Prucek R, Tuček J, Kolařík J, Filip J, Marušák Z, Sharma VK, Zbořil R (2013) Ferrate(VI)-induced
arsenite and arsenate removal by in situ structural incorporation into magnetic iron(III) oxide
nanoparticles. Environ Sci Technol 47(7):3283–3292. https://doi.org/10.1021/es3042719
Prucek R, Tuček J, Kolařík J, Hušková I, Filip J, Varma RS, Sharma VK, Zbořil R (2015) Ferrate
(VI)-prompted removal of metals in aqueous media: mechanistic delineation of enhanced
efficiency via metal entrenchment in magnetic oxides. Environ Sci Technol 49(4):2319–2327.
https://doi.org/10.1021/es5048683
Rai PK, Lee J, Kailasa SK, Kwon EE, Tsang YF, Ok YS, Kim K-H (2018) A critical review of
ferrate(VI)-based remediation of soil and groundwater. Environ Res 160:420–448. https://doi.
org/10.1016/j.envres.2017.10.016
Sharma VK (2002) Potassium ferrate(VI): an environmentally friendly oxidant. Adv Environ Res 6
(2):143–156. https://doi.org/10.1016/S1093-0191(01)00119-8
Sharma VK (2010) Oxidation of nitrogen-containing pollutants by novel ferrate(VI) technology: a
review. J Environ Sci Health, Part A: Tox Hazard Subst Environ Eng 45(6):645–667. https://doi.
org/10.1080/10934521003648784
Sharma VK (2013) Ferrate(VI) and ferrate(V) oxidation of organic compounds: kinetics and
mechanism. Coord Chem Rev 257(2):495–510. https://doi.org/10.1016/j.ccr.2012.04.014
Sharma VK, Mishra SK, Nesnas N (2006) Oxidation of sulfonamide antimicrobials by ferrate
(VI) [Fe
VI O 4
2À
]. Environ Sci Technol 40(23):7222–7227. https://doi.org/10.1021/es060351z
Sharma VK, Liu F, Tolan S, Sohn M, Kim H, Oturan MA (2013) Oxidation of β-lactam antibiotics
by ferrate(VI). Chem Eng J 221:446–451. https://doi.org/10.1016/j.cej.2013.02.024
Sharma VK, Zboril R, Varma RS (2015) Ferrates: greener oxidants with multimodal action in water
treatment technologies. Acc Chem Res 48(2):182–191. https://doi.org/10.1021/ar5004219
Sharma VK, Chen L, Zboril R (2016a) Review on high valent Fe
VI (ferrate): a sustainable green
oxidant in organic chemistry and transformation of pharmaceuticals. ACS Sustain Chem Eng 4
(1):18–34. https://doi.org/10.1021/acssuschemeng.5b01202
Sharma VK, Tolan S, Bumbálek V, Macova Z, Bouzek K (2016b) Stability of ferrate(VI) in 14 M
NaOH-KOH mixtures at different temperatures. In: Ferrites and ferrates: chemistry and applications in sustainable energy and environmental remediation, ACS Symposium Series, vol
1238. American Chemical Society, Washington, DC, pp 241–253. https://doi.org/10.1021/bk2016-1238.ch009
Sun XH, Zhang Q, Liang H, Ying L, Meng XX, Sharma VK (2016) Ferrate(VI) as a greener
oxidant: electrochemical generation and treatment of phenol. J Hazard Mater 319:130–136.
https://doi.org/10.1016/j.jhazmat.2015.12.020
Sun S, Liu Y, Ma J, Pang S, Huang Z, Gu J, Gao Y, Xue M, Yuan Y, Jiang J (2018) Transformation
of substituted anilines by ferrate(VI): kinetics, pathways, and effect of dissolved organic matter.
Chem Eng J 332:245–252. https://doi.org/10.1016/j.cej.2017.08.116
Yngard RA, Sharma VK, Filip J, Zboril R (2008) Ferrate(VI) oxidation of weak-acid dissociable
cyanides. Environ Sci Technol 42(8):3005–3010. https://doi.org/10.1021/es0720816
Yu XW, Licht S (2008) Advances in electrochemical Fe(VI) synthesis and analysis. J Appl
Electrochem 38(6):731–742. https://doi.org/10.1007/s10800-008-9536-0
Yu H, Chen JW, Xie HB, Ge P, Kong QW, Luo Y (2017) Ferrate(VI) initiated oxidative
degradation mechanisms clarified by DFT calculations: a case for sulfamethoxazole. Environ
Sci Process Impacts 19(3):370–378. https://doi.org/10.1039/c6em00521g
Zajíček P, Kolář M, Prucek R, Ranc V, Bednář P, Varma RS, Sharma VK, Zbořil R (2015)
Oxidative degradation of triazine- and sulfonylurea-based herbicides using Fe(VI): the case
study of atrazine and iodosulfuron with kinetics and degradation products. Sep Purif Technol
156:1041–1046. https://doi.org/10.1016/j.seppur.2015.08.024
8 Ferrates as Powerful Oxidants in Water Treatment Technologies
201
arsenite and arsenate removal by in situ structural incorporation into magnetic iron(III) oxide
nanoparticles. Environ Sci Technol 47(7):3283–3292. https://doi.org/10.1021/es3042719
Prucek R, Tuček J, Kolařík J, Hušková I, Filip J, Varma RS, Sharma VK, Zbořil R (2015) Ferrate
(VI)-prompted removal of metals in aqueous media: mechanistic delineation of enhanced
efficiency via metal entrenchment in magnetic oxides. Environ Sci Technol 49(4):2319–2327.
