155
Sakurai H, Haruta M (1996) Synergism in methanol synthesis from carbon dioxide over
gold catalysts supported on metal oxides. Catal Today 29(1–4):361–365. https://doi.
org/10.1016/0920-5861(95)00305-3
Seshadri G, Lin C, Bocarsly AB (1994) A new homogeneous electrocatalyst for the reduction
of carbon dioxide to methanol at low overpotential. J Electroanal Chem 372(1–2):145–150.
https://doi.org/10.1016/0022-0728(94)03300-5
Shao C, Fan L, Fujimoto K, Iwasawa Y (1995) Selective methanol synthesis from CO 2 /H 2 on new
SiO 2 -supported PtW and PtCr bimetallic catalysts. Appl Catal A Gen 128(1):L1–L6. https://
doi.org/10.1016/0926-860X(95)00109-3
Shen W-J, Okumura M, Matsumura Y, Haruta M (2001) The influence of the support on the activity and selectivity of Pd in CO hydrogenation. Appl Catal A Gen 213(2):225–232. https://doi.
org/10.1016/S0926-860X(01)00465-3
Shen WJ, Ichihashi Y, Matsumura Y (2005) Low temperature methanol synthesis from carbon monoxide and hydrogen over ceria supported copper catalyst. Appl Catal A Gen 282(1–2):221–226.
https://doi.org/10.1016/j.apcata.2004.12.046
Słoczyński J, Grabowski R, Kozłowska A, Olszewski P, Lachowska M, Skrzypek J, Stoch J (2003)
Effect of Mg and Mn oxide additions on structural and adsorptive properties of Cu/ZnO/ZrO2
catalysts for the methanol synthesis from CO 2 . Appl Catal A Gen 249(1):129–138. https://doi.
org/10.1016/S0926-860X(03)00191-1
Słoczyński J, Grabowski R, Kozłowska A, Olszewski P, Stoch J, Skrzypek J, Lachowska M (2004)
Catalytic activity of the M/(3ZnO·ZrO 2 ) system (M = Cu, Ag, Au) in the hydrogenation of CO 2
to methanol. Appl Catal A Gen 278(1):11–23. https://doi.org/10.1016/j.apcata.2004.09.014
Stangeland K, Li H, Yu Z (2018) Thermodynamic analysis of chemical and phase equilibria in CO 2
hydrogenation to methanol, dimethyl ether, and higher alcohols. Ind Eng Chem Res 57:4081–
4094. https://doi.org/10.1021/acs.iecr.7b04866
Stanislaw L, Nowicki L, Petera J, Niziol J, Kowalik P, Golebiowski A (2013) Kinetic characterization of catalysts for methanol synthesis. Chem Proc Engi 34(4):497–506. https://doi.
org/10.2478/cpe-2013-0040
Stephan DW (2008) “Frustrated Lewis pairs”: a concept for new reactivity and catalysis. Organic
Biomol Chem 6(9):1535–1539. https://doi.org/10.1039/B802575B
Sugawa S, Sayama K, Okabe K, Arakawa H (1995) Methanol synthesis from CO 2
and H 2 over silver catalyst. Energy Convers Manag 36(6–9):665–668. https://doi.
org/10.1016/0196-8904(95)00093-S
Sun YW, Rhee HK (2002) Optimum washing conditions for the preparation of Cu/ZnO/ZrO 2 for
methanol synthesis from CO hydrogenation: effects of residual sodium. Korean J Chem Eng
19(1):17–19. https://doi.org/10.1007/BF02706869
Sun Q, Liu CW, Pan W, Zhu QM, Deng JM (1998) In situ IR studies on the mechanism of methanol synthesis over an ultrafine Cu/ZnO/Al 2 O 3 catalyst. Appl Catal A Gen 171(2):301–308.
https://doi.org/10.1016/S0926-860X(98)00096-9
Takeshi K, Hayakawa I, Mabuse H, Mori K, Ushikoshi K, Watanabe T, Saito M (2001) Kinetic study
of methanol synthesis from carbon dioxide and hydrogen. Appl Organometal Chem 15:121–
126. https://doi.org/10.1002/1099-0739(200102)15:2<121::AID-AOC106>3.0.CO;2-3
Tang Q, Shen Z, Russell CK, Fan M (2018) Thermodynamic and kinetic study on carbon dioxide
hydrogenation to methanol over a Ga3Ni5(111) surface: the effects of step edge. J Phys Chem
C 122:315–330. https://doi.org/10.1021/acs.jpcc.7b08232
Tominaga K-I, Sasaki Y, Kawai M, Watanabe T, Saito M (1993) Ruthenium complex catalysed
hydrogenation of carbon dioxide to carbon monoxide, methanol and methane. Chem Comm
7:629–631. https://doi.org/10.1039/C39930000629
Tominaga K-I, Sasaki Y, Watanabe T, Saito M (1995) Homogeneous hydrogenation of carbon
dioxide to methanol catalyzed by ruthenium cluster anions in the presence of halide anions.
