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96. Zhang Y, Diao W, Williams CT, Monnier JR (2014) Selective hydrogenation of acetylene
in excess ethylene using Ag- and Au–Pd/SiO 2 bimetallic catalysts prepared by electroless
deposition. App Catal A Gen 469:419–426. https://doi.org/10.1016/j.apcata.2013.10.024
97. Evangelisti C, Panziera N, D’Alessio A, Bertinetti L, Botavina M, Vitulli G (2010) New
monodispersed palladium nanoparticles stabilized by poly-(N-vinyl-2-pyrrolidone): preparation, structural study and catalytic properties. J Catal 272(2):246–252. https://doi.org/10.
1016/j.jcat.2010.04.006
98. Hirai H, Yakura N (2001) Protecting polymers in suspension of metal nanoparticles. Polym
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99. Telkar MM, Rode CV, Chaudhari RV, Joshi SS, Nalawade AM (2004) Shape-controlled preparation and catalytic activity of metal nanoparticles for hydrogenation of 2-butyne-1,4-diol
and styrene oxide. App Catal A Gen 273(1–2):11–19. https://doi.org/10.1016/j.apcata.2004.
05.056
100. Witte PT, Boland S, Kirby F, van Maanen R, Bleeker BF, de Winter DAM, Post JA, Geus
JW, Berben PH (2013) NanoSelect Pd catalysts: what causes the high selectivity of these
supported colloidal catalysts in alkyne semi-hydrogenation? ChemCatChem 5(2):582–587.
http://dx.doi.org/10.1002/cctc.201200460
101. Niu M, Wang Y, Li W, Jiang J, Jin Z (2013) Highly efficient and recyclable ruthenium nanoparticle catalyst for semihydrogenation of alkynes. Catal Commun 38:77–81. https://doi.org/10.
1016/j.catcom.2013.04.015
102. Zharmagambetova A, Zamanbekova A, Jumekeyeva A, Tumabayev N (2017) Study of nickel
catalysts in hydrogenation of acetylene alcohols at low-temperature. Izv Nats Akad Nauk
Resp Kaz, Ser Khim Tekhnol 4:65–72
103. Zharmagambetova AK, Zamanbekova AT, Darmenbayeva AS, Auyezkhanova AS,
Jumekeyeva AI, Talgatov ET (2017) Effect of polymers on the formation of nanosized palladium catalysts and their activity and selectivity in the hydrogenation of acetylenic alcohols.
Theor Exp Chem 53(4):265–269. https://doi.org/10.1007/s11237-017-9524-8
104. Long W, Brunelli NA, Didas SA, Ping EW, Jones CW (2013) Aminopolymer-silica compositesupported Pd catalysts for selective hydrogenation of alkynes. ACS Catal 3(8):1700–1708.
https://doi.org/10.1021/cs3007395
105. Kuwahara Y, Kango H, Yamashita H (2019) Pd nanoparticles and aminopolymers confined in
hollow silica spheres as efficient and reusable heterogeneous catalysts for semihydrogenation
of alkynes. ACS Catal 9(3):1993–2006. https://doi.org/10.1021/acscatal.8b04653
106. Maesing F, Wang X, Nuesse H, Klingauf J, Studer A (2017) Facile light-mediated preparation of small polymer-coated palladium-nanoparticles and their application as catalysts for
alkyne semi-hydrogenation. Chem Eur J 23(25):6014–6018. https://doi.org/10.1002/chem.
201603297
107. Maesing F, Nuesse H, Klingauf J, Studer A (2017) Light Mediated preparation of palladium
nanoparticles as catalysts for alkyne cis-semihydrogenation. Org Lett 19(10):2658–2661.
https://doi.org/10.1021/acs.orglett.7b00999
108. Semagina N, Joannet E, Parra S, Sulman E, Renken A, Kiwi-Minsker L (2005) Palladium
nanoparticles stabilized in block-copolymer micelles for highly selective 2-butyne-1,4-diol
partial hydrogenation. App Catal A Gen 280(2):141–147. https://doi.org/10.1016/j.apcata.
2004.10.049
109. Mizugaki T, Murata M, Fukubayashi S, Mitsudome T, Jitsukawa K, Kaneda K (2008) PAMAM
dendron-stabilised palladium nanoparticles: effect of generation and peripheral groups on
particle size and hydrogenation activity. Chem Commun 2:241–243. https://doi.org/10.1039/
b710860e
110. Karakhanov EA, Maximov AL, Zolotukhina AV (2019) Selective semi-hydrogenation of
phenyl acetylene by Pd nanocatalysts encapsulated into dendrimer networks. Mol Catal
469:98–110. https://doi.org/10.1016/j.mcat.2019.03.005
J. A. Delgado and C. Godard
95. Shi X, Wen X, Nie S, Dong J, Li J, Shi Y, Zhang H, Bai G (2020) Fabrication of Ni 3 N nanorods
anchored on N-doped carbon for selective semi-hydrogenation of alkynes. J Catal 382:22–30.
