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170. Bruehwiler A, Semagina N, Grasemann M, Renken A, Kiwi-Minsker L, Saaler A, Lehmann
H, Bonrath W, Roessler F (2008) Three-phase catalytic hydrogenation of a functionalized
alkyne: mass transfer and kinetic studies with in situ hydrogen monitoring. Ind Eng Chem
Res 47(18):6862–6869. https://doi.org/10.1021/ie800070w
171. Wu Z, Calcio Gaudino E, Rotolo L, Medlock J, Bonrath W, Cravotto G (2016) Efficient
partial hydrogenation of 2-butyne-1,4-diol and other alkynes under microwave irradiation.
Chem Eng Process 110:220–224. https://doi.org/10.1016/j.cep.2016.10.016
172. Wu Z, Cravotto G, Gaudino EC, Giacomino A, Medlock J, Bonrath W (2017) Ultrasonically
improved semi-hydrogenation of alkynes to (Z-)alkenes over novel lead-free Pd/Boehmite
catalysts. Ultrason Sonochem Part B 35:664–672. http://dx.doi.org/10.1016/j.ultsonch.2016.
05.019
173. Fukazawa A, Minoshima J, Tanaka K, Hashimoto Y, Kobori Y, Sato Y, Atobe M (2019) A new
approach to stereoselective electrocatalytic semihydrogenation of alkynes to Z-alkenes using
a proton-exchange membrane reactor. ACS Sustain Chem Eng 7(13):11050–11055. https://
doi.org/10.1021/acssuschemeng.9b01882
J. A. Delgado and C. Godard
161. Vilé G, Dähler P, Vecchietti J, Baltanás M, Collins S, Calatayud M, Bonivardi A, PérezRamírez J (2015) Promoted ceria catalysts for alkyne semi-hydrogenation. J Catal 324:69–78.
https://doi.org/10.1016/j.jcat.2015.01.020
162. Vile G, Perez-Ramirez J (2014) Beyond the use of modifiers in selective alkyne hydrogenation:
silver and gold nanocatalysts in flow mode for sustainable alkene production. Nanoscale
6(22):13476–13482. https://doi.org/10.1039/c4nr02777a
163. Riley C, De La Riva A, Zhou S, Wan Q, Peterson E, Artyushkova K, Farahani MD, Friedrich
HB, Burkemper L, Atudorei N-V, Lin S, Guo H, Datye A (2019) Synthesis of nickeldoped ceria catalysts for selective acetylene hydrogenation. ChemCatChem 11(5):1526–1533.
https://doi.org/10.1002/cctc.201801976
164. Patarroyo J, Delgado JA, Merkoçi F, Genç A, Sauthier G, Llorca J, Arbiol J, Bastus NG,
Godard C, Claver C, Puntes V (2019) Hollow PdAg-CeO 2 heterodimer nanocrystals as highly
structured heterogeneous catalysts. Sci Rep 9(1):18776. https://doi.org/10.1038/s41598-01955105-x
165. Gulyaeva YK, Kaichev VV, Zaikovskii VI, Suknev AP, Bal’zhinimaev BS (2015) Selective
hydrogenation of acetylene over Pd/Fiberglass catalysts: kinetic and isotopic studies. App
Catal A Gen 506:197–205. http://dx.doi.org/10.1016/j.apcata.2015.09.016
166. Liang H, Zhang B, Ge H, Gu X, Zhang S, Qin Y (2017) Porous TiO 2 /Pt/TiO 2 sandwich catalyst
for highly selective semihydrogenation of alkyne to olefin. ACS Catal 7(10):6567–6572.
https://doi.org/10.1021/acscatal.7b02032
167. Chen F, Kreyenschulte C, Radnik J, Lund H, Surkus A-E, Junge K, Beller M (2017) Selective
semihdrogenation of alkynes with N-graphitic-modified cobalt nanoparticles supported on
silica. ACS Catal 7(3):1526–1532. https://doi.org/10.1021/acscatal.6b03140
168. Wang S, Zhao Z-J, Chang X, Zhao J, Tian H, Yang C, Li M, Fu Q, Mu R, Gong J (2019)
Activation and spillover of hydrogen on sub-1 nm palladium nanoclusters confined within
sodalite zeolite for the semi-hydrogenation of alkynes. Angew Chem Int Ed 58(23):7668–
7672. https://doi.org/10.1002/anie.201903827
169. Chesnokov VV, Podyacheva OY, Richards RM (2017) Influence of carbon nanomaterials
on the properties of Pd/C catalysts in selective hydrogenation of acetylene. Mater Res Bull
88:78–84. https://doi.org/10.1016/j.materresbull.2016.12.013
170. Bruehwiler A, Semagina N, Grasemann M, Renken A, Kiwi-Minsker L, Saaler A, Lehmann
H, Bonrath W, Roessler F (2008) Three-phase catalytic hydrogenation of a functionalized
alkyne: mass transfer and kinetic studies with in situ hydrogen monitoring. Ind Eng Chem
Res 47(18):6862–6869. https://doi.org/10.1021/ie800070w
171. Wu Z, Calcio Gaudino E, Rotolo L, Medlock J, Bonrath W, Cravotto G (2016) Efficient
partial hydrogenation of 2-butyne-1,4-diol and other alkynes under microwave irradiation.
Chem Eng Process 110:220–224. https://doi.org/10.1016/j.cep.2016.10.016
172. Wu Z, Cravotto G, Gaudino EC, Giacomino A, Medlock J, Bonrath W (2017) Ultrasonically
improved semi-hydrogenation of alkynes to (Z-)alkenes over novel lead-free Pd/Boehmite
catalysts. Ultrason Sonochem Part B 35:664–672. http://dx.doi.org/10.1016/j.ultsonch.2016.
05.019
173. Fukazawa A, Minoshima J, Tanaka K, Hashimoto Y, Kobori Y, Sato Y, Atobe M (2019) A new
approach to stereoselective electrocatalytic semihydrogenation of alkynes to Z-alkenes using
a proton-exchange membrane reactor. ACS Sustain Chem Eng 7(13):11050–11055. https://
doi.org/10.1021/acssuschemeng.9b01882