Bull Chem Soc Japan 68(10):2837–2842. https://doi.org/10.1246/bcsj.68.2837
5 Selective Hydrogenation of Carbon Dioxide into Methanol
Sakurai H, Haruta M (1996) Synergism in methanol synthesis from carbon dioxide over
gold catalysts supported on metal oxides. Catal Today 29(1–4):361–365. https://doi.
org/10.1016/0920-5861(95)00305-3
Seshadri G, Lin C, Bocarsly AB (1994) A new homogeneous electrocatalyst for the reduction
of carbon dioxide to methanol at low overpotential. J Electroanal Chem 372(1–2):145–150.
https://doi.org/10.1016/0022-0728(94)03300-5
Shao C, Fan L, Fujimoto K, Iwasawa Y (1995) Selective methanol synthesis from CO 2 /H 2 on new
SiO 2 -supported PtW and PtCr bimetallic catalysts. Appl Catal A Gen 128(1):L1–L6. https://
doi.org/10.1016/0926-860X(95)00109-3
Shen W-J, Okumura M, Matsumura Y, Haruta M (2001) The influence of the support on the activity and selectivity of Pd in CO hydrogenation. Appl Catal A Gen 213(2):225–232. https://doi.
org/10.1016/S0926-860X(01)00465-3
Shen WJ, Ichihashi Y, Matsumura Y (2005) Low temperature methanol synthesis from carbon monoxide and hydrogen over ceria supported copper catalyst. Appl Catal A Gen 282(1–2):221–226.
https://doi.org/10.1016/j.apcata.2004.12.046
Słoczyński J, Grabowski R, Kozłowska A, Olszewski P, Lachowska M, Skrzypek J, Stoch J (2003)
Effect of Mg and Mn oxide additions on structural and adsorptive properties of Cu/ZnO/ZrO2
catalysts for the methanol synthesis from CO 2 . Appl Catal A Gen 249(1):129–138. https://doi.
org/10.1016/S0926-860X(03)00191-1
Słoczyński J, Grabowski R, Kozłowska A, Olszewski P, Stoch J, Skrzypek J, Lachowska M (2004)
Catalytic activity of the M/(3ZnO·ZrO 2 ) system (M = Cu, Ag, Au) in the hydrogenation of CO 2
to methanol. Appl Catal A Gen 278(1):11–23. https://doi.org/10.1016/j.apcata.2004.09.014
Stangeland K, Li H, Yu Z (2018) Thermodynamic analysis of chemical and phase equilibria in CO 2
hydrogenation to methanol, dimethyl ether, and higher alcohols. Ind Eng Chem Res 57:4081–
4094. https://doi.org/10.1021/acs.iecr.7b04866
Stanislaw L, Nowicki L, Petera J, Niziol J, Kowalik P, Golebiowski A (2013) Kinetic characterization of catalysts for methanol synthesis. Chem Proc Engi 34(4):497–506. https://doi.
org/10.2478/cpe-2013-0040
Stephan DW (2008) “Frustrated Lewis pairs”: a concept for new reactivity and catalysis. Organic
Biomol Chem 6(9):1535–1539. https://doi.org/10.1039/B802575B
Sugawa S, Sayama K, Okabe K, Arakawa H (1995) Methanol synthesis from CO 2
and H 2 over silver catalyst. Energy Convers Manag 36(6–9):665–668. https://doi.
org/10.1016/0196-8904(95)00093-S
Sun YW, Rhee HK (2002) Optimum washing conditions for the preparation of Cu/ZnO/ZrO 2 for
methanol synthesis from CO hydrogenation: effects of residual sodium. Korean J Chem Eng
19(1):17–19. https://doi.org/10.1007/BF02706869
Sun Q, Liu CW, Pan W, Zhu QM, Deng JM (1998) In situ IR studies on the mechanism of methanol synthesis over an ultrafine Cu/ZnO/Al 2 O 3 catalyst. Appl Catal A Gen 171(2):301–308.
https://doi.org/10.1016/S0926-860X(98)00096-9
Takeshi K, Hayakawa I, Mabuse H, Mori K, Ushikoshi K, Watanabe T, Saito M (2001) Kinetic study
of methanol synthesis from carbon dioxide and hydrogen. Appl Organometal Chem 15:121–
126. https://doi.org/10.1002/1099-0739(200102)15:2<121::AID-AOC106>3.0.CO;2-3
Tang Q, Shen Z, Russell CK, Fan M (2018) Thermodynamic and kinetic study on carbon dioxide
hydrogenation to methanol over a Ga3Ni5(111) surface: the effects of step edge. J Phys Chem
C 122:315–330. https://doi.org/10.1021/acs.jpcc.7b08232
Tominaga K-I, Sasaki Y, Kawai M, Watanabe T, Saito M (1993) Ruthenium complex catalysed
hydrogenation of carbon dioxide to carbon monoxide, methanol and methane. Chem Comm
7:629–631. https://doi.org/10.1039/C39930000629
Tominaga K-I, Sasaki Y, Watanabe T, Saito M (1995) Homogeneous hydrogenation of carbon
dioxide to methanol catalyzed by ruthenium cluster anions in the presence of halide anions.
Bull Chem Soc Japan 68(10):2837–2842. https://doi.org/10.1246/bcsj.68.2837
5 Selective Hydrogenation of Carbon Dioxide into Methanol