Covalent organic frameworks, 149, 150, 176,
177, 180
Cross-dehydrogenative couplings, 266
Crosslinker, 158
Cross-linking, 129, 130, 132, 133, 140, 143,
146, 151, 152, 155, 156, 158–160,
168, 171, 173, 176, 182
Crotonaldehyde, 346, 348, 353, 355, 356,
358–360, 362–364, 366, 367, 374,
379, 381, 384–389, 393, 395, 397
C-S couplings, 269, 271
Cu, 356, 392, 396, 397
Cu ALD, 76
Cu 2 O NPs, 257, 269–271
Cu(thd)2, 74, 76
Cyclodextrin, 412, 418, 424, 425, 434
Cyclodextrinevidenced the strong coordination of the phosphine, 425
D
D 2 , 286, 289–292, 298
Dehydrogenation, 203, 210, 211
Dehydrogenation of ammonia-borane, 410
Dehydrogenation of formic acid, 209, 211,
212
Dehydrolinalool, 311, 328
Deryagin–Landau–Verwey–Overbeek
(DLVO), 109, 110, 113
Deuterated, 282–286, 291, 292, 294, 298
Deuteration, 283, 288–294, 296–299
Deuterium, 282–284, 288, 291–293, 296,
298
Deuterium incorporation, 293, 294, 299
DFT calculations, 293, 295
Dialkyne ligand, 151, 153
Dicarboxylic ligand, 135
Diels Alder reaction, 151
Dithiol ligand, 136, 143
DNA, 130, 150, 158–161, 172, 175–178, 181
Doping effect, 41, 43, 46, 64
Double solvent adsorption, 228, 230, 231,
236, 237
Dynamic covalent chemistry, 166, 167, 172
E
Earth-abundant, 249, 250, 252, 264, 269
Electrochemical catalysis, 39–42, 55
Encapsulation, 221, 227, 228, 309, 329–331
(Ester–assisted) hydration of alkynes (C–O),
13, 20, 21, 23, 27
EtCpIr(COD), 76
Ethylenediamine, 326, 410
Ethylene Glycol (EG), 251–253, 257, 258,
268, 269
F
Faradaic efficiency, 59, 61, 63
Fe 3 O 4 NPs, 257, 258, 261, 265
Film thickness, 70, 83
First row transition metal nanocatalysts, 251
Fischer–Tropsch, 107, 119, 122, 124
Fischer–Tropsch Synthesis, 408