https://doi.org/10.1016/j.jcat.2019.12.005
96. Zhang Y, Diao W, Williams CT, Monnier JR (2014) Selective hydrogenation of acetylene
in excess ethylene using Ag- and Au–Pd/SiO 2 bimetallic catalysts prepared by electroless
deposition. App Catal A Gen 469:419–426. https://doi.org/10.1016/j.apcata.2013.10.024
97. Evangelisti C, Panziera N, D’Alessio A, Bertinetti L, Botavina M, Vitulli G (2010) New
monodispersed palladium nanoparticles stabilized by poly-(N-vinyl-2-pyrrolidone): preparation, structural study and catalytic properties. J Catal 272(2):246–252. https://doi.org/10.
1016/j.jcat.2010.04.006
98. Hirai H, Yakura N (2001) Protecting polymers in suspension of metal nanoparticles. Polym
Adv Technol 12(11–12):724–733. https://doi.org/10.1002/pat.95
99. Telkar MM, Rode CV, Chaudhari RV, Joshi SS, Nalawade AM (2004) Shape-controlled preparation and catalytic activity of metal nanoparticles for hydrogenation of 2-butyne-1,4-diol
and styrene oxide. App Catal A Gen 273(1–2):11–19. https://doi.org/10.1016/j.apcata.2004.
05.056
100. Witte PT, Boland S, Kirby F, van Maanen R, Bleeker BF, de Winter DAM, Post JA, Geus
JW, Berben PH (2013) NanoSelect Pd catalysts: what causes the high selectivity of these
supported colloidal catalysts in alkyne semi-hydrogenation? ChemCatChem 5(2):582–587.
http://dx.doi.org/10.1002/cctc.201200460
101. Niu M, Wang Y, Li W, Jiang J, Jin Z (2013) Highly efficient and recyclable ruthenium nanoparticle catalyst for semihydrogenation of alkynes. Catal Commun 38:77–81. https://doi.org/10.
1016/j.catcom.2013.04.015
102. Zharmagambetova A, Zamanbekova A, Jumekeyeva A, Tumabayev N (2017) Study of nickel
catalysts in hydrogenation of acetylene alcohols at low-temperature. Izv Nats Akad Nauk
Resp Kaz, Ser Khim Tekhnol 4:65–72
103. Zharmagambetova AK, Zamanbekova AT, Darmenbayeva AS, Auyezkhanova AS,
Jumekeyeva AI, Talgatov ET (2017) Effect of polymers on the formation of nanosized palladium catalysts and their activity and selectivity in the hydrogenation of acetylenic alcohols.
Theor Exp Chem 53(4):265–269. https://doi.org/10.1007/s11237-017-9524-8
104. Long W, Brunelli NA, Didas SA, Ping EW, Jones CW (2013) Aminopolymer-silica compositesupported Pd catalysts for selective hydrogenation of alkynes. ACS Catal 3(8):1700–1708.
https://doi.org/10.1021/cs3007395
105. Kuwahara Y, Kango H, Yamashita H (2019) Pd nanoparticles and aminopolymers confined in
hollow silica spheres as efficient and reusable heterogeneous catalysts for semihydrogenation
of alkynes. ACS Catal 9(3):1993–2006. https://doi.org/10.1021/acscatal.8b04653
106. Maesing F, Wang X, Nuesse H, Klingauf J, Studer A (2017) Facile light-mediated preparation of small polymer-coated palladium-nanoparticles and their application as catalysts for
alkyne semi-hydrogenation. Chem Eur J 23(25):6014–6018. https://doi.org/10.1002/chem.
201603297
107. Maesing F, Nuesse H, Klingauf J, Studer A (2017) Light Mediated preparation of palladium
nanoparticles as catalysts for alkyne cis-semihydrogenation. Org Lett 19(10):2658–2661.
https://doi.org/10.1021/acs.orglett.7b00999
108. Semagina N, Joannet E, Parra S, Sulman E, Renken A, Kiwi-Minsker L (2005) Palladium
nanoparticles stabilized in block-copolymer micelles for highly selective 2-butyne-1,4-diol
partial hydrogenation. App Catal A Gen 280(2):141–147. https://doi.org/10.1016/j.apcata.
2004.10.049
109. Mizugaki T, Murata M, Fukubayashi S, Mitsudome T, Jitsukawa K, Kaneda K (2008) PAMAM
dendron-stabilised palladium nanoparticles: effect of generation and peripheral groups on
particle size and hydrogenation activity. Chem Commun 2:241–243. https://doi.org/10.1039/
b710860e
110. Karakhanov EA, Maximov AL, Zolotukhina AV (2019) Selective semi-hydrogenation of
phenyl acetylene by Pd nanocatalysts encapsulated into dendrimer networks. Mol Catal
469:98–110. https://doi.org/10.1016/j.mcat.2019.03.005