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M. Camats et al.
21. Bulut S, Fei Z, Siankevich S, Zhang J, Yan N, Dyson PJ (2015) Aqueous-phase hydrogenation
of alkenes and arenes: the growing role of nanoscale catalysts. Catal Today 247:96–103.
https://doi.org/10.1016/j.cattod.2014.09.002
22. Cahiez G, Moyeux A (2010) Cobalt-catalyzed cross-coupling reactions. Chem Rev
110(3):1435–1462. https://doi.org/10.1021/cr9000786
23. Chahdoura F, Favier I, Gómez M (2014) Glycerol as suitable solvent for the synthesis of
metallic species and catalysis. Chem Eur J 20(35):10884–10893. https://doi.org/10.1002/
chem.201403534
24. Chahdoura F, Pradel C, Gómez M (2014) Copper(I) oxide nanoparticles in glycerol: a convenient catalyst for cross-coupling and azide-alkyne cycloaddition processes. ChemCatChem
6(10):2929–2936. https://doi.org/10.1002/cctc.201402214
25. Chakraborty S, Shah NH, Fishbein JC, Hosmane RS (2011) A novel transition state analog
inhibitor of guanase based on azepinomycin ring structure: synthesis and biochemical assessment of enzyme inhibition. Bioorg Med Chem Lett 21(2):756–759. https://doi.org/10.1016/
j.bmcl.2010.11.109
26. Chattopadhyay K, Dey R, Ranu BC (2009) Shape-dependent catalytic activity of copper
oxide-supported Pd(0) nanoparticles for Suzuki and cyanation reactions. Tetrahedron Lett
50(26):3164–3167. https://doi.org/10.1016/j.tetlet.2009.01.027
27. Chirik P, Morris R (2015) Getting down to earth: the renaissance of catalysis with abundant
metals. Acc Chem Res 48(9):2495. https://doi.org/10.1021/acs.accounts.5b00385
28. Corain B, Schmid G, Toshima N (eds) (2011) Metal Nanoclusters in Catalysis and Materials
Science: The Issue of Size Control. Elsevier Science, Amsterdam
29. Cordente N, Respaud M, Senocq F, Casanove M-J, Amiens C, Chaudret B (2001) Synthesis
and magnetic properties of nickel nanorods. Nano Lett 1(10):565–568. https://doi.org/10.
1021/nl0100522
30. Corriu RJP, Masse JP (1972) Activation of grignard reagents by transition-metal complexes.
A new and simple synthesis of trans-stilbenes and polyphenyls. J Chem Soc Chem Commun
3:144a. https://doi.org/10.1039/C3972000144A
31. Dabiri M, Vajargahy MP (2017) PdCo bimetallic nanoparticles supported on threedimensional graphene as a highly active catalyst for sonogashira cross-coupling reaction.
Appl Organomet Chem 31(4):e3594. https://doi.org/10.1002/aoc.3594
32. Dahl JA, Maddux BLS, Hutchison JE (2007) Toward greener nanosynthesis. Chem Rev
107(6):2228–2269. https://doi.org/10.1021/cr050943k
33. Dang-Bao T, Pradel C, Favier I, Gómez M (2017) Making copper(0) nanoparticles in glycerol:
a straightforward synthesis for a multipurpose catalyst. Adv Synth Catal 359(16):2832–2846.
https://doi.org/10.1002/adsc.201700535
34. Dang-Bao T, Pradel C, Favier I, Gómez M (2019) Bimetallic nanocatalysts in glycerol for
applications in controlled synthesis. a structure–reactivity relationship study. ACS Appl. Nano
Mater 2(2):1033–1044. https://doi.org/10.1021/acsanm.8b02316
35. Díez-González S (2016) Copper(I)–acetylides: access, structure, and relevance in catalysis.
In: Pérez PJ (ed) Advances in Organometallic Chemistry, vol 66. Academic Press, pp 93–141
36. Dong H, Chen YC, Feldmann C (2015) Polyol synthesis of nanoparticles: status and options
regarding metals, oxides, chalcogenides, and non-metal elements. Green Chem 17(8):4107–
4132. https://doi.org/10.1039/C5GC00943J
37. Eicher T, Hauptmann S, Speicher A (2013) The chemistry of heterocycles: structures,
reactions, synthesis, and applications. Wiley-VCH, Weinheim
38. Evano G, Blanchard N, Toumi M (2008) Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis. Chem Rev 108(8):3054–
3131. https://doi.org/10.1021/cr8002505
39. Fakhri A, Naghipour A (2018) Organometallic polymer-functionalized Fe 3 O 4 nanoparticles
as a highly efficient and eco-friendly nanocatalyst for C-C bond formation. Trans Met Chem
43(5):463–472. https://doi.org/10.1007/s11243-018-0233-5
40. Favier I, Pla D, Gómez M (2018) Metal-based nanoparticles dispersed in glycerol: an efficient
approach for catalysis. Catal Today 310:98–106. https://doi.org/10.1016/j.cattod.2017.06.026
M. Camats et al.
21. Bulut S, Fei Z, Siankevich S, Zhang J, Yan N, Dyson PJ (2015) Aqueous-phase hydrogenation
of alkenes and arenes: the growing role of nanoscale catalysts. Catal Today 247:96–103.
