12 Ligand Effects in Ruthenium Nanoparticle Catalysis
447
69. Gonzalez-Galvez D, Lara P, Rivada-Wheelaghan O, Conejero S, Chaudret B, Philippot K,
van Leeuwen PWNM (2013) NHC-stabilized ruthenium nanoparticles as new catalysts for the
hydrogenation of aromatics. Catal Sci Tech 3:99–105
70. Martínez-Prieto LM, Ferry A, Lara P, Richter C, Philippot K, Glorius F, Chaudret B (2015)
New Route to Stabilize Ruthenium Nanoparticles with Non-Isolable Chiral N-Heterocyclic
Carbenes. Chem A Eur J 21:17495–17502
71. Lara P, Martínez-Prieto LM, Roselló-Merino M, Richter C, Glorius F, Conejero S, Philippot K,
Chaudret B (2016) NHC-stabilized Ru nanoparticles: Synthesis and surface studies. NanoSO
6:39–45
72. Higman CS, Lanterna AE, Marin ML, Scaiano JC, Fogg DE (2016) Catalyst decomposition
during yields isomerization-active ruthenium nanoparticles. ChemCatChem 8:2446–2449
73. Tay BY, Wang C, Phua PH, Stubbs LP, Huynh HV (2016) Selective hydrogenation of levulinic
acid to γ-valerolactone using in situ generated ruthenium nanoparticles derived complexes.
Dalton Trans 45:3558–3563
74. Baquero EA, Tricard S, Flores JC, de Jesús E, Chaudret B (2014) Highly stable water-soluble
platinum nanoparticles stabilized by hydrophilic N-heterocyclic carbenes. Angew Chem Int
Ed 126:13436–13440
75. Asensio JM, Tricard S, Coppel Y, Andrés R, Chaudret B, de Jesús E (2017) Knight shift in 13c
nmr resonances confirms the coordination of N-heterocyclic carbene ligands to water-soluble
palladium nanoparticles. Angew Chem Int Ed 129:883–887
76. Martinez-Prieto LM, Baquero EA, Pieters G, Flores JC, de Jesus E, Nayral C, Delpech F,
van Leeuwen PWNM, Lippens G, Chaudret B (2017) Monitoring of nanoparticle reactivity in
solution: interaction of l-lysine and Ru nanoparticles probed parallels regioselective H/. Chem
Commun 53:5850–5853
77. Taglang C, Martínez-Prieto LM, del Rosal I, Maron L, Poteau R, Philippot K, Chaudret B,
Perato S, Sam Lone A, Puente C, Dugave C, Rousseau B, Pieters G (2015) Enantiospecific
using ruthenium nanocatalysts. Angew Chem Int Ed 54:10474–10477
78. Palazzolo A, Feuillastre S, Pfeifer V, Garcia-Argote S, Bouzouita D, Tricard S, Chollet C,
Marcon E, Buisson D-A, Cholet S, Fenaille F, Lippens G, Chaudret B, Pieters G (2019) Efficient access to deuterated and tritiated nucleobase pharmaceuticals and oligonucleotides using
hydrogen-isotope exchange. Angew Chem Int Ed 58:4891–4895
79. Bouzouita D, Lippens G, Baquero EA, Fazzini PF, Pieters G, Coppel Y, Lecante P, Tricard S,
Martínez-Prieto LM, Chaudret B (2019) Tuning the catalytic activity and selectivity of watersoluble bimetallic by modifying their surface metal distribution. Nanoscale 11:16544–16552
80. Martinez-Prieto LM, Ferry A, Rakers L, Richter C, Lecante P, Philippot K, Chaudret B, Glorius
F (2016) as versatile catalysts for one-pot/hydrogenation reactions. Chem Commun 52:4768–
4771
81. Martínez-Prieto LM, Rakers L, López-Vinasco AM, Cano I, Coppel Y, Philippot K, Glorius F,
Chaudret B, van Leeuwen PWNM (2017) Soluble platinum nanoparticles ligated by long-chain
N-heterocyclic carbenes as catalysts. Chem A Eur J 23:12779–12786
82. Rakers L, Martínez-Prieto LM, López-Vinasco AM, Philippot K, van Leeuwen PWNM, Chaudret B, Glorius F (2018) Ruthenium nanoparticles ligated by and their application in the
hydrogenation of arenes. Chem Commun 54:7070–7073
83. Kunz S (2016) Supported, ligand-functionalized nanoparticles: an attempt to rationalize the
application and potential of ligands in heterogeneous catalysis. Top Catal 59:1671–1685
84. Mallat T, Orglmeister E, Baiker A (2007) Asymmetric catalysis at chiral metal surfaces. Chem
Rev 107:4863–4890
85. Ernst JB, Muratsugu S, Wang F, Tada M, Glorius F (2016) Tunable heterogeneous catalysis:
N-heterocyclic carbenes as ligands for supported heterogeneous Ru/ catalysts to tune reactivity
and selectivity. J Am Chem Soc 138:10718–10721
86. Albani D, Li Q, Vile G, Mitchell S, Almora-Barrios N, Witte PT, Lopez N, Perez-Ramirez J
(2017) Interfacial acidity in ligand-modified ruthenium nanoparticles boosts the hydrogenation
of levulinic acid to gamma-valerolactone. Green Chem 19:2361–2370
87. van Leeuwen PWNM, González Gálvez D (2013) WO/2014/056889, 8 Oct 2013
447
69. Gonzalez-Galvez D, Lara P, Rivada-Wheelaghan O, Conejero S, Chaudret B, Philippot K,
van Leeuwen PWNM (2013) NHC-stabilized ruthenium nanoparticles as new catalysts for the
hydrogenation of aromatics. Catal Sci Tech 3:99–105
70. Martínez-Prieto LM, Ferry A, Lara P, Richter C, Philippot K, Glorius F, Chaudret B (2015)
New Route to Stabilize Ruthenium Nanoparticles with Non-Isolable Chiral N-Heterocyclic
Carbenes. Chem A Eur J 21:17495–17502
71. Lara P, Martínez-Prieto LM, Roselló-Merino M, Richter C, Glorius F, Conejero S, Philippot K,
Chaudret B (2016) NHC-stabilized Ru nanoparticles: Synthesis and surface studies. NanoSO
6:39–45
72. Higman CS, Lanterna AE, Marin ML, Scaiano JC, Fogg DE (2016) Catalyst decomposition
during yields isomerization-active ruthenium nanoparticles. ChemCatChem 8:2446–2449
73. Tay BY, Wang C, Phua PH, Stubbs LP, Huynh HV (2016) Selective hydrogenation of levulinic
acid to γ-valerolactone using in situ generated ruthenium nanoparticles derived complexes.
