419
recyclable plastic, 96
technology, 96
Free flow agent, 222
Freeze-drying, 109
Functional nanocomposite, 113
Functional siloxanes
Azo-modified silicones, 272
biomedical applications (see Biomedical
applications)
chemical modification, 271
electromechanical applications (see
Electromechanical applications)
inorganic-organic hybrid materials, 271
LC materials (see Liquid crystalline (LC)
materials)
ligands (see Ligands)
organosilicones, 272
PDMS, 236
photocross-linked polymer, 272
POSS, 271
post-functionalization (see Postfunctionalization of silicones)
printing, textile materials, 271
pyridyl-siloxanes, 272
ROP, 238–240
silane monomers, 237, 238
siloxane segment, 272
stain resistance, 271
superhydrophobic coatings, 271
surface-modified NPs, 271
surfactants, 261–263
G
Gelatin, 82
Gelatin-siloxane NPs, 266
Gemini surfactants, 318
Grafting
approaches, 26
definition, 26
polymerization (see Polymerization
techniques, grafting)
Ground tire rubber (GTR)
applications, 52
cross-linked network, 52
functionalization/modification, 52
continuous methods, 59
grafting
acrylic acid, 57, 58
chemical compounds, 57
free-radical initiators decomposition, 57
high energy radiation, 57
monomers, 57
photo-induced grafting, 57
hydrophilic groups, 57
oxygen pretreatment, 58
ozonization treatment, 57
polymer matrix, 59
reactive sintering (see Reactive sintering)
GTR-based magnetorheological elastomers, 51
GTR functionalization/modification
coupling agents, 55, 56
objective, 52
reclaiming/devulcanization, 52, 53
structure-properties relationships, 46
surface polarity improvement, 54–55
GTR surface polarity improvement
acidic treatment, 54
chemical etching, 54
chlorination, 55
matrix-GTR compatibilization, 54
mesopores and macropores, 54
oxidizing agents, 55
H
Halloysites, 103
Hard segments (HS), 173
Heterolytic fissions, 209
Hexamethyldisiloxane (HMDS), 264
1,6-Hexamethylene diisocyanate (HDI), 178
1,6-Hexane diol (HD), 159
HDPE/GTR mixtures, 55
High antioxidant activities
chemical modification, 73
DL, 72
EHP, 73
EML, 73
enzymatic treatment, 72
extraction processes, 72
factors, 71
heterogeneity, 73
Miscanthus sinensis, 72
solubility, 73
High density polyethylene (HDPE), 54
High temperature vulcanization
(HTV), 312
HTV silicones, 297
Human hepatic stellate cells (HHSteCs), 74
Human keratinocyte (HaCaT), 74
Hybrid LC materials, 260, 261
Hydridosilanes, 306
2-Hydroxyethyl acrylate (HEA), 176
2-Hydroxyethyl methacrylate (HEMA),
176, 183
3-Hydroxypropyl methacrylate (HPMA), 176
Hydrolytic treatments, 23
Hydrophilic polymers, 9
Index
recyclable plastic, 96
technology, 96
Free flow agent, 222
Freeze-drying, 109
Functional nanocomposite, 113
Functional siloxanes
Azo-modified silicones, 272
biomedical applications (see Biomedical
applications)
chemical modification, 271
electromechanical applications (see
Electromechanical applications)
inorganic-organic hybrid materials, 271
LC materials (see Liquid crystalline (LC)
materials)
ligands (see Ligands)
organosilicones, 272
PDMS, 236
photocross-linked polymer, 272
POSS, 271
post-functionalization (see Postfunctionalization of silicones)
printing, textile materials, 271
pyridyl-siloxanes, 272
ROP, 238–240
silane monomers, 237, 238
siloxane segment, 272
stain resistance, 271
superhydrophobic coatings, 271
surface-modified NPs, 271
surfactants, 261–263
G
Gelatin, 82
Gelatin-siloxane NPs, 266
Gemini surfactants, 318
Grafting
approaches, 26
definition, 26
polymerization (see Polymerization
techniques, grafting)
Ground tire rubber (GTR)
applications, 52
cross-linked network, 52
functionalization/modification, 52
continuous methods, 59
grafting
acrylic acid, 57, 58
chemical compounds, 57
free-radical initiators decomposition, 57
high energy radiation, 57
monomers, 57
photo-induced grafting, 57
hydrophilic groups, 57
oxygen pretreatment, 58
ozonization treatment, 57
polymer matrix, 59
reactive sintering (see Reactive sintering)
GTR-based magnetorheological elastomers, 51
GTR functionalization/modification
coupling agents, 55, 56
objective, 52
reclaiming/devulcanization, 52, 53
structure-properties relationships, 46
surface polarity improvement, 54–55
GTR surface polarity improvement
acidic treatment, 54
chemical etching, 54
chlorination, 55
matrix-GTR compatibilization, 54
mesopores and macropores, 54
oxidizing agents, 55
H
Halloysites, 103
Hard segments (HS), 173
Heterolytic fissions, 209
Hexamethyldisiloxane (HMDS), 264
1,6-Hexamethylene diisocyanate (HDI), 178
1,6-Hexane diol (HD), 159
HDPE/GTR mixtures, 55
High antioxidant activities
chemical modification, 73
DL, 72
EHP, 73
EML, 73
enzymatic treatment, 72
extraction processes, 72
factors, 71
heterogeneity, 73
Miscanthus sinensis, 72
solubility, 73
High density polyethylene (HDPE), 54
High temperature vulcanization
(HTV), 312
HTV silicones, 297
Human hepatic stellate cells (HHSteCs), 74
Human keratinocyte (HaCaT), 74
Hybrid LC materials, 260, 261
Hydridosilanes, 306
2-Hydroxyethyl acrylate (HEA), 176
2-Hydroxyethyl methacrylate (HEMA),
176, 183
3-Hydroxypropyl methacrylate (HPMA), 176
Hydrolytic treatments, 23
Hydrophilic polymers, 9
Index