https://doi.org/10.1021/es5048683
Rai PK, Lee J, Kailasa SK, Kwon EE, Tsang YF, Ok YS, Kim K-H (2018) A critical review of
ferrate(VI)-based remediation of soil and groundwater. Environ Res 160:420–448. https://doi.
org/10.1016/j.envres.2017.10.016
Sharma VK (2002) Potassium ferrate(VI): an environmentally friendly oxidant. Adv Environ Res 6
(2):143–156. https://doi.org/10.1016/S1093-0191(01)00119-8
Sharma VK (2010) Oxidation of nitrogen-containing pollutants by novel ferrate(VI) technology: a
review. J Environ Sci Health, Part A: Tox Hazard Subst Environ Eng 45(6):645–667. https://doi.
org/10.1080/10934521003648784
Sharma VK (2013) Ferrate(VI) and ferrate(V) oxidation of organic compounds: kinetics and
mechanism. Coord Chem Rev 257(2):495–510. https://doi.org/10.1016/j.ccr.2012.04.014
Sharma VK, Mishra SK, Nesnas N (2006) Oxidation of sulfonamide antimicrobials by ferrate
(VI) [Fe
VI O 4
2À
]. Environ Sci Technol 40(23):7222–7227. https://doi.org/10.1021/es060351z
Sharma VK, Liu F, Tolan S, Sohn M, Kim H, Oturan MA (2013) Oxidation of β-lactam antibiotics
by ferrate(VI). Chem Eng J 221:446–451. https://doi.org/10.1016/j.cej.2013.02.024
Sharma VK, Zboril R, Varma RS (2015) Ferrates: greener oxidants with multimodal action in water
treatment technologies. Acc Chem Res 48(2):182–191. https://doi.org/10.1021/ar5004219
Sharma VK, Chen L, Zboril R (2016a) Review on high valent Fe
VI (ferrate): a sustainable green
oxidant in organic chemistry and transformation of pharmaceuticals. ACS Sustain Chem Eng 4
(1):18–34. https://doi.org/10.1021/acssuschemeng.5b01202
Sharma VK, Tolan S, Bumbálek V, Macova Z, Bouzek K (2016b) Stability of ferrate(VI) in 14 M
NaOH-KOH mixtures at different temperatures. In: Ferrites and ferrates: chemistry and applications in sustainable energy and environmental remediation, ACS Symposium Series, vol
1238. American Chemical Society, Washington, DC, pp 241–253. https://doi.org/10.1021/bk2016-1238.ch009
Sun XH, Zhang Q, Liang H, Ying L, Meng XX, Sharma VK (2016) Ferrate(VI) as a greener
oxidant: electrochemical generation and treatment of phenol. J Hazard Mater 319:130–136.
https://doi.org/10.1016/j.jhazmat.2015.12.020
Sun S, Liu Y, Ma J, Pang S, Huang Z, Gu J, Gao Y, Xue M, Yuan Y, Jiang J (2018) Transformation
of substituted anilines by ferrate(VI): kinetics, pathways, and effect of dissolved organic matter.
Chem Eng J 332:245–252. https://doi.org/10.1016/j.cej.2017.08.116
Yngard RA, Sharma VK, Filip J, Zboril R (2008) Ferrate(VI) oxidation of weak-acid dissociable
cyanides. Environ Sci Technol 42(8):3005–3010. https://doi.org/10.1021/es0720816
Yu XW, Licht S (2008) Advances in electrochemical Fe(VI) synthesis and analysis. J Appl
Electrochem 38(6):731–742. https://doi.org/10.1007/s10800-008-9536-0
Yu H, Chen JW, Xie HB, Ge P, Kong QW, Luo Y (2017) Ferrate(VI) initiated oxidative
degradation mechanisms clarified by DFT calculations: a case for sulfamethoxazole. Environ
Sci Process Impacts 19(3):370–378. https://doi.org/10.1039/c6em00521g
Zajíček P, Kolář M, Prucek R, Ranc V, Bednář P, Varma RS, Sharma VK, Zbořil R (2015)
Oxidative degradation of triazine- and sulfonylurea-based herbicides using Fe(VI): the case
study of atrazine and iodosulfuron with kinetics and degradation products. Sep Purif Technol
156:1041–1046. https://doi.org/10.1016/j.seppur.2015.08.024
8 Ferrates as Powerful Oxidants in Water Treatment Technologies
201