Dalton Trans 45:3558–3563
74. Baquero EA, Tricard S, Flores JC, de Jesús E, Chaudret B (2014) Highly stable water-soluble
platinum nanoparticles stabilized by hydrophilic N-heterocyclic carbenes. Angew Chem Int
Ed 126:13436–13440
75. Asensio JM, Tricard S, Coppel Y, Andrés R, Chaudret B, de Jesús E (2017) Knight shift in 13c
nmr resonances confirms the coordination of N-heterocyclic carbene ligands to water-soluble
palladium nanoparticles. Angew Chem Int Ed 129:883–887
76. Martinez-Prieto LM, Baquero EA, Pieters G, Flores JC, de Jesus E, Nayral C, Delpech F,
van Leeuwen PWNM, Lippens G, Chaudret B (2017) Monitoring of nanoparticle reactivity in
solution: interaction of l-lysine and Ru nanoparticles probed parallels regioselective H/. Chem
Commun 53:5850–5853
77. Taglang C, Martínez-Prieto LM, del Rosal I, Maron L, Poteau R, Philippot K, Chaudret B,
Perato S, Sam Lone A, Puente C, Dugave C, Rousseau B, Pieters G (2015) Enantiospecific
using ruthenium nanocatalysts. Angew Chem Int Ed 54:10474–10477
78. Palazzolo A, Feuillastre S, Pfeifer V, Garcia-Argote S, Bouzouita D, Tricard S, Chollet C,
Marcon E, Buisson D-A, Cholet S, Fenaille F, Lippens G, Chaudret B, Pieters G (2019) Efficient access to deuterated and tritiated nucleobase pharmaceuticals and oligonucleotides using
hydrogen-isotope exchange. Angew Chem Int Ed 58:4891–4895
79. Bouzouita D, Lippens G, Baquero EA, Fazzini PF, Pieters G, Coppel Y, Lecante P, Tricard S,
Martínez-Prieto LM, Chaudret B (2019) Tuning the catalytic activity and selectivity of watersoluble bimetallic by modifying their surface metal distribution. Nanoscale 11:16544–16552
80. Martinez-Prieto LM, Ferry A, Rakers L, Richter C, Lecante P, Philippot K, Chaudret B, Glorius
F (2016) as versatile catalysts for one-pot/hydrogenation reactions. Chem Commun 52:4768–
4771
81. Martínez-Prieto LM, Rakers L, López-Vinasco AM, Cano I, Coppel Y, Philippot K, Glorius F,
Chaudret B, van Leeuwen PWNM (2017) Soluble platinum nanoparticles ligated by long-chain
N-heterocyclic carbenes as catalysts. Chem A Eur J 23:12779–12786
82. Rakers L, Martínez-Prieto LM, López-Vinasco AM, Philippot K, van Leeuwen PWNM, Chaudret B, Glorius F (2018) Ruthenium nanoparticles ligated by and their application in the
hydrogenation of arenes. Chem Commun 54:7070–7073
83. Kunz S (2016) Supported, ligand-functionalized nanoparticles: an attempt to rationalize the
application and potential of ligands in heterogeneous catalysis. Top Catal 59:1671–1685
84. Mallat T, Orglmeister E, Baiker A (2007) Asymmetric catalysis at chiral metal surfaces. Chem
Rev 107:4863–4890
85. Ernst JB, Muratsugu S, Wang F, Tada M, Glorius F (2016) Tunable heterogeneous catalysis:
N-heterocyclic carbenes as ligands for supported heterogeneous Ru/ catalysts to tune reactivity
and selectivity. J Am Chem Soc 138:10718–10721
86. Albani D, Li Q, Vile G, Mitchell S, Almora-Barrios N, Witte PT, Lopez N, Perez-Ramirez J
(2017) Interfacial acidity in ligand-modified ruthenium nanoparticles boosts the hydrogenation
of levulinic acid to gamma-valerolactone. Green Chem 19:2361–2370
87. van Leeuwen PWNM, González Gálvez D (2013) WO/2014/056889, 8 Oct 2013