https://doi.org/10.1016/j.cattod.2014.09.002
22. Cahiez G, Moyeux A (2010) Cobalt-catalyzed cross-coupling reactions. Chem Rev
110(3):1435–1462. https://doi.org/10.1021/cr9000786
23. Chahdoura F, Favier I, Gómez M (2014) Glycerol as suitable solvent for the synthesis of
metallic species and catalysis. Chem Eur J 20(35):10884–10893. https://doi.org/10.1002/
chem.201403534
24. Chahdoura F, Pradel C, Gómez M (2014) Copper(I) oxide nanoparticles in glycerol: a convenient catalyst for cross-coupling and azide-alkyne cycloaddition processes. ChemCatChem
6(10):2929–2936. https://doi.org/10.1002/cctc.201402214
25. Chakraborty S, Shah NH, Fishbein JC, Hosmane RS (2011) A novel transition state analog
inhibitor of guanase based on azepinomycin ring structure: synthesis and biochemical assessment of enzyme inhibition. Bioorg Med Chem Lett 21(2):756–759. https://doi.org/10.1016/
j.bmcl.2010.11.109
26. Chattopadhyay K, Dey R, Ranu BC (2009) Shape-dependent catalytic activity of copper
oxide-supported Pd(0) nanoparticles for Suzuki and cyanation reactions. Tetrahedron Lett
50(26):3164–3167. https://doi.org/10.1016/j.tetlet.2009.01.027
27. Chirik P, Morris R (2015) Getting down to earth: the renaissance of catalysis with abundant
metals. Acc Chem Res 48(9):2495. https://doi.org/10.1021/acs.accounts.5b00385
28. Corain B, Schmid G, Toshima N (eds) (2011) Metal Nanoclusters in Catalysis and Materials
Science: The Issue of Size Control. Elsevier Science, Amsterdam
29. Cordente N, Respaud M, Senocq F, Casanove M-J, Amiens C, Chaudret B (2001) Synthesis
and magnetic properties of nickel nanorods. Nano Lett 1(10):565–568. https://doi.org/10.
1021/nl0100522
30. Corriu RJP, Masse JP (1972) Activation of grignard reagents by transition-metal complexes.
A new and simple synthesis of trans-stilbenes and polyphenyls. J Chem Soc Chem Commun
3:144a. https://doi.org/10.1039/C3972000144A
31. Dabiri M, Vajargahy MP (2017) PdCo bimetallic nanoparticles supported on threedimensional graphene as a highly active catalyst for sonogashira cross-coupling reaction.
Appl Organomet Chem 31(4):e3594. https://doi.org/10.1002/aoc.3594
32. Dahl JA, Maddux BLS, Hutchison JE (2007) Toward greener nanosynthesis. Chem Rev
107(6):2228–2269. https://doi.org/10.1021/cr050943k
33. Dang-Bao T, Pradel C, Favier I, Gómez M (2017) Making copper(0) nanoparticles in glycerol:
a straightforward synthesis for a multipurpose catalyst. Adv Synth Catal 359(16):2832–2846.
https://doi.org/10.1002/adsc.201700535
34. Dang-Bao T, Pradel C, Favier I, Gómez M (2019) Bimetallic nanocatalysts in glycerol for
applications in controlled synthesis. a structure–reactivity relationship study. ACS Appl. Nano
Mater 2(2):1033–1044. https://doi.org/10.1021/acsanm.8b02316
35. Díez-González S (2016) Copper(I)–acetylides: access, structure, and relevance in catalysis.
In: Pérez PJ (ed) Advances in Organometallic Chemistry, vol 66. Academic Press, pp 93–141
36. Dong H, Chen YC, Feldmann C (2015) Polyol synthesis of nanoparticles: status and options
regarding metals, oxides, chalcogenides, and non-metal elements. Green Chem 17(8):4107–
4132. https://doi.org/10.1039/C5GC00943J
37. Eicher T, Hauptmann S, Speicher A (2013) The chemistry of heterocycles: structures,
reactions, synthesis, and applications. Wiley-VCH, Weinheim
38. Evano G, Blanchard N, Toumi M (2008) Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis. Chem Rev 108(8):3054–
3131. https://doi.org/10.1021/cr8002505
39. Fakhri A, Naghipour A (2018) Organometallic polymer-functionalized Fe 3 O 4 nanoparticles
as a highly efficient and eco-friendly nanocatalyst for C-C bond formation. Trans Met Chem
43(5):463–472. https://doi.org/10.1007/s11243-018-0233-5
40. Favier I, Pla D, Gómez M (2018) Metal-based nanoparticles dispersed in glycerol: an efficient
approach for catalysis. Catal Today 310:98–106. https://doi.org/10.1016/j.cattod.2017.06.026